A thermoplastic resin composition according to the present invention comprises: about 100 parts by weight of a thermoplastic resin comprising about 30 to about 60 wt % of a rubber-modified aromatic vinyl-based copolymer resin, about 30 to about 60 wt % of a polycarbonate resin, and about 5 to about 25 wt % of a polyester resin; about 0.1 to about 5 parts by weight of zinc oxide; about 0.1 to about 3 parts by weight of a phosphite compound comprising at least one type from among a phosphite compound represented by chemical formula 1 and a phosphite compound represented by chemical formula 2; and about 5 to about 30 parts by weight of a phosphorus-based flame retardant. The thermoplastic resin composition has excellent hydrolysis resistance, flame retardancy, and impact resistance, excellent balance of the foregoing physical properties, and the like.

A thermoplastic resin composition according to the present invention comprises: about 100 parts by weight of a thermoplastic resin comprising about 30 to about 60 wt % of a rubber-modified aromatic vinyl-based copolymer resin, about 30 to about 60 wt % of a polycarbonate resin, and about 5 to about 25 wt % of a polyester resin; about 0.1 to about 5 parts by weight of zinc oxide; about 0.1 to about 3 parts by weight of a phosphite compound comprising at least one type from among a phosphite compound represented by chemical formula 1 and a phosphite compound represented by chemical formula 2; and about 5 to about 30 parts by weight of a phosphorus-based flame retardant. The thermoplastic resin composition has excellent hydrolysis resistance, flame retardancy, and impact resistance, excellent balance of the foregoing physical properties, and the like.

Cementing compositions including a di- or poly epoxide resin, and amine hardener, and a di- or polyfunctional alkylphosphonate ester fortifier and methods of using the cementing compositions such as in a subterranean zone penetrated by a well bore.

Cementing compositions including a di- or poly epoxide resin, and amine hardener, and a di- or polyfunctional alkylphosphonate ester fortifier and methods of using the cementing compositions such as in a subterranean zone penetrated by a well bore.

A curable composition comprising: i) a glycidyl ether of a novolac, comprising or consisting of moieties having the formula (I), wherein —R.sub.a is either always hydrogen or always methyl; —B is either always *—CH2-** or always formula (A); —a fraction of 0.8 to 0.99 of the Y moieties are essentially —O-glycidyl, this fraction being designated as x, and the remainder of the Y moieties, this fraction being designated as (1-x), are divalent bridging spacers of the structure *—O—CH.sub.2—CH(OH)—CH.sub.2—O—** connecting two moieties according to above formula (I); and—n is a number in the range of 0.1 to 3.0; and wherein said novolac glycidyl ether has an epoxy equivalent weight FEW in the range of 160 to 270 g/eq. and the average number of epoxy groups per molecule of novolac glycidyl ether (I), designated as f, is in the range of 2.1 to 5.0; ii) dicyandiamide; and iii) an urea derivative of the formula (II). This composition is stable upon storage at room temperature and fire-retardant. It can be used for preparation of prepregs and in core filling, particularly in the aerospace field.

A curable composition comprising: i) a glycidyl ether of a novolac, comprising or consisting of moieties having the formula (I), wherein —R.sub.a is either always hydrogen or always methyl; —B is either always *—CH2-** or always formula (A); —a fraction of 0.8 to 0.99 of the Y moieties are essentially —O-glycidyl, this fraction being designated as x, and the remainder of the Y moieties, this fraction being designated as (1-x), are divalent bridging spacers of the structure *—O—CH.sub.2—CH(OH)—CH.sub.2—O—** connecting two moieties according to above formula (I); and—n is a number in the range of 0.1 to 3.0; and wherein said novolac glycidyl ether has an epoxy equivalent weight FEW in the range of 160 to 270 g/eq. and the average number of epoxy groups per molecule of novolac glycidyl ether (I), designated as f, is in the range of 2.1 to 5.0; ii) dicyandiamide; and iii) an urea derivative of the formula (II). This composition is stable upon storage at room temperature and fire-retardant. It can be used for preparation of prepregs and in core filling, particularly in the aerospace field.

A levoglucosan-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a polymer that contains the levoglucosan-based flame retardant compound. The levoglucosan-based flame retardant compound has phosphorus-based flame retardant functional groups. At least one of the phosphorus-based flame retardant groups includes a phenyl substituent. The process for forming the flame retardant polymer includes providing a phosphorus-based flame retardant molecule, providing levoglucosan, chemically reacting the phosphorus-based flame retardant molecule and the levoglucosan derivative to form a levoglucosan-based flame retardant compound, and incorporating the levoglucosan-based flame retardant compound into a polymer by covalent binding to form the levoglucosan-based flame retardant polymer.

A levoglucosan-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a polymer that contains the levoglucosan-based flame retardant compound. The levoglucosan-based flame retardant compound has phosphorus-based flame retardant functional groups. At least one of the phosphorus-based flame retardant groups includes a phenyl substituent. The process for forming the flame retardant polymer includes providing a phosphorus-based flame retardant molecule, providing levoglucosan, chemically reacting the phosphorus-based flame retardant molecule and the levoglucosan derivative to form a levoglucosan-based flame retardant compound, and incorporating the levoglucosan-based flame retardant compound into a polymer by covalent binding to form the levoglucosan-based flame retardant polymer.

A flame retardant sugar-derived molecule, a process for forming a flame retardant sugar-derived molecule, and an article of manufacture comprising a flame retardant sugar-derived molecule are disclosed. The flame retardant sugar-derived molecule can be synthesized from arabitol, xylitol, arabic acid, or xylonic acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety. The process for forming the flame retardant sugar-derived molecule can include reacting arabitol, xylitol, arabic acid, or xylonic acid and a flame retardant phosphorus-based molecule to form the flame retardant sugar-derived molecule.

A flame retardant sugar-derived molecule, a process for forming a flame retardant sugar-derived molecule, and an article of manufacture comprising a flame retardant sugar-derived molecule are disclosed. The flame retardant sugar-derived molecule can be synthesized from arabitol, xylitol, arabic acid, or xylonic acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety. The process for forming the flame retardant sugar-derived molecule can include reacting arabitol, xylitol, arabic acid, or xylonic acid and a flame retardant phosphorus-based molecule to form the flame retardant sugar-derived molecule.