Provided are a transparent conducting film laminate to which a curl generated during a heating step and after the heating step can be controlled, and a method for processing the same. A transparent conducting film laminate comprises a transparent conducting film 20 and a carrier film 10 stacked thereon, wherein the transparent conducting film 20 comprises a transparent resin film 3, transparent conducting layer 4, and an overcoat layer 5 stacked in this order, the transparent resin film 3 having a thickness T.sub.1 of 5 to 25 μm and being made of an amorphous cycloolefin-based resin, the carrier film 10 is releasably stacked on the other main face, the face opposite to the face having the transparent conducting layer 4, of the transparent resin film 3 with an adhesive agent layer 2 therebetween, and a protection film 1 has a thickness T.sub.2 which is 5 times or more of the thickness T.sub.1 of the transparent resin film 3 and is 150 μm or less, and is made of polyester having an aromatic ring in its molecular backbone.

A multicomponent adhesive composition comprises a composition A and a composition B. Composition A comprises at least one silyl polymer comprising at least one hydrolyzable alkoxysilane group and at least one tackifying resin. Composition B comprises at least one catalyst and at least one compound C chosen from a compound C1 with a number-average molecular mass ranging from 300 g/mol to 500 000 g/mol; and a compound C2 with a vapor pressure at 20° C. of greater than or equal to 0.08 kPa; and mixtures thereof. The composition A:composition B mass ratio ranges from 99.98:0.02 to 60:40. The total content of catalyst ranges from 0.01% to 10% relative to the total weight of said adhesive composition.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

Disclosed herein is an aqueous coating composition including an anionically stabilized binder,a color pigment, a polycarboxylic acid, and optionally a solvent. Further disclosed is a method for producing an inventive aqueous coating composition by adding a solution of polycarboxylic acid in a solvent to a coating composition including an anionically stabilized binder and color pigment.Additionally disclosed is a method for producing a multicoat paint system by producing a basecoat layer or at least two directly consecutive basecoat layers directly on a substrate optionally coated with a first coating layer, producing a clearcoat layer directly on the basecoat layer or the topmost basecoat layer, and jointly curing the basecoat layer(s) and the clearcoat layer. At least one of the basecoat materials includes the aqueous coating composition disclosed herein and/or an aqueous coating prepared by the disclosed method. A multicoat paint system obtainable by the method is additionally disclosed.

A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.

Problem to be Solved

A thermoplastic polyurethane film that is capable of achieving a stress relaxation property regardless of the type of polyol, while having good pasting workability, as well as a multilayer film using the same, is provided.

Solution

The thermoplastic polyurethane film is constituted by a reaction product obtained by using dicyclohexylmethane diisocyanate (H.sub.12MDI). This enables the thermoplastic polyurethane film and the multilayer film to have a good stress relaxation property regardless of the type of polyol, and to have excellent pasting workability.

A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm.sup.3 to 0.8 g/cm.sup.3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.

The present disclosure provides photo-polymerizable components, photo-curable resins comprising one or more of such monomers, as well as polymeric materials formed from the photo-curable resins. Further provided herein are methods of producing the compositions and using the same for the fabrication of medical devices, such as orthodontic appliances.

Disclosed herein are hard coat compositions and composite films including a thermoplastic polyurethane. A hard coat composition includes a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater. The thermoplastic polyurethane is a reaction product of a) a diisocyanate; b) a polyol optionally comprising a cyclic structure; and c) a chain extender. At least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure. A composite film includes 1) a hard coat layer having opposing first and second major surfaces; and 2) a second layer disposed on at least a portion of the hard coat layer. These materials can serve decorative and/or protective functions while displaying both good elongation at moderate temperatures and high hardness.

The present disclosure describes phosphonium-containing polyurethane compositions, coating compositions, and coated fabric media. In one example, a phosphonium-containing polyurethane composition can include an aqueous liquid vehicle and polyurethane particles. The polyurethane particles can include a polyurethane polymer devoid of end cap groups. The polyurethane polymer can include a polyurethane backbone having a polymerized diamine chain extender forming a portion of the backbone. The polyurethane polymer can also include side chain groups along the polyurethane backbone. The side chain groups can collectively include aliphatic phosphonium salts and polyalkylene oxide groups.