The invention relates to a process for the oxidation of carbon-containing organic compounds where the said compounds have at least one bond with a bond order >1, wherein an oxidizing of these carbon-containing organic compounds to be oxidized is performed with electrochemically generated C—O—O oxidizing agents, in particular peroxodicarbonate. Also described is the use of C—O—O oxidizing agents generated electrochemically from carbonate, in particular peroxodicarbonate, as oxidizing agents for the oxidation of carbon-containing organic compounds, in particular carbon-containing organic compounds where the said compounds have at least one bond with a bond order >1. Finally, an arrangement for the oxidation of carbon-containing organic compounds is provided, comprising a first unit for the electrochemical preparation of C—O—O oxidizing agents generated electrochemically from carbonate, in particular peroxodicarbonate, and a second unit for the oxidizing of the carbon-containing organic compound with the C—O—O oxidizing agent generated electrochemically from carbonate, in particular peroxodicarbonate. In this case, these two units are connected to one another in such a way that an ex situ generated oxidizing agent can be fed to the second unit.

The present application discloses a photoelectrode and a preparation method therefor, and a Pt-based alloy catalyst and a preparation method therefor. The method for preparing the Pt-based nano-alloy catalyst includes: placing a photoelectrode in an electrolytic cell with at least one light-transmitting surface and including an electrolyte; using a light source to irradiate a surface of the photoelectrode from the light-transmitting surface of the electrolytic cell, where the photoelectrode includes an active metal layer, a passivation layer, a semiconductor light absorption layer, a rear conductive layer, and an insulating protective layer that are sequentially stacked along the light incident direction; based on an electrochemical workstation and light irradiation, using a Pt electrode and a reference electrode to match the photoelectrode to electrochemically treat the surface of the photoelectrode; and cleaning the electrochemically-treated photoelectrode to obtain the Pt-based nano-alloy catalyst and a photoelectrode modified by the Pt-based nano-alloy catalyst.

The present application discloses a photoelectrode and a preparation method therefor, and a Pt-based alloy catalyst and a preparation method therefor. The method for preparing the Pt-based nano-alloy catalyst includes: placing a photoelectrode in an electrolytic cell with at least one light-transmitting surface and including an electrolyte; using a light source to irradiate a surface of the photoelectrode from the light-transmitting surface of the electrolytic cell, where the photoelectrode includes an active metal layer, a passivation layer, a semiconductor light absorption layer, a rear conductive layer, and an insulating protective layer that are sequentially stacked along the light incident direction; based on an electrochemical workstation and light irradiation, using a Pt electrode and a reference electrode to match the photoelectrode to electrochemically treat the surface of the photoelectrode; and cleaning the electrochemically-treated photoelectrode to obtain the Pt-based nano-alloy catalyst and a photoelectrode modified by the Pt-based nano-alloy catalyst.

An electrolytic ozone cell that a housing that includes an interfacial seal, a top plate, and bottom plate. The electrolytic ozone cell also includes an internal compartment that having a pair of contact plates, and a tolerance compressor. The tolerance compressor compresses an electrode-membrane-electrode stack that is disposed between the pair of contact plates and the tolerance compressor alters its shape in order to maintain compressive forces on the electrode-membrane-electrode stack.

An electrolytic ozone cell that a housing that includes an interfacial seal, a top plate, and bottom plate. The electrolytic ozone cell also includes an internal compartment that having a pair of contact plates, and a tolerance compressor. The tolerance compressor compresses an electrode-membrane-electrode stack that is disposed between the pair of contact plates and the tolerance compressor alters its shape in order to maintain compressive forces on the electrode-membrane-electrode stack.

The invention is directed to a process for electrochemically converting a reactant gas, to an electrolyser, to a gas diffusion electrode, to a method for producing a gas diffusion electrode, to a gas diffusion layer, and to the use of said gas diffusion layer and/or gas diffusion electrode.

The process comprises reacting a reactant gas at a gas diffusion electrode to form a product gas and/or a liquid product,

wherein the gas diffusion electrode comprises a gas diffusion layer comprising a non-porous layer that is permeable to carbon monoxide and/or carbon dioxide gas, and a porous layer, and
the reactant gas comprises carbon monoxide and/or carbon dioxide.

An electrocatalyst comprising (i) carbon nanospikes and (ii) copper alloy nanoparticles containing copper and at least one noble metal and residing on and/or between the carbon nanospikes. Also disclosed herein is a method of producing the electrocatalyst. Also described herein is a method for converting carbon dioxide into hydrocarbons by use of the above-described electrocatalyst. The method for producing hydrocarbons more specifically involves contacting the electrocatalyst with an aqueous solution of a bicarbonate salt while the aqueous solution is in contact with a source of carbon dioxide, and electrically powering the electrocatalyst as a cathode at negative potential condition while the cathode is in electrical communication with a counter electrode electrically powered as an anode, to convert the carbon dioxide into hydrocarbons containing at least four carbon atoms and composed of only carbon and hydrogen.

An electrode having an embedded charge contains a substrate, a first electronic charge trap defined at the interface of a first insulating layer and a second insulating layer; and a first conductive layer disposed on the first electronic charge trap; wherein the first conductive layer contains a conductive material configured to permit an external electric field to penetrate the electrode from the first electronic charge trap; and wherein the first insulating layer is not the same as the second insulating layer.

A process provides an unlimited source of ammonia, for primary use as a liquid disinfectant for application directly to human hands or to hand wipes, by combining a carbon nanospike catalyst with a copper catalyst, carbon dioxide, water and water vapor in an electrochemical process initiated by a power source. And a process for making urea by addition of carbon dioxide. Further, an improved process provides for making the carbon nanospike, through injection with photons and electromagnetic waves.

A process provides an unlimited source of ethanol, for primary use as a liquid disinfectant for application directly to human hands or to hand wipes, by combining a carbon nanospike catalyst with a copper catalyst, carbon dioxide, water and water vapor, and injection of photons and electromagnetic waves, in an electrochemical process initiated by a power source. The process also provides an unlimited source for hydrogen peroxide and ammonia. Further, the application provides an improved process for making the carbon nanospike, through injection with photons and electromagnetic waves.