A polymer-encapsulated mineral acid solution and a method for forming the polymer-encapsulated mineral acid solution. Introducing a strong mineral acid solution to a monomer solution occurs such that a primary emulsion that is a water-in-oil type emulsion forms. Introducing the primary emulsion to a second aqueous solution forms a secondary emulsion that is a water-in-oil-in-water type double emulsion. The monomer in the secondary emulsion is cured such a polymerized shell forms that encapsulates the strong mineral acid solution and forms the capsule. The strong mineral acid solution has up to 30 wt. % strong mineral acid. A method of stimulating a hydrocarbon-bearing formation using the polymer-encapsulated mineral acid solution includes introducing a capsule suspension into a fissure in the hydrocarbon-bearing formation to be stimulated through a face in a well bore. The capsule is maintained within the fissure until the polymer shell degrades.

A polymer-encapsulated mineral acid solution and a method for forming the polymer-encapsulated mineral acid solution. Introducing a strong mineral acid solution to a monomer solution occurs such that a primary emulsion that is a water-in-oil type emulsion forms. Introducing the primary emulsion to a second aqueous solution forms a secondary emulsion that is a water-in-oil-in-water type double emulsion. The monomer in the secondary emulsion is cured such a polymerized shell forms that encapsulates the strong mineral acid solution and forms the capsule. The strong mineral acid solution has up to 30 wt. % strong mineral acid. A method of stimulating a hydrocarbon-bearing formation using the polymer-encapsulated mineral acid solution includes introducing a capsule suspension into a fissure in the hydrocarbon-bearing formation to be stimulated through a face in a well bore. The capsule is maintained within the fissure until the polymer shell degrades.

Process for producing aqueous polyacrylamide solutions by polymerizing an aqueous solution comprising at least acrylamide thereby obtaining an aqueous polyacrylamide gel and dissolving said aqueous polyacrylamide gel in water, wherein the process is carried out in a modular, relocatable plant. The plant preferably is deployed at a location at which aqueous polyacrylamide solutions are used, for example on an oilfield or in a mining area.

In wellbore servicing fluids and methods related thereto a Pickering emulsion is produced by mixing silica, an oleaginous fluid, an aqueous base fluid and an emulsifier. The silica can comprise a silica dust and larger proppant particles that work together to form a Pickering emulsion with the proppant particles suspended therein. In some embodiments, the proppant particles are a silica sand.

Methods for breaking polymer-containing treatment fluids for use in subterranean formations are provided. In one or more embodiments, the methods include providing a treatment fluid comprising a base fluid and a polymer, wherein the treatment fluid was recovered from at least a portion of a subterranean formation located at a wellsite; transporting the treatment fluid from the wellsite to an off-site location; and applying a cavitation technique to at least a portion of the treatment fluid at the off-site location.

Methods for removing polymers from treatment fluids for use in subterranean formations are provided. In one or more embodiments, the methods include providing a treatment fluid comprising an aqueous base fluid and a polymer comprising polyvinylpyrrolidone or a derivative thereof; and adding a precipitant to the treatment fluid to form a precipitate with at least a portion of the polymer.

Methods for treating subterranean formations by diverting treatment fluids therein are provided. In one embodiment, the methods comprise: introducing a first diverter material comprising polyvinyl alcohol and a plasticizer into or adjacent to a permeable zone of a subterranean formation; introducing a second diverter material into or adjacent to the permeable zone of the subterranean formation, wherein at least a portion of the first diverter material comprises particles larger than particles of the second diverter material; and allowing the first diverter material and the second diverter material to at least partially divert at least a portion of a treatment fluid to a different portion of the subterranean formation.

Methods of treating a subterranean formation are described. The methods include introducing a treatment fluid that includes a friction reducing polymer (e.g., a cationic friction reducing polymer or an anionic friction reducing polymer) into the subterranean formation. The cationic friction reducing polymer is allowed to degrade and release choline chloride or polyDADMAC, which can each act as a clay stabilizer. The anionic friction reducing polymer is allowed to degrade and release AMPS, which can act as a surfactant, a scale inhibitor, a paraffin inhibitor, or an asphaltene inhibitor, or polyacrylic acid, which can act as a scale inhibitor.

A method, comprising contacting a proppant, water, and a water external emulsion to form a mixture, wherein the water external emulsion has an organic internal phase comprising a surface modifying agent; contacting the mixture with an emulsion breaker to form a wellbore servicing fluid comprising a proppant coated with the surface modifying agent; an placing the wellbore servicing fluid in a wellbore penetrating a subterranean formation. A method comprising contacting a proppant, water, and a water external emulsion to form a first mixture, wherein the water external emulsion has an organic internal phase comprising a surface modifying agent; contacting the first mixture with an emulsion breaker to form second mixture comprising a proppant coated with the surface modifying agent; and recovering a coated proppant from the second mixture.

A structural stabilizer for a fiber and proppant complex to enhance proppant migration and placement in a fractured well during propping and a preparation method thereof are provided. The structural stabilizer consists of: water, inorganic salt, kaolinite, nitrogen-doped modified graphene oxide, anionic surfactant, non-ionic alkyl polyglucoside, and polyacrylamide. The structural stabilizer improves bonding between a proppant and a fiber when slick water is used in stimulated reservoir volume (SRV) fracturing, prevents separation of the fiber and the proppant during migration, thereby reducing escape rate of the fiber from the fiber and proppant complex.