A levoglucosan-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a levoglucosan-based flame retardant polymer are disclosed. The levoglucosan-based flame retardant compound has phosphorus-based flame retardant functional groups. The process for forming the flame retardant polymer includes providing a phosphorus-based flame retardant molecule, providing levoglucosan, chemically reacting the phosphorus-based flame retardant molecule and the levoglucosan derivative to form a levoglucosan-based flame retardant compound, and incorporating the levoglucosan-based flame retardant compound into a polymer to form the levoglucosan-based flame retardant polymer.

A levoglucosan-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a levoglucosan-based flame retardant polymer are disclosed. The levoglucosan-based flame retardant compound has phosphorus-based flame retardant functional groups. The process for forming the flame retardant polymer includes providing a phosphorus-based flame retardant molecule, providing levoglucosan, chemically reacting the phosphorus-based flame retardant molecule and the levoglucosan derivative to form a levoglucosan-based flame retardant compound, and incorporating the levoglucosan-based flame retardant compound into a polymer to form the levoglucosan-based flame retardant polymer.

Compounds are of the formula (Ia), (Ib), (Ic), or are stereoisomers thereof, wherein: R1 is hydrogen, (C1-C20)alkyl; (C3-C20)alkenyl; (C3 C20)alkynyl; (C1-C6)alkyl-O; (C3-C20)cycloalkyl; (C1 C20)haloalkyl; (C6-C20)aryl optionally substituted; (C6-C20)heteroaryl optionally substituted; R2 and R2 are hydrogen; (C1-C20)alkyl; (C1-C6)alkyl-O; (C1-C6)haloalkyl; halogen; cyano; and nitro; Z1 to Z4 are diradicals of formula (III) wherein A1 and A2 are O or NR3-, wherein R3 is selected from the group consisting of hydrogen and (C1-C20)alkyl; and G is (C1-C6)alkyl; P(S)R5-; P(O)R4; P(O)(OR4)-; P(O)(NR6R7)-; S(O)2-; S(O); or C(O); and Y1 to Y4 are (C1-C8)alkyl; (C3-C7)cycloalkyl; (C6-C20)aryl optionally substituted; or (C6-C20)heteroaryl optionally substituted; and FG1 and FG2 are H, OH, or NHR8.

Compounds are of the formula (Ia), (Ib), (Ic), or are stereoisomers thereof, wherein: R1 is hydrogen, (C1-C20)alkyl; (C3-C20)alkenyl; (C3 C20)alkynyl; (C1-C6)alkyl-O; (C3-C20)cycloalkyl; (C1 C20)haloalkyl; (C6-C20)aryl optionally substituted; (C6-C20)heteroaryl optionally substituted; R2 and R2 are hydrogen; (C1-C20)alkyl; (C1-C6)alkyl-O; (C1-C6)haloalkyl; halogen; cyano; and nitro; Z1 to Z4 are diradicals of formula (III) wherein A1 and A2 are O or NR3-, wherein R3 is selected from the group consisting of hydrogen and (C1-C20)alkyl; and G is (C1-C6)alkyl; P(S)R5-; P(O)R4; P(O)(OR4)-; P(O)(NR6R7)-; S(O)2-; S(O); or C(O); and Y1 to Y4 are (C1-C8)alkyl; (C3-C7)cycloalkyl; (C6-C20)aryl optionally substituted; or (C6-C20)heteroaryl optionally substituted; and FG1 and FG2 are H, OH, or NHR8.

A pinene-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a pinene-based flame retardant polymer are disclosed. The pinene-based flame retardant compound includes a pinene derivative core and at least one flame retardant substituent having a phosphorus-based moiety. The process for forming the flame retardant polymer includes obtaining pinene, forming a derivative of pinene, obtaining a phosphorus-based compound, reacting the phosphorus-based compound and the pinene derivative to form a pinene-based flame retardant compound, and incorporating the pinene-based flame retardant compound into a polymer to form the pinene-based flame retardant polymer.

A pinene-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a pinene-based flame retardant polymer are disclosed. The pinene-based flame retardant compound includes a pinene derivative core and at least one flame retardant substituent having a phosphorus-based moiety. The process for forming the flame retardant polymer includes obtaining pinene, forming a derivative of pinene, obtaining a phosphorus-based compound, reacting the phosphorus-based compound and the pinene derivative to form a pinene-based flame retardant compound, and incorporating the pinene-based flame retardant compound into a polymer to form the pinene-based flame retardant polymer.

The present disclosure provides a flame retardant and antistatic regenerated polyester wig fiber and a preparation method thereof, and relates to the field of simulated wig technology. A composite flame retardant composed of poly(sulfonyldiphenylene phenylphosphonate) (PSPPP), a derivative of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-FT), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide triphosphonitrile (DOPO-TPN), and biomass-derived graphene are subjected to a re-polymerization reaction with an alcoholysis product BHET of a waste PET bottle flake, respectively to obtain an in-situ modified flame retardant regenerated masterbatch and an antistatic regenerated polyester masterbatch. The masterbatches are blended and melt-spun with regenerated polyester, so that the obtained wig fiber has good flame retardant property, better flame retardant coefficient and antistatic property, and a significant antibacterial effect, thereby increasing the safety of the wig. The recycled and regenerated polyester from the PET bottle is utilized, effectively reducing environmental pollution caused by waste polyester, and contributing to resource conservation and sustainable development.

The present disclosure provides a flame retardant and antistatic regenerated polyester wig fiber and a preparation method thereof, and relates to the field of simulated wig technology. A composite flame retardant composed of poly(sulfonyldiphenylene phenylphosphonate) (PSPPP), a derivative of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-FT), and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide triphosphonitrile (DOPO-TPN), and biomass-derived graphene are subjected to a re-polymerization reaction with an alcoholysis product BHET of a waste PET bottle flake, respectively to obtain an in-situ modified flame retardant regenerated masterbatch and an antistatic regenerated polyester masterbatch. The masterbatches are blended and melt-spun with regenerated polyester, so that the obtained wig fiber has good flame retardant property, better flame retardant coefficient and antistatic property, and a significant antibacterial effect, thereby increasing the safety of the wig. The recycled and regenerated polyester from the PET bottle is utilized, effectively reducing environmental pollution caused by waste polyester, and contributing to resource conservation and sustainable development.

A process of forming a resveratrol-based flame retardant small molecule with a phosphonate/phosphinate molecule that includes a chloride group and a terminal functional group.

A process of forming a resveratrol-based flame retardant small molecule with a phosphonate/phosphinate molecule that includes a chloride group and a terminal functional group.