Polyol premixes and thermally insulating rigid polyurethane foams, such as those that can be used as a thermal insulation medium in the construction of refrigerated storage devices, are disclosed. A polymer polyol having a OH number of greater than 260 mg KOH/g is utilized. The resulting polyurethane foams can exhibit improved thermal insulation properties without sacrificing other important physical and processing properties.

A catalyst composition comprising at least one compound with a general formula I:

##STR00001##

wherein A is N—R.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, x=0-6, n and m are each independently 1 to 6, R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are —CH.sub.3 groups; or A=O, x=0-6. n and m are each independently 1 to 6. R.sup.1 and R.sup.2 are each independently C.sub.2-C.sub.8 alkyl, and R.sup.4 and R.sup.5 are —CH.sub.3 groups; or A=O or N—R.sup.3, R.sup.3 is C.sub.1-C.sub.8 linear or branched, and N(R.sup.1-R.sup.4) and N(R.sup.2-R.sup.5) each independently represent a C.sub.3-C.sub.7 ring amine moiety of the type:

##STR00002##

A method of applying a closed cell spray foam insulation may include spraying a first layer of a closed cell spray foam insulation into a wall cavity. A B-side mixture of the closed cell spray foam insulation may include a polyol blend having a polyester polyol having a functionality of at least about 3.0 and a polyether polyol. The method may include spraying at least one additional layer of the closed cell spray foam insulation against the first layer within 5 minutes of spraying the first layer.

Storage-stable two-component polyurethane or polyisocyanurate spray foam compositions are disclosed, said compositions comprising: (a) an A-side component comprising one or more polyisocyanate and one or more blowing agent; and (b) a B-side component comprising one or more polyol and one or more blowing agent comprising pressurized gaseous carbon dioxide and one or more liquid blowing agent; wherein both the A-side component and the B-side component, separately, generate less than 300 ppm of fluoride ion after one week of aging at 50° C.

Disclosed is a polyurethane foam formulation based on conventional polyether and novolac polyols with, in particular, MDI for the production of soft-elastic PUR moulded foams with viscoelastic properties, in particular for sound insulation with foams based thereon.

Disclosed is a polyurethane foam formulation based on conventional polyether and polyester polyols based on renewable raw materials, with in particular MDI, for the production of preferably viscoelastic PUR moulded foams and sound insulations with foams based thereon.

What are described are (a) a composition suitable for production of rigid polyurethane foam, comprising at least one isocyanate component, a polyol component, optionally a catalyst that catalyses the formation of a urethane or isocyanurate bond, optionally blowing agents, where the composition additionally comprises polyalkylsiloxane (PAS) containing no polyether modification, and polyether-modified siloxane, (b) a process for producing rigid polyurethane foam using polyalkylsiloxanes and polyether-modified siloxane, (c) the rigid polyurethane foam Thus obtainable and (d) the use thereof.

Disclosed is a polyurethane foam formulation based on conventional polyether and novolac polyols with, in particular, MDI for the production of soft-elastic PUR moulded foams with viscoelastic properties, in particular for sound insulation with foams based thereon.

The present technology provides a method of manufacturing a polyurethane foam having a low thermal conductivity from a foam formulation comprising a polyol, an isocyanate, a polyurethane catalyst, a surfactant, water, and a siloxane rich composition. The siloxane rich composition may act as a nucleating agent to reduce the cell size of the foams and may reduce its thermal conductivity.

A polyurethane composition raw material liquid agent comprises a polyol or an isocyanate, and a filler. The polyurethane composition raw material liquid agent has a viscosity at 25° C. and a rotation speed of 60 rpm of 950 mPa.Math.s or less, and is filled in at least one cartridge-like container of a caulking gun that includes two cartridge-like containers and is capable of mixing two components.