Embodiments of the present disclosure are directed to embodiments of synthetic functionalized additives. The synthetic functionalized additive may include a layered magnesium silicate. The layered magnesium silicate may include a first functionalized silicate layer including a first tetrahedral silicate layer covalently bonded to at least two different functional groups, an octahedral brucite layer, including magnesium, and a second functionalized silicate layer including a second tetrahedral silicate layer covalently bonded to at least two different functional groups. The octahedral brucite layer may be positioned between the first functionalized silicate layer and the second functionalized silicate layer. The at least two different functional groups covalently bonded to the first tetrahedral silicate layer may be the same or different than the at least two different functional groups covalently bonded to the second tetrahedral silicate layer.

A magnetic drilling mud for use in a well, the magnetic drilling mud including water; bentonite; magnetic micro-particles; and an anionic surfactant that prevents separation of the bentonite and the magnetic micro-particles in the water. The magnetic micro-particles have a diameter less than 100 μm.

A magnetic drilling mud for use in a well, the magnetic drilling mud including water; bentonite; magnetic micro-particles; and an anionic surfactant that prevents separation of the bentonite and the magnetic micro-particles in the water. The magnetic micro-particles have a diameter less than 100 μm.

A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.

A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.

The invention relates to powdered lubricants for water based drilling fluids. Conventional liquid lubricants containing particularly divalent ions have the tendency to grease out. The powdered lubricants have excellent dispersion properties and hence do not grease out, when added to the drilling mud in the concentrations, preferably of the order of about 3% or less. The powdered lubricant is a combination of inert fillers with fatty acids that are essentially free from fatty acid esters and metal soaps and have organic acids containing C10-C24 alkyl groups fatty acids. The improved lubricating properties of the drilling muds result in greatly increased life of the rotary drilling bits and marked reduction in torque required to rotate the bit. Solid powdered additives compositions greatly reduce transportation costs and simplify the logistics and environmental concerns associated with shipping large volumes of liquids and overcome the pour point issues associated with liquid additives.

The invention relates to powdered lubricants for water based drilling fluids. Conventional liquid lubricants containing particularly divalent ions have the tendency to grease out. The powdered lubricants have excellent dispersion properties and hence do not grease out, when added to the drilling mud in the concentrations, preferably of the order of about 3% or less. The powdered lubricant is a combination of inert fillers with fatty acids that are essentially free from fatty acid esters and metal soaps and have organic acids containing C10-C24 alkyl groups fatty acids. The improved lubricating properties of the drilling muds result in greatly increased life of the rotary drilling bits and marked reduction in torque required to rotate the bit. Solid powdered additives compositions greatly reduce transportation costs and simplify the logistics and environmental concerns associated with shipping large volumes of liquids and overcome the pour point issues associated with liquid additives.

A composition of matter comprises a liquid and functionalized nanoparticles suspended in the liquid. At least some of the functionalized nanoparticles comprise nanoparticles of aluminosilica and have a chemical structure of:

##STR00001##

wherein at least one of the X's represents —O— bonded to a silicon (Si) atom or an aluminum (Al) atom of the aluminosilica of at least one of the nanoparticles; each other of the X's represents an additional —O— bonded to another silicon (Si) atom or another aluminum (Al) atom of the aluminosilica of at least one of the nanoparticles, an alkoxy group, an alkyl group, a hydroxyl group (OH), a hydrogen atom, or a halide; Z represents an oxygen (O) atom or an NH group; and Q represents an epoxide group, an aziridine group, a —CH(OH)CH.sub.2OH group, a —CH(OH)CH.sub.2NH.sub.2 group, a —CH(NH).sub.2CH.sub.2OH group, or a —CH(NH.sub.2)CH.sub.2NH.sub.2 group. Methods of formation and of use are also disclosed.

A composition of matter comprises a liquid and functionalized nanoparticles suspended in the liquid. At least some of the functionalized nanoparticles comprise nanoparticles of aluminosilica and have a chemical structure of:

##STR00001##

wherein at least one of the X's represents —O— bonded to a silicon (Si) atom or an aluminum (Al) atom of the aluminosilica of at least one of the nanoparticles; each other of the X's represents an additional —O— bonded to another silicon (Si) atom or another aluminum (Al) atom of the aluminosilica of at least one of the nanoparticles, an alkoxy group, an alkyl group, a hydroxyl group (OH), a hydrogen atom, or a halide; Z represents an oxygen (O) atom or an NH group; and Q represents an epoxide group, an aziridine group, a —CH(OH)CH.sub.2OH group, a —CH(OH)CH.sub.2NH.sub.2 group, a —CH(NH).sub.2CH.sub.2OH group, or a —CH(NH.sub.2)CH.sub.2NH.sub.2 group. Methods of formation and of use are also disclosed.

A nano-organosilicon film-forming and hydrophobic shale surface hydration inhibitor is obtained by performing hydrophobic modification for nano-particles through long-chain organosilicon together with a surface-active agent. A preparation method of the said hydrophobic shale surface hydration inhibitor comprises steps as follows: nano-particles are added to the solvent under stirring conditions, and then an ultrasonic dispersion is performed; upon the end of the ultrasonic dispersion, the reaction system is adjusted to a pH of 9-11 to obtain mixed solution A; a long-chain organosilicon solution is then dropwise added to the mixed solution A for reaction under stirring conditions to obtain mixed solution B; a surface-active agent is added to the mixed solution B for reaction under stirring conditions; upon the reaction is finished, part of the solvent is removed to obtain the inhibitor.