Two-component solventless polyurethane adhesive compositions comprising an isocyanate component and an isocyanate-reactive are disclosed, the compositions comprising an isocyanate component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and, optionally, a bio-based polyol. Methods for forming laminate structures are also disclosed, the methods comprising forming an adhesive composition by mixing an isocyanate adhesive component comprising an isocyanate-terminated prepolymer and an isocyanate-reactive adhesive component comprising a hydroxy-terminated polyurethane resin, a polyether polyol, a phosphate ester adhesion promoter, and optionally, a bio-based polyol, applying the adhesive composition to a surface of a first substrate, and bringing a surface of a second substrate into contact with the adhesive composition on the surface of the first substrate, thereby forming the laminate structure. Laminate structures are also disclosed.

A urethane-based adhesive composition includes a urethane prepolymer, a carbon black A having a dibutyl phthalate oil absorption number of 30 to 40 ml/100 g, a carbon black B having a dibutyl phthalate oil absorption number of 98 to 108 ml/100 g, a calcium carbonate C, a plasticizer D, a modified product E of an aliphatic diisocyanate, and a catalyst, and the urethane-based adhesive composition is configured to satisfy all of the following (1) to (6): (1) 25≤a≤35, (2) 55≤b≤75, (3) 197≤a+3b≤251, (4) 30≤c≤35, (5) 35≤d≤45, and (6) 9≤e≤13.

Disclosed herein are a cannabidiol (CBD)-containing bio-based polyurethane composite material and a preparation thereof. The composite material is prepared from a component A and a component B in a weight ratio of 100:(20-50), where the component A includes 40-60 parts by weight of a vegetable oil-based polyol, 35-50 parts by weight of polyether polyol I, 0-10 parts by weight of polyether polyol II, 0.5-5 parts by weight of CBD, 0-5 parts by weight of a natural pigment, 0.5-3 parts by weight of silicon oil, 0-5 parts by weight of a cross-linking agent, 0.2-1 part by weight of a catalyst and 0.8-4 parts by weight of water, and the component B includes 20-50 parts by weight of modified methylene diphenyl diisocyanate (MDI).

A two-component composition is described which comprises A) an isocyanate component comprising an isocyanate-terminated urethane prepolymer, B) a water component comprising water, and at least one latent amine hardener in component A). The two-component composition of the invention is suitable as a sealant, in particular as a joint sealant. Particular advantages are that primerless application is possible with good adhesion, even at low temperatures, such as 4.4° C. or below. The substrate to be sealed are preferably concrete substrates.

A foam-forming composition for producing a rigid polyurethane foam including: (a) at least one isocyanate component; and (b) at least one isocyanate-reactive composition including: (bi) a rigid polyol compound; and (bii) a flexible polyol compound; (c) a catalyst package including at least one latent gelling catalyst; and (d) at least one blowing agent.

A compound of formula (I) having advantageous properties when used as a latent curing agent for compositions containing isocyanate groups, and to compositions containing the compound of formula (I). The compound of formula (I) is odourless, is liquid and has comparatively low viscosity at room temperature and is stable in storage together with isocyanates. It makes possible odourless single-component polyurethane compositions which have good stability in storage, do not produce bubbles when cured in the presence of moisture, and cause no problematic odour emissions, giving a cured elastic material having good mechanical properties, good heat stability, a surprisingly non-adhesive surface and little tendency towards plasticizer migration.

A one-component type polyurethane prepolymer composition comprises a reaction product formed through a reaction between reactants comprising (a) at least one polyisocyanate, and (b) a polyol blend comprising at least one bifunctional polyether polyol, wherein the bifunctional polyether polyol is a homopolymer of propylene oxide, homopolymer of butylene oxide, or copolymer of alkylene oxide, and has a number average molecular weight from 3000 g/mol to 9000 g/mol, and at least one trifunctional polyether polyol, wherein the trifunctional polyether polyol is a copolymer of alkylene oxide and end-capped with 10 wt % to 28 wt %, by the total weight of the trifunctional polyether polyol, of ethylene oxide, and has a number average molecular weight from 5000 g/mol to 8000 g/mol, wherein the bifunctional polyether polyol and the trifunctional polyether polyol are present in a parts by weight ratio from 4:1 to 2.5:1, and wherein the polyisocyanate and the polyol blend are present in a parts by weight ratio of from 1:7 to 1:2.5.

The use of an aldehyde mixture containing 70 to 95 wt % of aldehydes of formula (I) and 5 to 30 wt % of alkylbenzene compounds not corresponding to formula (I) as a blocking agent for amines results in odorless, especially economically blocked amines, which at room temperature are typically liquid and have a surprisingly low viscosity. Such blocked amines are particularly suitable as latent hardeners in isocyanate-group-containing compositions. Single-component moisture-curing polyurethane compositions formulated therewith are surprisingly stable in storage, can be used for low-emission applications without odor problems and do not trigger any problems with plasticizer migration. Surprisingly, said compositions even have advantages over corresponding compositions having latent hardeners based on purified aldehydes of formula (I), in particular with respect to viscosity, storage stability and especially strength.

To provide a polyether polyol having a high degree of freedom in the design of a polyurethane foam, and capable of providing a polyol system solution excellent in storage stability. A polyether polyol having a polyoxyalkylene chain consisting of oxyalkylene units, and having a degree of unsaturation of at most 0.020 meq/g, a hydroxy value of from 1 to 80 mgKOH/g, a content of oxyethylene units of from 0 to 50 mass %, and a content of ultra-high molecular weight components which have molecular weights of from 12 to 46 times the number average molecular weight of at most 1,000 mass ppm. The number average molecular weight is a molecular weight as calculated as polystyrene measured by gel permeation chromatography (GPC) method, and the content of ultra-high molecular weight components is a value measured by high performance liquid chromatography (HPLC) method using a charged aerosol detector (CAD).

An embodiment of the present technology is an isocyanate-based adhesive used for a surface-treated crystalline thermoplastic resin base material, the isocyanate-based adhesive having a value represented by (JIS-A hardness)/(strength at break [MPa])×(elongation at break (%))/100 of 2.0 to 70 after being cured by being allowed to stand still under a condition at 23° C. and 50% RH for 3 days, and the crystalline thermoplastic resin base material having a value represented by (δ.sup.d/δ.sup.p+δ.sup.p) of 2.0 to 30.0. δ.sup.p=γ.sup.p−γ.sup.p0 and δ.sup.d=|γ.sup.d−γ.sup.d0|, γ.sup.p0 is a polar term of surface free energy before the surface treatment, γ.sup.p is a polar term of surface free energy after the surface treatment, γ.sup.d0 is a dispersion term of the surface free energy before the surface treatment, and γ.sup.d is a dispersion term of the surface free energy after the surface treatment.