A cellulose ester composition is provided comprising at least one cellulose ester and at least one impact modifier and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

An injection molded article comprising a thin-walled body portion formed from a polymer-based resin derived from cellulose, wherein the thin-walled body portion comprises: i. a gate position; ii. a last fill position; iii. a flow length to wall thickness ratio greater than or equal to 100, wherein the flow length is measured from the gate position to the last fill position; and iv. a wall thickness less than or equal to about 2 mm; and wherein the polymer-based resin has an HDT or at least 95 C., a bio-derived content of at least 20 wt %, and a spiral flow length of at least 3.0 cm, when the polymer-based resin is molded with a spiral flow mold with the conditions of a barrel temperature of 238 C., a melt temperature of 246 C., a molding pressure of 13.8 MPa, a mold thickness of 0.8 mm, and a mold width of 12.7 mm.

An injection molded article comprising a thin-walled body portion formed from a polymer-based resin derived from cellulose, wherein the thin-walled body portion comprises: i. a gate position; ii. a last fill position; iii. a flow length to wall thickness ratio greater than or equal to 100, wherein the flow length is measured from the gate position to the last fill position; and iv. a wall thickness less than or equal to about 2 mm; and wherein the polymer-based resin has an HDT or at least 95 C., a bio-derived content of at least 20 wt %, and a spiral flow length of at least 3.0 cm, when the polymer-based resin is molded with a spiral flow mold with the conditions of a barrel temperature of 238 C., a melt temperature of 246 C., a molding pressure of 13.8 MPa, a mold thickness of 0.8 mm, and a mold width of 12.7 mm.

A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has an HDT of at least 95 C., a bio-derived content of at least 20 wt %, a notched izod impact strength of greater than 80 J/m and at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa; a spiral flow length or at least 3.0 cm; a flex creep deflection of less than 12 mm; a transmission of at least 70%; a E value of less than 25; or an L* color of at least 85.

A shaped article comprising a polymer-based resin derived from cellulose, wherein the polymer-based resin has an HDT of at least 95 C., a bio-derived content of at least 20 wt %, a notched izod impact strength of greater than 80 J/m and at least one of the following properties chosen from: flexural modulus of greater than 1900 MPa; a spiral flow length or at least 3.0 cm; a flex creep deflection of less than 12 mm; a transmission of at least 70%; a E value of less than 25; or an L* color of at least 85.

A cellulose ester composition is provided comprising at least one cellulose ester and at least one impact modifier and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

A cellulose ester composition is provided comprising at least one cellulose ester and at least one impact modifier and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

A cellulose ester composition with heat distortion temperatures greater than 90 C. is provided comprising at least one cellulose ester and optionally at least one plasticizer. The cellulose ester compositions are useful for making articles such as eyeglass frames, automotive parts, and toys are also provided.

A cellulose ester composition with heat distortion temperatures greater than 90 C. is provided comprising at least one cellulose ester and optionally at least one plasticizer. The cellulose ester compositions are useful for making articles such as eyeglass frames, automotive parts, and toys are also provided.

The present application discloses cellulose ester compositions that are plasticizer free that can be processed at higher temperatures with reduced degradation. The cellulose ester compositions disclosed are useful for the preparation of articles, for example eyeglass frames, automotive parts, and toys.