C09K8/887

Formulations comprising recovered water and a viscosifier and associated methods

High viscosity fracturing fluids for fracturing a subterranean formulation are prepared by: (i) selecting recovered water; (ii) contacting said recovered water with a viscosifying agent, wherein said viscosifying agent is selected from fenugreek gum, tara gum, locust bean gum, guar gum and derivatives of the aforesaid; (iii) contacting said recovered water with one or more other additives for example with a cross-linking agent (A) for cross-linking said viscosifying agent, wherein contact of said recovered water with cross-linking agent (A) takes place when the pH of said recovered water is less than pH 6.5; (iv) adjusting the pH to pH 6.5-8.8.

POLYMER BLENDS FOR STIMULATION OF OIL & GAS WELLS

Compositions and methods for fracturing a subterranean formation are presented. Also provided are compositions and methods for reducing friction-related losses in a well treatment fluid. In general, the compositions include a copolymer that includes one or more vinylphosphonic acid (VPA) monomers.

Additives to minimize viscosity reduction for guar/borate system under high pressure

A composition for use as a pressure-tolerant dual-crosslinker gel in a fracturing fluid that comprises polymer, the polymer operable to increase the viscosity of a fluid; boron-containing crosslinker, the boron-containing crosslinker operable to crosslink the polymer; and a transition metal oxide additive, the transition metal oxide additive operable to crosslink the polymer.

Enzyme-Encapsulated Hydrogel Nanoparticles for Hydraulic Fracturing Fluid Cleanup
20210009891 · 2021-01-14 · ·

Provided herein is a hydraulic fracturing fluid containing enzyme encapsulated hydrogel nanoparticles and a breaker composition of a viscosifier-degrading enzyme encapsulated in the hydrogel nanoparticle. Also provided are methods for hydraulic fracturing utilizing hydrogel nanoparticles encapsulating an enzyme as a breaker to prevent the premature degradation of the fracturing fluid, to improve transport and placement of the proppant and to facilitate subsequent cleaning of the fracturing fluid.

Self-breakable treatment fluids for use in subterranean formation operations

Treatment fluids comprising an aqueous base fluid and a gelling agent of selected from the group consisting of hydroxypropyl starch phosphate, a hydroxypropyl starch phosphate derivative, and any combination thereof. The treatment fluids may be used to perform subterranean formation operations, such as fracturing operations and proppant particulate placement operations. The treatment fluids are self-breakable and provide viscosity for proppant particulate suspension without the use of breakers or crosslinkers.

Rheology modifier

The composition provided herein includes an aqueous base fluid, a water-based polymer and glass microspheres comprising a metal cross-linking agent and where the water-based polymer cross-links in the presence of the glass microspheres.

Compositions and methods for cross-linking hydratable polymers using produced water

Fracturing fluid compositions including a base fluid including a high TDS produced and/or flow back water, brackish water, RO reject water, clear brine, and mixtures thereof with or without added fresh water and systems, and methods for making and using same, where the method includes: (a) adding a first buffer to adjust the pH of a base fluid to an acidic pH, (b) adding a hydratable polymer or polymer slurry to the base fluid to form a hydratable polymer fracturing fluid, (c) adding a cross-linking composition to the hydratable polymer fracturing fluid to form a pre-cross-linked fracturing fluid, and (d) if needed, adding a second buffer to the pre-cross-linked fracturing fluid to adjust the pH of the pre-cross-linked fracturing fluid to form a viscosified fracturing fluid having a crosslinked structure.

ENHANCED PROPPANT TRANSPORT FOR HYDRAULIC FRACTURING

The present disclosure relates to compositions and methods for recovery of hydrocarbons from subterranean formations. The compositions may be dry blends of synthetic and naturally derived polymers. The blend compositions may also be produced as high activity solvent-based fluidized polymer suspensions. Either in dry or liquid forms, the blend compositions provide higher proppant carrying capacity in comparison to conventional solutions, as well as improved breakability and crosslinking capacity.

CROSSLINKABLE FRICTION REDUCER
20200392397 · 2020-12-17 ·

The present invention relates to the use of a water soluble synthetic copolymer comprising acrylamide monomer units and additionally monomer units bearing phosphonic groups, said copolymer having not more than 5 wt.-% of monomer units containing carboxylic groups, as friction reducer for subterranean treatment and said water soluble synthetic copolymer being cross-linkable using polyvalent cations.

Enhanced high temperature crosslinked fracturing fluids
10865342 · 2020-12-15 · ·

A fracturing fluid including a mixture of an aqueous terpolymer composition including a terpolymer, an additive, and crosslinker. The terpolymer includes 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or a salt thereof. The additive includes a sugar alcohol or a derivative thereof, and the crosslinker includes a metal. The weight ratio of the metal to the terpolymer is in a range of 0.01 to 0.16, and a concentration of the additive is in a range of 0.001 wt. % to 10 wt. % of the fracturing fluid. Treating a subterranean formation includes introducing the fracturing fluid into a subterranean formation, and crosslinking the fracturing fluid in the subterranean formation to yield a crosslinked fracturing fluid. The crosslinked fracturing fluid mitigates damage caused by substantial amounts of total dissolved solids or significant water hardness.