A rigid polyurethane foam formulation comprising a polyester polyol having a hydroxyl number of from 150 to 600 mg KOH/g and a functionality of at least 2, a blowing agent comprising water and an auxiliary blowing agent, a non-silicone organic surfactant, greater than 0.1% to less than 3.7% of a cyclic siloxane, by weight based on the total weight of the foam formulation, a catalyst, and optionally a flame retardant; and a polyisocyanate; such that the isocyanate index is in the range of from 100 to 500, a rigid polyurethane foam formed from the foam formulation; and a method of forming a rigid polyurethane foam.

An exemplary embodiment of the present disclosure provides a polyurethane core for use in a floor or wall panel, the core comprising a polyol made, at least in part, from one or more recycled materials, and an isocyanate.

The present disclosure relates to improving insulation properties of foams by employing an azeotropically-modified blowing agent that preserves or improves R-value at various temperatures such as lower than ambient temperatures (below 24° C.). The present disclosure also provides foams with improved long-term thermal resistance (LTTR).

The present application relates to a resin or polymer system suitable for two-component compositions, and a resin or polymer system configured for durable coatings with only thin coating weights. The resins and polymer systems of this invention provide high performance extremely thin, low gloss coatings with excellent adhesion, abrasion, scratch and chemical resistance The resins include a polyester component with one or more polyester polyols having a hydroxyl value of about 50 to about 300 and a polyurea component with one or more polyester polyol grafted polyurea polymers having a hydroxyl value of about 20 to about 100. These resin or polymer systems and two-component solvent borne coating compositions including such resin or polymer systems are surprisingly capable of achieving strong adhesion, excellent linear abrasion, and high chemical resistance all at the same time in a dry film thickness of about 2 mil or less, in some instances, about 1.2 mils or less, and in other instances, even about 1 mil or less.

This disclosure provides for new polyisocyanurate (PIR) foams that exhibit improved flame retardant properties and thermal barrier properties, and which can pass certain thermal barrier tests in the absence of a protective covering such as specified in the thermal barriers codes. In an aspect, it has been unexpectedly discovered that when a relatively high viscosity and high functionality polyisocyanate is used with a high aromatic content polyester polyol and an HFO and/or HCFO blowing agent, and a flame retardant compound, unexpectedly good flame retardant polyisocyanurate foams can be generated, for example, when a high A-side:B-side volume ratio (v:v) and a relatively high Isocyanate Index (ISO Index) are used in the process.

The disclosure includes brominated alkenyl alcohols, their use as a flame retardant in polyurethane and polyurethane foams, and polyurethanes containing the brominated alkenyl alcohols. Compositions, methods, and processes are disclosed. The brominated alkenyl alcohols used as flame retardants in polyurethanes can be generally described by Formula (I), the scope of which is disclosed herein.

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A two-component adhesive composition is provided. The two-component adhesive composition comprises an isocyanate component, an isocyanate-reactive component and an amine-epoxy adduct, and can achieve superior adhesion strength between the adhesive and a substrate like metal alloy substrate. A laminated article prepared with said composition, a method for preparing the article and the use of the amine-epoxy adduct as adhesion promoter in a two-component polyurethane adhesive composition are also provided.

The present invention provides fire-retarded rigid polyurethane foam comprising the reaction product of polyol and isocyanate foam forming components and a dialkyl phosphorus-containing compound, namely a reactive mono-hydroxyl-functional dialkyl phosphinates, as flame retardant, serving as highly efficient reactive flame retardant in said rigid polyurethane foam.

The present invention is directed to a powder coating composition including a hydroxy-functional polymer, a carbodiimide crosslinker, and an organometallic catalyst. The present invention is also directed to a substrate at least partially coated with the powder coating composition. The present invention is also directed to a method of applying a coating composition to a substrate including: applying the powder coating composition to a substrate and heating the powder coating composition to form a coating over the substrate.

A two-component adhesive composition is provided. The two-component adhesive composition comprises an isocyanate component, an isocyanate-reactive component and an epoxy-aromatic diisocyanate adduct, and can achieve superior adhesion strength between the adhesive and a substrate like metal alloy substrate. A laminated article prepared with said composition, a method for preparing the article and the use of the epoxy-aromatic diisocyanate adduct as adhesion promoter in a two-component polyurethane adhesive composition are also provided.