The invention relates to a foamed, fissure-free skin-compatible article, produced by mixing a first polyurethane dispersion (A) with at least one second polyurethane dispersion (B) which differs from the first polyurethane dispersion (A), optionally with the addition of other additives, then by foaming and subsequently drying the mixture. The invention also relates to a process for preparing the foamed article and to the use thereof.

The invention relates to a foamed, fissure-free skin-compatible article, produced by mixing a first polyurethane dispersion (A) with at least one second polyurethane dispersion (B) which differs from the first polyurethane dispersion (A), optionally with the addition of other additives, then by foaming and subsequently drying the mixture. The invention also relates to a process for preparing the foamed article and to the use thereof.

The present invention relates to a process for producing polyaspartic ester compositions by reacting cyclic ethers bearing primary amino and/or primary aminoalkyl groups with fumaric and/or maleic esters, to the polyaspartic ester compositions thus obtainable, and to the use thereof in two-component coating compositions.

A polyaspartate composition is provided which comprises a reaction product of a diamine and a diester reacted at a ratio of diamine equivalents to diester equivalents of from 1:0.95 to 1:0.50. The polyaspartate compositions of the invention may be combined with polyisocyanates to produce polyurea compositions, e.g., coatings, adhesives, sealants, composites, castings, and films, which exhibit a faster cure time along with faster development time for physical properties such as hardness and tensile strength.

Silicone polyurea block copolymers are prepared by copolymerizing: (a) a diamine composition that includes a polyethylene glycol diamine, and optionally, a dipiperidyl alkane; (b) a monofunctional silicone isocyanate; and (c) a diisocyanate. Compositions useful as passivating coatings comprising the block copolymer are also provided, and substrates coated with the compositions. Methods of preparing and using the compositions are also described.

A photochromic hydroxyurethane compound of the present invention is characterized in that, on condition of having at least one photochromic moiety as the photochromic minimal unit in a molecule, it has a hydroxyurethane constitutional unit represented by Formula (1):

—X—O—CO—NH—  (1)

In the formula, X is an oxygen-containing chain organic group having a hydroxyl group as a substituent, or a hydrogen atom in the hydroxyl group is substituted by any one of (A): a photochromic group having the photochromic moiety; (B): a polymerization reactive group having a polymerizable substituent; (C) an alkyl group having 1 to 10 carbon atoms; (D) a cycloalkyl group having 3 to 10 carbon atoms; or (E): an aryl group having 6 to 14 carbon atoms (each of the groups (C)-(E) can be bonded to an oxygen atom derived from the hydroxyl group via the oxygen-containing chain organic group).

A photochromic hydroxyurethane compound of the present invention is characterized in that, on condition of having at least one photochromic moiety as the photochromic minimal unit in a molecule, it has a hydroxyurethane constitutional unit represented by Formula (1):

—X—O—CO—NH—  (1)

In the formula, X is an oxygen-containing chain organic group having a hydroxyl group as a substituent, or a hydrogen atom in the hydroxyl group is substituted by any one of (A): a photochromic group having the photochromic moiety; (B): a polymerization reactive group having a polymerizable substituent; (C) an alkyl group having 1 to 10 carbon atoms; (D) a cycloalkyl group having 3 to 10 carbon atoms; or (E): an aryl group having 6 to 14 carbon atoms (each of the groups (C)-(E) can be bonded to an oxygen atom derived from the hydroxyl group via the oxygen-containing chain organic group).

The present invention relates to [1] a polymerizable composition for optical member containing a polymerizable component and a urethaneurea compound having a structural unit derived from tolylene diisocyanate in an amount of 0.1 to 10 parts by mass based on 100 parts by mass of a total amount of the polymerizable component; [2] a production method of an optical member, including a step of injecting the polymerizable composition of [1] into a molding die, and a step of polymerizing the polymerizable composition; and [3] a spectacle lens including a spectacle lens substrate obtained by the production method of [2].

The present application discloses a polyol system for preparing polyurethane comprising: i) at least one active chain extender having at least two groups that can react with an isocyanate, wherein at least one group that can react with an isocyanate is free primary —NH2 group; ii) at least one active chain extender having three groups that can react with an isocyanate, wherein at least one group that can react with an isocyanate is free primary —OH group, and iii) at least one polyether polyol starting from an amine. The polyol system according to the present disclosure is phase-stable without layering and capable of releasing mold quickly after reacting with an isocyanate to produce polyurethane.

The present invention provides a urethane resin composition including an anionic urethane resin (X) and water (Y). The anionic urethane resin (X) is produced using, as essential raw materials: a polyol (a) including a polycarbonate polyol (a1) produced using biomass-derived decanediol as a raw material; and a polyisocyanate (b) including an aliphatic polyisocyanate (b1) and an alicyclic polyisocyanate (b2). Furthermore, the present invention provides a dry coating formed from the urethane resin composition, and provides a synthetic leather including the coating as a skin layer. The polycarbonate polyol (a1) is preferably produced further using butanediol as a raw material. The molar ratio [(b1)/(b2)] of the aliphatic polyisocyanate (b1) to the alicyclic polyisocyanate (b2) is preferably within a range of 10/90 to 90/10.