Formulation systems usable for fabricating a three-dimensional object made of a polyamide-containing material, by three-dimensional 3D inkjet printing, and methods and systems utilizing same, are provided. The formulation systems are formed of at least a first and second model formulations containing a lactam and a catalyst for inducing anionic ring opening polymerization of the lactam in the first formulation, and an activator for promoting anionic ring opening polymerization of the lactam in the second formulation, and are further characterized as: including in the first and/or second formulation a compound capable of increasing a rate of said polymerization upon exposure to said curing energy; including as an activator a lactam-blocked polyisocyanate; and/or as including in the first model formulation at least one material capable of reducing a melting point of said first model formulation. Formulation systems usable at a selected ratio are also provided.

The invention relates to a method for producing a poly(anthranilamide) via the polymerisation of isatoic anhydride, preferably in the presence of a solvent, on a starter at a reaction temperature in the region of 110° C. to 300° C., wherein the starter comprises an aliphatic mono- or diamine with 5 to 13 carbon atoms, an araliphatic mono- or diamine with 7 to 15 carbon atoms, an aromatic diamine with 6 to 13 carbon atoms, a carboxylic acid amide of formula Ar—(C═O)NHR, where Ar represents an aromatic group substituted with an amine NH— or NH2 group and R represents an aromatic or aliphatic group, or a mixture of the above-mentioned starters, and wherein the solvent, if used, comprises an organic solvent, which is in liquid form at the reaction temperature, an ionic liquid or a mixture of these solvents, obtaining a poly(anthranilamide) based on the starter. The invention also relates to the poly(anthranilamide) obtained with the method according to the invention and to the use thereof in the production of fibres or composite materials.

A process for the production of a masterbatch (M) which includes at least one lactam and at least one fiber material is provided herein. Also described herein is the masterbatch (M) and a polymerizable two-component system (pS), as well as a process for the production of a polyamide (P), the use of the masterbatch (M) for the production of the polyamide (P), and the polyamide (P). A molding made of the polyamide (P) is also described.

Formulation systems usable for fabricating a three-dimensional object made of a polyamide-containing material, by three-dimensional 3D inkjet printing, and methods and systems utilizing same, are provided. The formulation systems are formed of at least a first and second model formulations containing a lactam and a catalyst for inducing anionic ring opening polymerization of the lactam in the first formulation, and an activator for promoting anionic ring opening polymerization of the lactam in the second formulation, and are further characterized as: including in the first and/or second formulation a compound capable of increasing a rate of said polymerization upon exposure to said curing energy; including as an activator a lactam-blocked polyisocyanate; and/or as including in the first model formulation at least one material capable of reducing a melting point of said first model formulation. Formulation systems usable at a selected ratio are also provided.

Formulation systems usable for fabricating a three-dimensional object made of a polyamide-containing material, by three-dimensional 3D inkjet printing, and methods and systems utilizing same, are provided. The formulation systems are formed of at least a first and second model formulations containing a lactam and a catalyst for inducing anionic ring opening polymerization of the lactam in the first formulation, and an activator for promoting anionic ring opening polymerization of the lactam in the second formulation, and are further characterized as: including in the first and/or second formulation a compound capable of increasing a rate of said polymerization upon exposure to said curing energy; including as an activator a lactam-blocked polyisocyanate; and/or as including in the first model formulation at least one material capable of reducing a melting point of said first model formulation. Formulation systems usable at a selected ratio are also provided.

A polymerizable composition comprising a) at feast one cyclic amide, b) from 2.8 to 3.5% by weight, preferably from 2.9 to 3.1% by weight, of at least one blocked polyisocyanate, and c) from 1.2 to 1.4% by weight of at least one catalyst for the polymerization of the cyclic amide,
where the ratio by weight of components b) to c) is from 2.0 to 2.9 and the % by weight data are always based on the entirety of components a) to c).

A polymerizable composition comprising a) at feast one cyclic amide, b) from 2.8 to 3.5% by weight, preferably from 2.9 to 3.1% by weight, of at least one blocked polyisocyanate, and c) from 1.2 to 1.4% by weight of at least one catalyst for the polymerization of the cyclic amide,
where the ratio by weight of components b) to c) is from 2.0 to 2.9 and the % by weight data are always based on the entirety of components a) to c).

The present invention provides a method for producing a polyamide with controlled activator addition, and a polyamide produced thereby, the method allowing a polymerization conversion rate and a polydispersity index (PDI) to be enhanced by controlling the addition of an activator so as to prevent a gelation phenomenon that occurs during anionic polymerization.

The present invention provides a method for producing a polyamide with controlled activator addition, and a polyamide produced thereby, the method allowing a polymerization conversion rate and a polydispersity index (PDI) to be enhanced by controlling the addition of an activator so as to prevent a gelation phenomenon that occurs during anionic polymerization.

The invention relates to a seeded particle of polyamide (PA) powder consisting of: a polyamide core with a D50 within the range from 15 to 60 μm, and a polyamide shell,
characterized in that the shell has an inherent viscosity in solution and a melting temperature which are respectively higher than those of the core.