A method for preventing or reducing engine knock or pre-ignition in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition comprising at least one ester of a non-aromatic dicarboxylic acid. The at least one ester of a non-aromatic dicarboxylic acid preferably comprises at least one adipate ester (e.g., dialkyl adipate ester). A lubricating engine oil having a composition comprising at least one ester of a non-aromatic dicarboxylic acid (e.g., adipate ester). A fuel additive composition for use in a gasoline fuel composition or a diesel fuel composition. The gasoline fuel composition or the diesel fuel composition is used in a spark ignition internal combustion engine. The fuel additive composition comprises at least one ester of a non-aromatic dicarboxylic acid (e.g., adipate ester). The lubricating oils of this disclosure are particularly advantageous as passenger vehicle engine oil products.

The present disclosure provides fuel additives including Mannich detergent additive(s) and succinimide detergent additive(s) effective to improve engine performance in both port fuel injected and gasoline direct injection engines.

The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds.

In certain embodiments, a vegetable oil-based diester (1,6-hexyldioleate) was branched with propanoic acid (C3) using a green synthetic approach involving solvent-free and catalyst-free epoxide ring opening followed by in situ normal esterification. A total of three branched ester derivatives possessing varied numbers of internal protruding branched ester groups and hydroxyl groups were obtained. All of the pure branched derivatives were comprised of mixtures of positional isomers and/or stereoisomers. Differential scanning calorimetry (DSC) showed that regardless of the composition inhomogeneity of each branched derivative, crystallization was suppressed completely in all of the branched compounds, and they all demonstrated glass transitions below 65 C.

Without being bound by any theory, it is believed that this unique thermal behavior is attributed to the internal protruding branched moieties and hydroxyl groups, which dramatically slowed down mass transfer starting with the least branched compound (2-branched derivative). The viscosity of the branched compounds was one order of magnitude larger than that of the starting di ester due to the increased branching and increased resistance to flow associated with hydrogen bonding introduced by the OH groups. Overall, these branched diesters demonstrated superior low temperature and flow properties comparable to existing non-sustainable commercial lubricants and analogous biobased materials which makes them suitable alternatives for use in lubricant formulations particularly in high performance industrial gear and bearing lubricants.

The present disclosure provides a diesel fuel composition containing DMC and multifunctional additives to reduce particulate emission, improve efficiency and be used in cold and/or hypoxia conditions.

A liquid fuel composition comprising a base fuel suitable for use in an internal combustion engine; one or more organic UV filter compounds; and one or more ester co-additive compounds provides improvements in terms of stability properties in an additive blend containing said one or more organic UV filter compounds and said one or more ester co-additive compounds, particularly at low temperatures, such as temperatures of 5 C. or lower.

Oil compositions derived from transgenic soybeans having a high concentration of oleic acid are described for use in various applications including use to enhance the low temperature pour characteristics of engine fluids. Such oil compositions are useful as lubricants, rail curve grease and engine penetrants.

A fuel composition comprising as an additive the reaction product of a polycarboxylic acid compound of formula (I): (I) or an anhydride thereof; and an alcohol having at least 5 carbon atoms; wherein each of n and m may be 0 or a positive integer. ##STR00001##

A method for the continuous production of an improved diesel fuel, having enhanced ignition characteristics, more particularly with a greater electric conductivity, enhanced cetane numbers and lubricity and with greater percentage of complete combustion, resulting in less soot production and NOx reduction at the same time in an internal combustion diesel engine, breaking the tradeoff in the emission of those two pollutants from an internal combustion diesel engine.

A lubricity improver composition for fuel oil composition contains a dicarboxylic acid monoester represented by the formula (I) as component A, and a C.sub.8-24 long-chain fatty acid, its polyol ester or a mixture thereof as component B. The total amount of component A and component B is 70-100 wt %, based on the total weight of the composition. The mass ratio of component A to component B is 9:1 to 1:9.

A fuel composition comprising as an additive the reaction product of a polycarboxylic acid having no more than 5 carbon atoms per carboxylic acid group, or an anhydride thereof and an alcohol having at least 5 carbon atoms.