The present invention relates to the use of NOR-HALS compounds in flame retardant polymer compositions. These compositions are especially useful for the manufacture of flame retardant compositions based on thermoplastic polymers, especially polyolefin homo- and copolymers, polycondensates, such as polyamines or polyesters and duro-plastic polymers, such as polyepoxides.

A limonene-based flame-retardant compound, a method of making a flame-retardant polymer, and an article of manufacture comprising a material that includes a limonene-based flame-retardant compound. In an embodiment, the method includes forming a limonene-based derivative; forming a phosphorus-based flame-retardant molecule; reacting the limonene-based derivative with the phosphorus-based flame-retardant molecule to form a limonene-based flame-retardant compound; and forming a flame-retardant polymer from the limonene-based flame-retardant compound. In some embodiments, the limonene-based flame-retardant compound has variable functionality including vinyl, epoxide, methylene bridges, and thioethers.

A limonene-based flame-retardant compound, a method of making a flame-retardant polymer, and an article of manufacture comprising a material that includes a limonene-based flame-retardant compound. In an embodiment, the method includes forming a limonene-based derivative; forming a phosphorus-based flame-retardant molecule; reacting the limonene-based derivative with the phosphorus-based flame-retardant molecule to form a limonene-based flame-retardant compound; and forming a flame-retardant polymer from the limonene-based flame-retardant compound. In some embodiments, the limonene-based flame-retardant compound has variable functionality including vinyl, epoxide, methylene bridges, and thioethers.

The invention relates to a flame retardant (meth)acrylate composition combining an impact-resistant (meth)acrylic polymer (such as Solarkote? resin from Trinseo) with specific levels of selected organic phosphinate and selected organic phosphorous flame retardants. The composition is halogen free, with superior flame performance, flowability and impact resistance. The composition of the invention is melt-processible and can be co-extruded with a thermoplastic substrate material to obtain a multilayer structure, having a tough, impact resistant cap layer(s). The obtained multilayer structure can be further thermoformed into useful profiles and structures, such as the exterior housing of EV charging stations and car wash stations, automotive applications, aerospace, and building and construction applications.

The invention relates to a flame retardant (meth)acrylate composition combining an impact-resistant (meth)acrylic polymer (such as Solarkote? resin from Trinseo) with specific levels of selected organic phosphinate and selected organic phosphorous flame retardants. The composition is halogen free, with superior flame performance, flowability and impact resistance. The composition of the invention is melt-processible and can be co-extruded with a thermoplastic substrate material to obtain a multilayer structure, having a tough, impact resistant cap layer(s). The obtained multilayer structure can be further thermoformed into useful profiles and structures, such as the exterior housing of EV charging stations and car wash stations, automotive applications, aerospace, and building and construction applications.

A near infrared absorbing composition includes a near infrared absorber. The near infrared absorber contains at least one of Ingredient (A) and Ingredient (B). Ingredient (A) consists of a first compound having a first structure represented by General Formula (I), a second compound having a second structure represented by General Formula (II), and a copper ion. Ingredient (B) consists of a first copper complex in which the first compound is coordinated and a second copper complex in which the second compound is coordinated. In General Formula (I), R.sup.1 represents an alkyl group containing 1-20 carbons or an aryl group containing 6-20 carbons, and may further have a substituent. In General Formula (II), R.sup.2 represents an alkyl group containing 1-20 carbons or an aryl group containing 6-20 carbons, and may further have a substituent. ##STR00001##

A near infrared absorbing composition includes a near infrared absorber. The near infrared absorber contains at least one of Ingredient (A) and Ingredient (B). Ingredient (A) consists of a first compound having a first structure represented by General Formula (I), a second compound having a second structure represented by General Formula (II), and a copper ion. Ingredient (B) consists of a first copper complex in which the first compound is coordinated and a second copper complex in which the second compound is coordinated. In General Formula (I), R.sup.1 represents an alkyl group containing 1-20 carbons or an aryl group containing 6-20 carbons, and may further have a substituent. In General Formula (II), R.sup.2 represents an alkyl group containing 1-20 carbons or an aryl group containing 6-20 carbons, and may further have a substituent. ##STR00001##

The use of tetrahydrobenzoxazines I ##STR00001##
where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

The use of tetrahydrobenzoxazines I ##STR00001##
where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

A flame-retardant composition is described as comprising phosphonate oligomers or polymers of formula (I) as a component (A)

##STR00001##

an amino ether of formula (II) as a component (B)

##STR00002##

and a thermoplastic polymer as a component (C), where the components (A), (B) and (C) are as defined.