Patent classifications
C08G18/725
Polyisocyanate mixture, coating composition, and coating film
Provided is a polyisocyanate mixture including: a triisocyanate compound (A) represented by Formula (I); and polyisocyanate (B) obtained from at least one diisocyanate selected from the group consisting of aliphatic diisocyanate, alicyclic diisocyanate, and aromatic diisocyanate. ##STR00001## (In Formula (1), a plurality of Y.sup.1's each independently represent a single bond or a divalent hydrocarbon group having 1 to 20 carbon atoms which may have an ester structure and/or an ether structure. A plurality of Y.sup.1's may be the same as or different from one another. R.sup.1 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 12 carbon atoms.)
METHOD FOR REDUCING COEFFICIENT OF FRICTION OF A LAMINATE COMPRISING A POLYURETHANE ADHESIVE
A method for reducing coefficient of friction of a laminate comprising a polyurethane adhesive is provided. The method comprises providing the polyurethane adhesive; and adhering at least two substrates with the polyurethane adhesive to form a laminate, wherein the polyurethane adhesive is formed by reacting (A) an isocyanate component comprising a prepolymer derived from the reaction of a diisocyanate, a polyethylene glycol and optionally an additional polyol; with (B) a polyol component. The method can achieve minimized COF and viscosity, while retaining other performance properties such as bond strength, heat seal strength and boil in bag resistance. A composition for preparing the adhesive, a laminate product prepared with said composition as well the method for preparing the laminate product are also provided.
AQUEOUS BINDER FORMULATION
Described herein are aqueous binder formulations including organic compounds including acryloyloxy groups and carboxylic acid hydrazides.
Novel Polymers Depolymerizable by Metathesis of a Cleavable Unit
Novel polymers are depolymerizable by metathesis of a cleavable unit. As an example, a series of linear and crosslinked polyurethanes were prepared that can be selectively depolymerized under mild conditions. Two unique polyols were synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis to five- and six-membered cycloalkenes. These polyols were co-polymerized with toluene diisocyanate to generate linear polyurethanes and trifunctional hexamethylene- and diphenylmethane-based isocyanates to generate crosslinked polyurethanes. The polyol design is such that the ring-closing metathesis reaction cleaves the backbone of the polymer chain. Upon exposure to dilute solutions of Grubbs' catalyst under ambient conditions, the polyurethanes were rapidly depolymerized to low molecular weight, soluble products bearing vinyl and cycloalkene functionalities. These functionalities enabled further re-polymerization by traditional strategies for polymerization of double bonds. This general approach can be expanded to develop a range of chemically recyclable condensation polymers that are readily depolymerized by orthogonal metathesis chemistry.
ADDITIVE MANUFACTURING OF AN OBJECT MADE OF A POLYUREA MATERIAL
Modeling material formulations usable for forming a polyurea material in additive manufacturing, and methods for additive manufacturing of three-dimensional objects made of these formulations are provided. The modeling material formulation comprises at least one isocyanate-containing material and at least one amine-containing material such that at least one isocyanate-containing material comprises at least one polyisocyanate material and at least one amine-containing material comprises at least one aromatic polyamine material.
Golf ball
An object of the present invention is to provide a golf ball having improved spin performance on wedge shots under a wet condition such as rain by controlling the formulation of the paint film. The present invention provides a golf ball comprising a golf ball body and a paint film covering the golf ball body, wherein the paint film contains a base resin and a porous filler, and the porous filler contains SiO.sub.2 as a constituent in an amount of 50 mass % or more.
Golf ball
An object of the present invention is to provide a golf ball having improved spin performance on wedge shots under a wet condition such as rain by controlling the formulation of the paint film. The present invention provides a golf ball comprising a golf ball body and a paint film covering the golf ball body, wherein the paint film contains a base resin and a porous filler, and the porous filler contains SiO.sub.2 as a constituent in an amount of 50 mass % or more.
ADHESIVE COMPOSITION, LAMINATE AND OPTICAL ARTICLE COMPRISING THE LAMINATE
To provide an adhesive composition capable of firmly bonding polymer sheets together, comprising: (I) 100 parts by mass of an end-unreactive urethane urea resin; and (III) 4.0 to 20 parts by mass of a polyisocyanate compound having at least two isocyanate groups in the molecule, wherein the polyisocyanate compound (III) contains (IIIA) a polyisocyanate compound having an isocyanate group bonded to secondary carbon and (IIIB) a polyisocyanate compound having 4 to 30 carbon atoms in the molecule other than the component (IIIA), and the amount of the component (IIIB) is 10 to 500 parts by mass based on 100 parts by mass of the component (IIIA).
ADHESIVE COMPOSITION, LAMINATE AND OPTICAL ARTICLE COMPRISING THE LAMINATE
To provide an adhesive composition capable of firmly bonding polymer sheets together, comprising: (I) 100 parts by mass of an end-unreactive urethane urea resin; and (III) 4.0 to 20 parts by mass of a polyisocyanate compound having at least two isocyanate groups in the molecule, wherein the polyisocyanate compound (III) contains (IIIA) a polyisocyanate compound having an isocyanate group bonded to secondary carbon and (IIIB) a polyisocyanate compound having 4 to 30 carbon atoms in the molecule other than the component (IIIA), and the amount of the component (IIIB) is 10 to 500 parts by mass based on 100 parts by mass of the component (IIIA).
Flexible foams
The present invention relates to a composition for preparing flexible foams and the application thereof. The composition comprises the following components: a. an isocyanate mixture comprising: a1) an aliphatic and/or alicyclic isocyanate monomer, and a2) an aliphatic and/or alicyclic; isocyanate trimer, wherein the mass ratio of said monomer to said trimer is in a range of 3:1-200:1; b. a polymer polyol mixture comprising: b1) a first polyether polyol having a number average molecular weight of not less than 3000 g/mol with an ethylene oxide content of 5-20 wt. %, b2) a second polyether polyol having a number average molecular weight of not less than 3000 g/mol with an ethylene oxide content of more than 60 wt. %, wherein the mass ratio of said first polyether polyol to said second polyether polyol is in a range of 4:1-100:1; c. an isocyanate-reactive group comprising compound having a number average molecular weight of 32-400 g/mol; d. a catalyst; e. a foaming agent; and f. optionally, an additive; wherein said composition has an isocyanate index of 70-120.