The present invention provides a urethane resin composition including an anionic urethane resin (X) and water (Y). The anionic urethane resin (X) is produced using, as essential raw materials: a polyol (a) including a polycarbonate polyol (a1) produced using biomass-derived decanediol as a raw material; and a polyisocyanate (b) including an aliphatic polyisocyanate (b1) and an alicyclic polyisocyanate (b2). Furthermore, the present invention provides a dry coating formed from the urethane resin composition, and provides a synthetic leather including the coating as a skin layer. The polycarbonate polyol (a1) is preferably produced further using butanediol as a raw material. The molar ratio [(b1)/(b2)] of the aliphatic polyisocyanate (b1) to the alicyclic polyisocyanate (b2) is preferably within a range of 10/90 to 90/10.

The invention relates to a two-component coating composition comprising i) a base component comprising: (A) a diamine resin with two secondary amine groups of general formula (b2)-NH-(b1)-NH-(b2) wherein (b1) is a cycloaliphatic hydrocarbon group, preferably a cycloaliphatic hydrocarbon group with 5 to 18 carbon atoms; and (b2) is, independently, selected from the group consisting of —C.sub.nh.sub.2n-CN wherein n is an integer in the range of from 2 to 6, —CH.sub.2CH.sub.2—C(O)—O—C.sub.mH.sub.(2m−1) or —CH.sub.2CH(CH.sub.3)—C(O)—O—C.sub.mH.sub.(2m+1) wherein m is an integer in the range of from 1 to 6, and optionally halogenated alkyl radicals with 2 to 10 carbon atoms; and ii) a curing component comprising: (B) a polyisocyanate prepolymer having two free isocyanate groups and an isocyanate content in the range of from 3 wt % to 9 wt %, based on solid weight of the polyisocyanate prepolymer; and (C) optionally up to 3 wt % of a polyisocyanate with more than two free isocyanate groups, based on the total weight of polyisocyanates (B) and (C), wherein the two-component coating composition comprises less than 5 wt % of polyol resin. The invention further elates to a method for coating a substrate using such two-component coating composition, to a coated substrate obtainable by such method, and to use of such coating composition for improving erosion resistance of a substrate.

In some embodiments, a film forming composition described herein comprises an aliphatic polyisocyanate; an aliphatic polyfunctional nucleophile; a chain extender; a first solvent; and a second solvent, wherein an evaporation rate of the first solvent and an evaporation rate of the second solvent are within 150% of each other, the percentage being based on the larger value. In some embodiments, a method of forming a film on a substrate is described herein, the method comprising combining a polyisocyanate with a polyol to form a polyurethane pre-polymer; combining the polyurethane pre-polymer with a chain extender to form a polymer; and applying the polymer to the substrate.

In some embodiments, a film forming composition described herein comprises an aliphatic polyisocyanate; an aliphatic polyfunctional nucleophile; a chain extender; a first solvent; and a second solvent, wherein an evaporation rate of the first solvent and an evaporation rate of the second solvent are within 150% of each other, the percentage being based on the larger value. In some embodiments, a method of forming a film on a substrate is described herein, the method comprising combining a polyisocyanate with a polyol to form a polyurethane pre-polymer; combining the polyurethane pre-polymer with a chain extender to form a polymer; and applying the polymer to the substrate.

The present disclosure includes a textile printing system including a fabric substrate and an ink composition. The ink composition can include water, organic co-solvent, from 0.5 wt % to 15 wt % pigment with a dispersant associated with a surface thereof, and from 0.1 wt % to 30 wt % of polyurethane particles including sulfonated- or carboxylated-diamine groups and isocyanate-generated amine groups.

The present disclosure includes a textile printing system including a fabric substrate and an ink composition. The ink composition can include water, organic co-solvent, from 0.5 wt % to 15 wt % pigment with a dispersant associated with a surface thereof, and from 0.1 wt % to 30 wt % of polyurethane particles including sulfonated- or carboxylated-diamine groups and isocyanate-generated amine groups.

The disclosure provides a non-ionic water based polyurethane, which is prepared from the following components in parts by weight: 120-185 parts of polymeric polyol, 30-40 parts of diisocyanate, 0.3-0.6 parts of antioxidant, 0.1-0.5 parts of organometallic catalyst, 1-3 parts of intramolecular crosslinking agent, 4-6 parts of silicone oil, 2.1-5.5 parts of auxiliary, 1-2 parts of chain extender, and 600-750 parts of water, where the polymeric polyol includes a polyether diol and a polyester diol, and the auxiliary includes a wetting agent, a leveling agent and a defoamer. The non-ionic water based polyurethane provided by the disclosure has excellent water resistance, mechanical properties and compatibility. Moreover, no organic solvent is added, thus, the disclosure results in no secondary pollution, and ensures environmental protection.

The disclosure provides a non-ionic water based polyurethane, which is prepared from the following components in parts by weight: 120-185 parts of polymeric polyol, 30-40 parts of diisocyanate, 0.3-0.6 parts of antioxidant, 0.1-0.5 parts of organometallic catalyst, 1-3 parts of intramolecular crosslinking agent, 4-6 parts of silicone oil, 2.1-5.5 parts of auxiliary, 1-2 parts of chain extender, and 600-750 parts of water, where the polymeric polyol includes a polyether diol and a polyester diol, and the auxiliary includes a wetting agent, a leveling agent and a defoamer. The non-ionic water based polyurethane provided by the disclosure has excellent water resistance, mechanical properties and compatibility. Moreover, no organic solvent is added, thus, the disclosure results in no secondary pollution, and ensures environmental protection.

Polyurethane prepolymers having non-linear short chain diols and/or soft diisocyanates incorporated into the backbone are used to provide cured polyurethane coatings having a high hard segment content and low haze. The polyurethane prepolymers can also be used to improve the dispersion of filler in cured polyurethane compositions having a high filler loading. Cured coatings prepared from the two-part polyurethane systems meet the requirements for aerospace applications.

Polyurethane prepolymers having non-linear short chain diols and/or soft diisocyanates incorporated into the backbone are used to provide cured polyurethane coatings having a high hard segment content and low haze. The polyurethane prepolymers can also be used to improve the dispersion of filler in cured polyurethane compositions having a high filler loading. Cured coatings prepared from the two-part polyurethane systems meet the requirements for aerospace applications.