An electrode of a chemical cell includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, each conductive projection of the array of conductive projections having a semiconductor composition for reduction of carbon dioxide (CO.sub.2) in the chemical cell, and a catalyst arrangement disposed along each conductive projection of the array of conductive projections, the catalyst arrangement including a copper-based catalyst and an iron-based catalyst for the reduction of carbon dioxide (CO.sub.2) in the chemical cell.

An oxygen evolution reaction catalyst electrode may include: a glass electrode; a first coating, directly upon the glass electrode, comprising a layer of fluorine-doped tin oxide (FTO); and a second coating, directly upon the first coating, comprising a layer comprising at least 95 wt. % palladium, relative to a total weight of the second coating, wherein the palladium in the second coating is in the form of porous, spongy-textured clusters comprising palladium spheroid nanoparticles in cubic crystalline phase. The second coating may have a thickness in a range of from 0.5 to 10 μm, and the clusters may have an average largest dimension in a range of from 500 to nm.

An oxygen evolution reaction catalyst electrode may include: a glass electrode; a first coating, directly upon the glass electrode, comprising a layer of fluorine-doped tin oxide (FTO); and a second coating, directly upon the first coating, comprising a layer comprising at least 95 wt. % palladium, relative to a total weight of the second coating, wherein the palladium in the second coating is in the form of porous, spongy-textured clusters comprising palladium spheroid nanoparticles in cubic crystalline phase. The second coating may have a thickness in a range of from 0.5 to 10 μm, and the clusters may have an average largest dimension in a range of from 500 to nm.

The present disclosure relates to an electrode for electrolysis, in which a structure of a metal base layer is optimized, and a preparation method thereof, wherein the electrode for electrolysis of the present invention exhibits an overvoltage improved in comparison to a conventional electrode while having excellent durability due to a small loss of a coating layer.

The present disclosure relates to an electrode for electrolysis, in which a structure of a metal base layer is optimized, and a preparation method thereof, wherein the electrode for electrolysis of the present invention exhibits an overvoltage improved in comparison to a conventional electrode while having excellent durability due to a small loss of a coating layer.

The present disclosure provides a cathode electrode that can stably sustain a catalytic reaction producing an olefinic hydrocarbon such as ethylene and an alcohol such as ethanol by a reduction reaction of carbon dioxide over a long term. A cathode electrode that electrically reduces carbon dioxide, including cuprous oxide, copper, and at least one additional metal element selected from the group consisting of silver, gold, zinc, and cadmium.

The present disclosure provides a cathode electrode that can stably sustain a catalytic reaction producing an olefinic hydrocarbon such as ethylene and an alcohol such as ethanol by a reduction reaction of carbon dioxide over a long term. A cathode electrode that electrically reduces carbon dioxide, including cuprous oxide, copper, and at least one additional metal element selected from the group consisting of silver, gold, zinc, and cadmium.

Catalytic materials useful, e.g., in water oxidation performing at low overpotential and/or stable for applications such as solar-to-fuel conversion systems may include nanoscale, nanoporous Pd-containing materials. Thin-film Pd electrocatalysts may be obtained via Aerosol-Assisted Chemical Vapor Deposition (AACVD) on conducting surfaces. XRD and XPS analyses show a phase pure crystalline metallic Pd deposit. Surface morphology study reveals a nanoparticulate highly porous nanostructure. Under electrochemical conditions, such Pd electrocatalysts may conduct water oxidation at onset potentials starting around 1.43 V against a reversible hydrogen electrode (ηof 200 mV, Tafel slope of 40 mV/dec), and/or may achieve around 100 mA/cm.sup.2 current density at 1.63 V against a reversible hydrogen electrode, and may exhibits long-term stability in oxygen evolution. Method of making such electrocatalysts and their uses are also provided.

Catalytic materials useful, e.g., in water oxidation performing at low overpotential and/or stable for applications such as solar-to-fuel conversion systems may include nanoscale, nanoporous Pd-containing materials. Thin-film Pd electrocatalysts may be obtained via Aerosol-Assisted Chemical Vapor Deposition (AACVD) on conducting surfaces. XRD and XPS analyses show a phase pure crystalline metallic Pd deposit. Surface morphology study reveals a nanoparticulate highly porous nanostructure. Under electrochemical conditions, such Pd electrocatalysts may conduct water oxidation at onset potentials starting around 1.43 V against a reversible hydrogen electrode (ηof 200 mV, Tafel slope of 40 mV/dec), and/or may achieve around 100 mA/cm.sup.2 current density at 1.63 V against a reversible hydrogen electrode, and may exhibits long-term stability in oxygen evolution. Method of making such electrocatalysts and their uses are also provided.

An electrode of a chemical cell includes a substrate having a surface, an array of conductive projections supported by the substrate and extending outward from the surface of the substrate, each conductive projection of the array of conductive projections having a semiconductor composition for reduction of carbon dioxide (CO.sub.2) in the chemical cell, and a catalyst arrangement disposed along each conductive projection of the array of conductive projections, the catalyst arrangement including a copper-based catalyst and an iron-based catalyst for the reduction of carbon dioxide (CO.sub.2) in the chemical cell.