Patent classifications
C08J5/2256
ION EXCHANGE POLYMERS AND ION EXCHANGE MEMBRANES INCORPORATING SAME
An ion exchange membrane is provided which includes an ion exchange polymer that is partially cross-linked. The partially cross-linked ion exchange polymer will be more stable and will not be washed out over time. The ion exchange polymer may be UV or chemically cross-linked, wherein a cross-linking compound is added to the ion exchange polymer either before or after coupling to a support material. A support material may be made of, or be coated with, a cross-linking compound and the support material may initiate cross-linking proximal to the support material. The support material may be made of a material that chemically bonds with the ionomer.
DEVICE FOR REMOVING MICROPARTICLES CONTAINED IN WATER AND ULTRAPURE-WATER PROUCTION AND SUPPLY SYSTEM
In a subsystem or water-feed path located upsteam of a use point in an ultrapure water production/supply process, fine particles having a particle diameter of 50 nm or less, in particular 10 nm or less are highly removed. A device for removing fine particles in water has a membrane filtration device including a microfiltration membrane or an ultrafiltration membrane having a weak cationic functional group. The microfiltration membrane or the ultrafiltration membrane having a weak cationic functional group is preferred to have a polyketone film with the weak cationic functional group. Negatively-charged particles in water are adsorbed by the weak cationic functional group and can thus be removed.
Copolyesters derived from aliphatic glycols, aromatic dicarboxylic acids and poly(alkylene-oxides) and films made therefrom
An optionally oriented copolyester film comprising a copolyester which comprises repeating units derived from an aliphatic diol, an aromatic dicarboxylic acid and a poly(alkylene oxide), wherein the copolyester film further comprises lithium ions, and wherein the film has a thickness of no more than about 25 m. The copolyester film is suitable for use a separator in a lithium-ion rechargeable battery.
LAYERED BIMETALLIC HYDROXIDE-BASED HYDROGEL BIPOLAR MEMBRANE AND METHOD FOR PREPARING SAME
The present disclosure relates to a layered bimetallic hydroxide-based hydrogel bipolar membrane and a method for preparing the same. The method includes: blade-coating a quaternized polyethersulfone solution on a substrate, and carrying out drying to obtain an anion exchange layer; immersing the layer sequentially and cyclically in a sodium alginate solution and a first metal ion mixed solution to obtain a hydrogel anion exchange membrane; immersing the hydrogel membrane sequentially in a second metal ion mixed solution and an alkaline solution; and blade-coating a sulfonated polyethersulfone solution on the obtained membrane, and carrying out drying to obtain the layered bimetallic hydroxide-based hydrogel bipolar membrane. The anion and cation exchange membrane layers on two sides of the bipolar membrane prepared in the present disclosure are closely bound by way of hydrogel cross-linking. The bipolar membrane has the advantages of high water dissociation efficiency, low energy consumption, and good stability.
PARTICLE COMPOSITION, FILM, OPTICAL LENS, DIFFRACTIVE OPTICAL ELEMENT, ION CONDUCTIVE MEMBRANE, BATTERY SEPARATOR FILM, SECONDARY BATTERY, CIRCUIT BOARD, AND DIAPHRAGM
The present disclosure provides a resin composition containing an aromatic polyamide and/or an aromatic polyamic acid.
FUNCTIONALIZED MAIN CHAIN POLYMERS
A non crosslinked, covalently crosslinked and/or ionically crosslinked polymer, having repeating units of the general formula (1)
KR(1)
In which K is a bond, oxygen, sulfur,
##STR00001##
the radical R is a divalent radical of an aromatic or heteroaromatic compound.
Ion exchange membrane
An ion exchange membrane is provided. The ion exchange membrane includes a reaction product of a polymer and a cross-linking reagent. The polymer includes a first repeat unit, and a second repeat unit. In particular, the first repeat unit is ##STR00001##
and, the second repeat unit is ##STR00002##
wherein R.sup.+ is ##STR00003##
A.sup. is F.sup., Cl.sup., Br.sup., I.sup., OH.sup., HCO.sub.3.sup., HSO.sub.4.sup., SbF.sub.6.sup., BF.sub.4.sup., H.sub.2PO.sub.4.sup., H.sub.2PO.sub.3.sup., or H.sub.2PO.sub.2.sup.; X is CH.sub.2
.sub.iY
CH.sub.2
.sub.j, i and j are independently 0, or an integer from 1 to 4; Y is O, S, CH.sub.2, or NH; R.sup.1 is independently C.sub.1-8 alkyl group; and, R.sup.2 and R.sup.3 are hydrogen, or independently C.sub.1-8 alkyl group; and, the cross-linking reagent is a compound having at least two imide groups.
POLYMER ELECTROLYTE MATERIAL, POLYMER ELECTROLYTE MOLDED PRODUCT USING THE POLYMER ELECTROLYTE MATERIAL AND METHOD FOR MANUFACTURING THE POLYMER ELECTROLYTE MOLDED PRODUCT, MEMBRANE ELECTRODE COMPOSITE, AND SOLID POLYMER FUEL CELL
It is an object of the present invention to provide a polymer electrolyte material which has excellent proton conductivity even under the conditions of a low humidity or a low temperature and is excellent in mechanical strength and fuel barrier properties, and which moreover can achieve high output, high energy density and long-term durability in forming a polymer electrolyte fuel cell therefrom, and a polymer electrolyte form article using the same and a method for producing the same, a membrane electrode assembly and a polymer electrolyte fuel cell, each using the same.
The present invention employs the following means. Namely, the polymer electrolyte material of the present invention is a polymer electrolyte material including a constituent unit (A1) containing an ionic group and a constituent unit (A2) substantially not containing an ionic group, wherein a phase separation structure is observed by a transmission electron microscope and a crystallization heat measured by differential scanning calorimetry is 0.1 J/g or more, or a phase separation structure is observed by a transmission electron microscope and the degree of crystallinity measured by wide angle X-ray diffraction is 0.5% or more. Also, the polymer electrolyte form article, the membrane electrode assembly and the polymer electrolyte fuel cell of the present invention are characterized by being composed of such polymer electrolyte materials.
NANOCOMPOSITE MEMBRANE COMPRISING POLYHEDRAL OLIGOMERIC SILSESQUIOXANE HAVING SULFONIC ACID GROUPS AND METHOD FOR MANUFACTURING THE SAME
The present invention relates to a sulfonated polyetheretherketone (sPEEK) nanocomposite film containing silsesquioxane and exhibiting excellent proton conductivity and mechanical strength, and a method for manufacturing the same. The nanocomposite film of the present invention has excellent conductivity since multiple sulfonic acid groups as a proton source exist in POSS used as a filler. In addition, the POSS used in the present invention is very small, having a size of 1-2 nm, and thus hardly obstructs the migration of protons in the ion channel in the polymer membrane, thereby realizing excellent proton conductivity. In addition, the proton conductive nanocomposite film by the present invention shows excellent mechanical strength even though the degree of sulfonation of sulfonated polyetheretherketone is increased.
POLY(PHENYLENE)-BASED ANION EXCHANGE POLYMERS AND METHODS THEREOF
The present invention relates to anionic exchange polymers including a poly(phenylene) structure. The structure can include any useful cationic moiety. Methods and uses of such structures and polymers are also described herein. In one instance, such polymers are employed to form a solid membrane.