Patent classifications
C08K5/523
Transparent Polyimide Film and Production Method Therefor
The present invention relates to a transparent polyimide film containing a polyimide and a phosphate ester. The content of the phosphate ester based on 100 parts by mass of the polyimide is 3 parts by mass or more, preferably 5 to 100 parts by mass. It is preferable to use a phosphate ester that has a high birefringence reduction effect and with which a decrease in the tensile modulus of the film is small. In production of the polyimide film, it is preferable to employ a method in which: a solvent-soluble polyimide resin and a phosphate ester are dissolved in an organic solvent exhibiting solubility with respect to the polyimide resin to prepare a polyimide solution; the polyimide solution is applied onto a substrate; and the organic solvent is removed.
HIGHLY ELASTIC AND HEAT-RESISTANT POLYIMIDE FILM AND METHOD FOR PRODUCING SAME
Disclosed herein are a highly thick polyimide film that contains a reduced number of bubbles therein and exhibits high elasticity and high heat resistance, and a manufacturing method therefor. The polyimide film is obtained by imidizing a poly(amic acid) solution containing an acid dianhydride component including 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA), and pyromellitic dianhydride (PMDA), and a diamine component including 4,4′-oxydianiline (ODA), para-phenylenediamine (p-phenylenediamine, PPD), and 3,5-diaminobenzoic acid (DABA), and contains a phosphorus (P)-based compound.
HIGHLY ELASTIC AND HEAT-RESISTANT POLYIMIDE FILM AND METHOD FOR PRODUCING SAME
Disclosed herein are a highly thick polyimide film that contains a reduced number of bubbles therein and exhibits high elasticity and high heat resistance, and a manufacturing method therefor. The polyimide film is obtained by imidizing a poly(amic acid) solution containing an acid dianhydride component including 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA), and pyromellitic dianhydride (PMDA), and a diamine component including 4,4′-oxydianiline (ODA), para-phenylenediamine (p-phenylenediamine, PPD), and 3,5-diaminobenzoic acid (DABA), and contains a phosphorus (P)-based compound.
FIBER-REINFORCED RESIN MOLDING MATERIAL, FIBER-REINFORCED RESIN MOLDED ARTICLE, AND METHOD OF MANUFACTURING FIBER-REINFORCED RESIN MOLDED ARTICLE
A fiber-reinforced resin molding material includes at least components (A) to (D), wherein the fiber-reinforced resin molding material has a weight loss on heating, when heated at 300° C. for 10 minutes either in a nitrogen atmosphere or in an air atmosphere, of 1.5% or less, and components (A) to (D) are:
(A) an amorphous thermoplastic resin: 100 parts by weight
(B) a reinforcement fiber: 4 to 60 parts by weight
(C) a phosphorus-based flame retardant: 20 to 60 parts by weight
(D) an antioxidant (D): 1.0% by weight or more.
FIBER-REINFORCED RESIN MOLDING MATERIAL, FIBER-REINFORCED RESIN MOLDED ARTICLE, AND METHOD OF MANUFACTURING FIBER-REINFORCED RESIN MOLDED ARTICLE
A fiber-reinforced resin molding material includes at least components (A) to (D), wherein the fiber-reinforced resin molding material has a weight loss on heating, when heated at 300° C. for 10 minutes either in a nitrogen atmosphere or in an air atmosphere, of 1.5% or less, and components (A) to (D) are:
(A) an amorphous thermoplastic resin: 100 parts by weight
(B) a reinforcement fiber: 4 to 60 parts by weight
(C) a phosphorus-based flame retardant: 20 to 60 parts by weight
(D) an antioxidant (D): 1.0% by weight or more.
Highly flame-retardant organically modified nanoparticle, organic-inorganic composite synthetic resin containing the same and processed product thereof
Proposed are an organic-inorganic composite synthetic resin using a highly flame-retardant organically modified nanoparticle, and a production method thereof. The method for producing the organic-inorganic composite synthetic resin using a highly flame-retardant organically modified nanoparticle includes the steps of: adding and stirring metal ion-based phosphinate, melamine cyanurate, and nanoclay to a container containing an aqueous or oily solvent, applying ultrasonic waves and high pressure energy to the stirred solution to prepare a highly flame-retardant organically modified silicate solution through a chemical bonding, and then adding a synthetic resin to form synthetic leather and foam used as life consumer goods to the silicate solution, processing and drying it.
Highly flame-retardant organically modified nanoparticle, organic-inorganic composite synthetic resin containing the same and processed product thereof
Proposed are an organic-inorganic composite synthetic resin using a highly flame-retardant organically modified nanoparticle, and a production method thereof. The method for producing the organic-inorganic composite synthetic resin using a highly flame-retardant organically modified nanoparticle includes the steps of: adding and stirring metal ion-based phosphinate, melamine cyanurate, and nanoclay to a container containing an aqueous or oily solvent, applying ultrasonic waves and high pressure energy to the stirred solution to prepare a highly flame-retardant organically modified silicate solution through a chemical bonding, and then adding a synthetic resin to form synthetic leather and foam used as life consumer goods to the silicate solution, processing and drying it.
THERMALLY-CONDUCTIVE STRUCTURAL ADHESIVE FOR NEW ENERGY POWER BATTERY AND METHOD OF PREPARING SAME
A thermally-conductive structural adhesive for new energy power batteries, including: composition A including 3.3-14 wt. % of a block polymerized telechelic carboxyl compound and/or a block polymerized telechelic amino compound; 0.1-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3.0 wt. % of a flame retardant agent; and composition B including 3.3-14 wt. % of a block polymerized telechelic isocyanate compound and/or a block polymerized telechelic epoxy compound; 0-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of a curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3 wt. % of a flame retardant agent. The composition A and the composition B are mixed evenly in a weight or volume ratio of 1:(0.25-2) and cured to obtain the thermally-conductive structural adhesive. A preparation of the thermally-conductive structural adhesive is also provided.
RESIN COMPOSITION AND PRODUCTION METHOD OF SAME
Provided is a resin composition for injection molding including a polyolefin resin, containing: at least one selected from the group consisting of aluminum hydroxide, magnesium hydroxide and a phosphorus compound in an amount of 10 to 60 mass %; a NOR-type hindered amine compound in an amount of 0.05 to 5 mass %; and a fibrous filler having an aspect ratio of 10 or more in an amount of 1 to 20 mass %, respectively, relative to the total amount of the resin composition, wherein a phosphorous content is 5 mass % or less relative to the total amount of the resin composition.
RESIN COMPOSITION AND PRODUCTION METHOD OF SAME
Provided is a resin composition for injection molding including a polyolefin resin, containing: at least one selected from the group consisting of aluminum hydroxide, magnesium hydroxide and a phosphorus compound in an amount of 10 to 60 mass %; a NOR-type hindered amine compound in an amount of 0.05 to 5 mass %; and a fibrous filler having an aspect ratio of 10 or more in an amount of 1 to 20 mass %, respectively, relative to the total amount of the resin composition, wherein a phosphorous content is 5 mass % or less relative to the total amount of the resin composition.