Reversion problems with heavy oils, such as heavy fuel oils, are mitigated by introducing an effective amount of an additive that contains both a phase change material and a pour point depressant, even synergistically mitigated.

A block copolymer including: at least one block A of following formula (I):

##STR00001##

in which p is an integer ranging from 2 to 100, R1 is selected from hydrogen and the methyl group, R2 is chosen from C1 to C34 hydrocarbon-based chains, at least one block B of following formula (II):

##STR00002##

in which n is an integer ranging from 2 to 40, R1 is chosen from hydrogen and the methyl group, Z is chosen from the oxygen atom and the group NR with R being chosen from a hydrogen atom and C1 to C12 hydrocarbon-based chains, G is a C1 to C34 hydrocarbon-based chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. Also, the use of such a block copolymer as detergent additive in an internal combustion engine liquid fuel.

An additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material, consisting essentially of (A) from 1 to 50% by weight of an olefin-sulfur dioxide copolymer, (B) from 1 to 50% by weight of a compound which comprises one or more basic nitrogen atoms and has at least one relatively long-chain linear or branched hydrocarbon radical having at least four carbon atoms or an equivalent structural element which ensures the solubility of component (B) in the inanimate organic material, (C) from 0.1 to 30% by weight of an oil-soluble acid and (D) from 1 to 80% by weight of a high-boiling organic solvent which consists of one or more molecule types, where at least 80% by weight of these molecule types have a boiling point of more than 150 C. at standard pressure,
where the sum of all components adds up to 100% by weight.

Novel uses of copolymers for removing and/or reducing the level of deposits in the fuel system and/or injection system of direct injection diesel and/or gasoline engines are provided. What is provided is the use of particular copolymers as fuel additive or lubricant additive; to processes for preparation of such additives, and fuels and lubricants added therewith, such as, more particularly, as a detergent additive; to use of these copolymers for reducing the level of or preventing deposits in the fuel systems and especially the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.

Ethylene-C.sub.3-C.sub.10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C.sub.3-C.sub.10 alpha-olefin-derived units. The C.sub.3-C.sub.10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C.sub.3-C.sub.10 alpha-olefin-derived units may be propylene-derived units.

Disclosed herein are antifouling compositions including a combination of one or more dispersant polymers and one or more inhibitors, the one or more dispersant polymers including the polymerized residues of one or more -olefins and maleic anhydride, further wherein the maleic anhydride residues are reacted with a primary amine; and the one or more inhibitors including a functionalized p-phenylene diamine. Concentrates of the antifouling compositions in solvents are stable and pourable at temperatures of 0 C. to 40 C. The antifouling compositions are added to a petroleum product to form a treated petroleum product, wherein fouling by the treated petroleum product is reduced and a stable dispersion is formed over a wide range of processing conditions.

The present invention relates to a process for preparing grafted polyalkyl(meth)acrylates (PAMAs) containing dispersant repeating units in the polymer backbone as well as in the grafted layer, which polymers are characterized by a low sulfur content, the products available by this process and their use as an additive to fuels, especially to middle distillates and blends thereof. The present invention further relates to a composition comprising the grafted polyalkyl(meth)acrylates prepared by the process according to the present invention and the use of said composition as an additive component to fuels, especially to middle distillates and blends thereof, and for improving the cold flow properties of fuel oil and fuel oil compositions, especially to middle distillate fuels and blends thereof.

Disclosed are paraffin inhibitors, paraffin suppressant compositions, and methods of making and using them. The paraffin inhibitors comprise polymers of a maleic moiety polymerized with at least two olefins having hydrocarbon chains of a different length from each other. When added to hydrocarbon media such as crude oils to form crude oil compositions, the paraffin inhibitors inhibit the precipitation of paraffin waxes in the crude oil compositions and exhibit reduced precipitation, gelling, and/or crystallization from the hydrocarbon media when the media are subjected to sustained low temperatures.

Disclosed herein are paraffin suppressant compositions, and methods of making and using them. The compositions comprise a paraffin inhibitor, a hydrocarbon-soluble hydrotrope equivalent, and optionally one or more additional paraffin dispersants. When added to hydrocarbon media such as crude oils to form crude oil compositions, the suppressant compositions inhibit the precipitation of paraffin waxes in the crude oil compositions. The suppressant compositions, added to hydrocarbon media such as hydrocarbon solvents or crude oils, exhibit reduced precipitation, gelling, and/or crystallization of paraffin inhibitor from the hydrocarbon media, when the media are subjected to sustained temperatures between 4 C. and 60 C.

The present invention relates to novel uses of corrosion inhibitors in fuels and lubricants.