A method of preparation of a ceramic slurry for use in 3D printing includes steps of: (A) providing a plasticizer and a disperser and mixing the plasticizer and the disperser evenly; (B) mixing the mixture obtained in step (A) with an adhesive, wherein the adhesive is polyvinyl alcohol; and (C) adding a Yttria-stabilized zirconia powder to the mixture obtained in step (B) to produce, by sufficient blending and deaerating, the ceramic slurry for use in 3D printing. A method of preparation of a ceramic product includes steps of: (A) preparing a ceramic slurry with the method; (B) performing 3D printing with the ceramic slurry to form a primary green body; (C) placing the primary green body in a freezer to undergo a refrigeration process, thereby causing crystallization of polyvinyl alcohol; and (D) thawing the frozen primary green body to form a plastic green body with gel structure.

The present invention relates to a surface treatment method for dental zirconia, including sandblasting the surface of three types of dental zirconia (3Y-TZP, 4Y-PSZ and 5Y-PSZ) with alumina particles, and this method optimizes sandblasting conditions for each type of zirconia and enhances mechanical properties by strengthening residual stress. In addition, a dental article including dental zirconia made by the surface treatment method for zirconia, and suitable protocols for the durable bond between resin cements and high-translucent zirconia are suggested.

A composition comprises a zirconia powder, in which 55% or more thereof is monoclinic, and a stabilizer capable of suppressing phase transition of zirconia. An average particle diameter of zirconia particles and particles of the stabilizer is 0.06 μm to 0.17 μm. At least a portion of the stabilizer does not form a solid solution with zirconia.

A sintered body includes a solid solution containing cobalt and iron, with the balance being zirconia. The total content of cobalt in terms of CoO and iron in terms of Fe.sub.2O.sub.3 is more than 0.1 wt % and less than 3.0 wt %, and the proportion of cobalt regions larger than 5.5 μm.sup.2 in an elemental map obtained using an electron probe microanalyzer is 25% or less.

Process for treating a porous dental zirconia block with a coloring solution, the process comprising the steps of providing a porous dental zirconia block having two opposing surfaces, surface U and surface L, treating the upper surface U of the porous dental zirconia block with a coloring solution A.sub.1, wherein the coloring solution is provided with a volume VA.sub.1, turning the porous dental zirconia block around, treating the lower surface L with a coloring solution A.sub.2 which is provided with a volume VA.sub.2. wherein the coloring solutions A.sub.1 and A.sub.2 comprise a solvent and coloring ions, wherein the volume of at least one of the coloring solutions A.sub.1 or A.sub.2 is applied in portions, wherein the following condition is met: Vo=ΣV.sub.AX, with x≥2, with Vo being the overall amount of coloring solution used to infiltrate the porous dental zirconia block.

A grain-grade zirconia toughened alumina ceramic substrate and a method for preparing the same. The ceramic substrate is prepared from alumina power (main phase) and zirconia powder (secondary phase) in a binary azeotrope of anhydrous ethanol and butanone in the presence of magnesia-alumina spinel powder (as sintering aid), phosphate ester (as dispersant), polyvinyl butyral (as binder) and dibutyl phthalate (as plasticizer). In a mixture of the alumina power and the zirconia powder, a volume percentage of the alumina power is 82.44-96.7%, and a volume percentage of the zirconia powder is 3.30-17.56%. The magnesia-alumina spinel powder is 0.1-4.0% by weight of the mixture of the alumina power and the zirconia powder. A particle size ratio of the alumina powder to the zirconia powder is 2.415-4.444.

A disclosure is provided for methods to prepare high-strength and high-toughness partially stabilized zirconia (PSZ) materials by incorporating a starting ceramic powder in which the stabilizing oxide agent is pre-alloyed with the zirconia material powder. The ceramic powder is pre-stabilized so there is little or no remaining free stabilizing oxide, thereby resulting in an improved material that is more convenient to process using conventional ceramic processing techniques.

Provided is a ZrO.sub.2—CaO—C based refractory material which is capable of maintaining high adhesion resistance over a long period of time, while exhibiting significant slaking resistance, and suppressing self-fluxing, i.e., exhibiting corrosion-erosion resistance. The refractory material comprises a CaO—ZrO.sub.2 composition containing a CaO component in an amount of 40% by mass to 60% by mass, wherein a mass ratio of the CaO component to a ZrO.sub.2 component is 0.67 to 1.5, and wherein the CaO—ZrO.sub.2 composition includes a eutectic microstructure of CaO crystals and CaZrO.sub.3 crystals, wherein a width of each of the CaO crystals observable in a cross-sectional microstructure is 50 μm or less.

The present disclosure provides a method of making a ceramic article. The method includes (a) obtaining a photopolymerizable slurry or sol including a plurality of ceramic particles distributed in the photopolymerizable slurry or sol and (b) selectively polymerizing the photopolymerizable slurry or sol using actinic radiation and continuous movement of a build substrate through the photopolymerizable slurry or sol to form a gelled article. The method also includes (c) extracting solvent from the gelled article to form an aerogel article or a xerogel article; (d) heat treating the aerogel article or the xerogel article to form a porous ceramic article; and (e) sintering the porous ceramic article to form a sintered ceramic article. The sintered ceramic article exhibits a particular density. Further, additive manufactured ceramic articles are provided that exhibit a particular density, opacity, or both. Preferably, all cross-sectional portions of an interior of the ceramic article having selected dimensions are free of a frequency analysis signal maxima larger than a background signal.

A rim-rotor assembly has an annular structure including a composite rim and a hub. Blades project from the hub, tips of the blades contacting the annular structure, the blades configured to be loaded in compression against the annular structure. A thermal barrier is in the annular structure, the thermal barrier defining at least part of a radially inward surface of the annular structure. The tips of the blades contact the thermal barrier, the thermal barrier being a thermal barrier coating.