The present disclosure relates to subterranean formation operations and, more particularly, to embedded treatment fluid additives for use in subterranean formation operations. The embedded treatment additives may comprise an aqueous-soluble downhole reactive material embedded in a crosslinked polymeric solution to delay the reactivity of the aqueous-soluble downhole reactive material, thereby forming the embedded treatment additive, wherein the aqueous-soluble downhole reactive material is a solid.

A filling material for underground treatment of the present invention contains at least one polyvinyl alcohol-based resin of a modified polyvinyl alcohol-based resin and an unmodified polyvinyl alcohol, and a swelling ratio of the polyvinyl alcohol-based resin after immersion in water at a temperature of 80° C. for 30 minutes is 250% to 900%. The filling material for underground treatment has enhanced swelling performance, is effective in preventing phenomena such as lost circulation, and has improved workability of filling a well drilled part with the filling material.

Treatment fluid compositions that include a carrier fluid, a crosslinkable polymer, one or more degradable fibers grafted with a crosslinking moiety capable of crosslinking the crosslinkable polymer, and optionally a proppant or gravel. Methods and systems for treating a subterranean wellbore or formation using the grafted degradable fiber treatment fluids are further provided. The presently disclosed treatment fluids may be suitable for use as hydraulic fracturing treatment fluids, gravel packing treatment fluids, or fluid diversion treatment fluids.

A process for consolidating sand, proppant and other suspended particles present in a subterranean reservoir using an aqueous emulsion particle consolidation system is described. Surfactants with cloud points at or below the reservoir temperature are used to make a low viscosity aqueous external emulsion system with resin and curing agent as the internal phase. As the surfactant reaches its cloud point, it loses its emulsification ability and releases the resin and curing agent to consolidate the sand. The aqueous phase of the system then functions as a spacer to maintain the permeability needed for oil and gas production without additional post flush required.

A variety of systems, methods and compositions are disclosed for delayed release of a resin curing agent. An example method may comprise introducing a treatment fluid comprising a resin and delayed release curing agent particulates into a subterranean formation, wherein the delayed release curing agent particulates comprises a carrier, a curing agent disposed on the carrier, and a coating; degrading the coating; and curing the resin in the subterranean formation.

Methods may include introducing a polymerizable composition containing a polycyclic monomer and a catalyst into a subterranean formation; and polymerizing the polymerizable composition in the presence of the catalyst in situ to form a polymer. Methods may also include lowering a wellbore tool into the subterranean formation, wherein the tool contains a first partition containing a polymerizable composition, and a second partition containing a catalyst; releasing the polymerizable composition from the first partition; releasing the catalyst from the second partition; contacting the polymerizable composition and the catalyst in a mixing region; and reacting the polymerizable composition and the catalyst in situ to form a polymer.

The present disclosure relates to subterranean formation operations and, more particularly, to embedded treatment fluid additives for use in subterranean formation operations. The embedded treatment additives may comprise an aqueous-soluble downhole reactive material embedded in a crosslinked polymeric solution to delay the reactivity of the aqueous-soluble downhole reactive material, thereby forming the embedded treatment additive, wherein the aqueous-soluble downhole reactive material is a solid.

Methods of treating a subterranean formation include obtaining or providing compositions that include an alkenoate ester. The compositions also includes at least one of a dialkenyldihydrocarbylammonium halide and an N,N-dihydrocarbyl-substituted alkenamide. The methods also include placing the composition in a subterranean formation downhole. Methods of treating a subterranean formation include using a composition including a polymer that is a reaction product of a mixture including an alkenoate ester and at least one of a dialkenyldihydrocarbylammonium halide and an N,N-dihydrocarbyl-substituted alkenamide.

A downhole fluid composition having a saccharide gelling agent, an oxidative breaker, and a sequestering agent. The sequestering agent is hydrocarbon miscible and inert to oxidation by the oxidative breaker. The sequestering agent sequesters the oxidative breaker or an activator for the oxidative breaker, whereby oxidation of the gelling agent is inhibited. The downhole fluid may also include a proppant. Upon contacting hydrocarbons downhole or reaching a predetermined temperature, the sequestering agent releases the oxidative breaker or activator thereby oxidizing the saccharide gelling agent.

The invention provides polymers comprising repeating units derived from at least one monomer comprising at least one functionalized or unfunctionalized acryloyl moiety and at least one lactam moiety; at least one monomer comprising at least one sulfonic acid moiety or a salt thereof; and at least one crosslinker. The invention further provides various compositions comprising the polymers. The invention furthermore provides applications of these compositions in various industrial arts, particularly in oilfield operations such as drilling and cementing.