Provided are a photocatalyst, a method for preparing the same, and a water splitting apparatus including the same. Without using an additional device, a photoelectrode with improved current density may be obtained through visible light absorption using the upconversion.

Provided are a photocatalyst, a method for preparing the same, and a water splitting apparatus including the same. Without using an additional device, a photoelectrode with improved current density may be obtained through visible light absorption using the upconversion.

A device for performing electrolysis of water is disclosed. The device may include a semiconductor structure with a surface and an electron guiding layer below said surface, the electron guiding layer of the semiconductor structure being configured to guide electron movement in a plane parallel to the surface. The electron guiding layer of the semiconductor structure may include an InGaN quantum well or a heterojunction, the heterojunction being a junction between AlN material and GaN material or between AlGaN material and GaN material and at least one metal cathode arranged on the surface of the semiconductor structure. The device may further include at least one photoanode arranged on the surface of the semiconductor structure, wherein the at least one photoanode may include a plurality of quantum dots of In.sub.xGa.sub.(1-x)N material, wherein 0.4≤x≤1. A system including such a device is also disclosed.

A CaTiO.sub.3—TiO.sub.2 composite electrode and method of making is described. The composite electrode comprises a substrate with an average 2-12 μm thick layer of CaTiO.sub.3—TiO.sub.2 composite particles having average diameters of 0.2-2.2 μm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a calcium complex, and a titanium complex. The CaTiO.sub.3—TiO.sub.2 composite electrode is capable of being used in a photoelectrochemical cell for water splitting.

A CaTiO.sub.3—TiO.sub.2 composite electrode and method of making is described. The composite electrode comprises a substrate with an average 2-12 μm thick layer of CaTiO.sub.3—TiO.sub.2 composite particles having average diameters of 0.2-2.2 μm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a calcium complex, and a titanium complex. The CaTiO.sub.3—TiO.sub.2 composite electrode is capable of being used in a photoelectrochemical cell for water splitting.

A method of preparing bismuth vanadate particles is described. The bismuth vanadate particles prepared via ultrasonication and hydrothermal treatment exhibit controlled morphology (e.g., octahedral shape) and crystallinity (e.g., tetragonal crystal symmetry). A photoelectrode containing bismuth vanadate particles and a method of using the photoelectrode in a photoelectrochemical cell for water splitting is also provided.

A method of preparing bismuth vanadate particles is described. The bismuth vanadate particles prepared via ultrasonication and hydrothermal treatment exhibit controlled morphology (e.g., octahedral shape) and crystallinity (e.g., tetragonal crystal symmetry). A photoelectrode containing bismuth vanadate particles and a method of using the photoelectrode in a photoelectrochemical cell for water splitting is also provided.

The present disclosure relates to a carbon dioxide capture device comprising a first reactor and a second reactor both of which show a (photo)anode containing or connected to oxygen evolution and/or carbon dioxide evolution catalyst(s) and a (photo)cathode containing or connected to an oxygen reduction catalyst, wherein the first reactor comprises an anion exchange membrane placed between the porous (photo)anode and porous (photo)cathode, and the second reactor comprises a proton exchange membrane placed between the porous (photo)anode and porous (photo)cathode. On the porous (photo)cathode side of the first reactor there is a fluid inlet able to carry carbon dioxide, air and water, and on the side of the porous (photo)cathode of the second reactor there is a fluid outlet able to carry carbon dioxide and water.

The present disclosure provides for a composition that includes a modified M/TiO.sub.2 composite, method of making the modified M/TiO.sub.2 composite, an electrode having modified M/TiO.sub.2 composite surface and a photoelectrochemical cell including the electrode, and methods of photoelectrochemical oxidation of water. The modified M/TiO.sub.2 composite can be used in an electrode configuration, for example, in a photoelectrochemical cell for the photoelectrochemical oxidation of water. The present disclosure provides for a modified M/TiO.sub.2 composite that has a catechol compound(s) (e.g., oligo-catechol) adsorbed onto at least the M (metal) on the surface of the modified M/TiO.sub.2 composite.

The present disclosure provides for a composition that includes a modified M/TiO.sub.2 composite, method of making the modified M/TiO.sub.2 composite, an electrode having modified M/TiO.sub.2 composite surface and a photoelectrochemical cell including the electrode, and methods of photoelectrochemical oxidation of water. The modified M/TiO.sub.2 composite can be used in an electrode configuration, for example, in a photoelectrochemical cell for the photoelectrochemical oxidation of water. The present disclosure provides for a modified M/TiO.sub.2 composite that has a catechol compound(s) (e.g., oligo-catechol) adsorbed onto at least the M (metal) on the surface of the modified M/TiO.sub.2 composite.