The present disclosure provides a porous polymeric membrane that is coated with a cross-linked polymerized monomer. The coating on the porous polymeric membrane has a charge when it is immersed in an organic liquid. The coated porous polymeric membrane, a filter utilizing the membrane, and a method for treating an organic liquid used for photoresist with the coated porous polymeric membrane to remove metal contaminants from the organic liquid are disclosed.

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

The present disclosure provides a porous polymeric membrane that is coated with a cross-linked polymerized monomer. The coating on the porous polymeric membrane has a charge when it is immersed in an organic liquid. The coated porous polymeric membrane, a filter utilizing the membrane, and a method for treating an organic liquid used for photoresist with the coated porous polymeric membrane to remove metal contaminants from the organic liquid are disclosed.

A crosslinkable copolymer is provided. The crosslinkable copolymer has pendant cationic nitrogen-containing groups with some, but not all, of these pendant groups further including a (meth)acryloyl group. The (meth)acryloyl groups can react to form a crosslinked copolymer that is ionically conductive. The crosslinked copolymer can be used to provide an anion exchange membrane that can be used in electrochemical cells such as fuel cells, electrolyzers, batteries, and electrodialysis cells.

A composition is disclosed comprising a sulfonated styrenic block copolymer (SSBC) having an ion exchange capacity (IEC) of at least 0.5 meq/g; and at least one compound which reacts with the SSBC forming a cross-linked SSBC. The compound is selected from: (i) a cross-linking agent, (ii) a metal cation, and (iii) a non-sulfonated polymer. A film prepared from the composition containing the cross-linked SSBC has a toughness in wet state measured after 1 week of 1.2 to 8 MJ/m.sup.3; and a tensile stress in wet state measured after 1 week of 3.2 to 8 MPa, according to ASTM D412. The film can be used as a water 10 purification membrane or an antimicrobial protection layer.

The invention relates to inorganic particles which are covalently bonded to first polymer chains made up of at least one polymer carrying proton exchange groups, optionally in the form of salts, and bonded to second polymer chains made up of at least one fluorinated polymer that does not carry any proton exchange groups, the second chains being bonded to the particles via organic spacer groups, or the second chains being bonded to first chains via organic spacer groups, or some of the second chains being bonded to the particles via organic spacer groups while the remaining second chains are bonded to first chains via organic spacer groups.

Membranes having an average pore size of 5 nm to 5,000 nm and a porosity of 10% or more, said membrane being obtainable by a process comprising curing a composition comprising: (i) a cross-linking agent comprising at least one anionic group; and (ii) inert solvent(s).

The membranes are useful for detecting metal ions and for filtering and/or purifying biomolecules and compositions comprising metal-ions.

The present disclosure is directed to triblock copolymer based anion exchange membranes (AEMs) and methods for making same. The membranes are useful as separators in electrochemical devices, such as fuel cells, electrolyzers, water desalination systems, and redox flow batteries.

Methods of producing an ion exchange membrane support are disclosed. The methods include saturating a polymeric microporous substrate with a charged monomer solution comprising at least one functional monomer, a cross-linking agent, and an effective amount of at least one photopolymerization initiator and polymerizing the at least one functional monomer by exposing the saturated polymeric microporous substrate to ultraviolet light under conditions effective to cross-link the at least one functional monomer and produce the ion exchange membrane support. Methods of producing a monovalent selective ion exchange membrane are also disclosed. The methods include functionalizing an exterior surface of the ion exchange membrane support with a charged compound layer, drying the ion exchange membrane support and soaking the ion exchange membrane support in a solution comprising an acid or a base for an amount of time effective to produce the monovalent selective ion exchange membrane.

Cationic polymers are provided that comprise monomeric units of Formula (V). (V) Each asterisk (*) indicates an attachment position to another monomeric unit; R is hydrogen or methyl; each R.sup.2 is each independently an alkyl, aryl, or a combination thereof; L is a linking group comprising an alkylene group; and +R.sup.3 is a cationic nitrogen-containing group free of any N—H bonds. Membranes formed from said cationic polymers, devices including such membranes, and methods of making such cationic polymers are also provided.