Disclosed are polyurethane-foam forming compositions, rigid polyurethane foams and methods for their production, as well as to composite articles comprising such foams sandwiched between facer substrates, including use of such composite elements for side-wall and/or roof insulating elements for refrigerated tractor trailers. The rigid polyurethane foams are produced from an isocyanate-reactive component comprising: (1) a polyol blend; (2) a halogenated hydroolefin; (3) a surfactant; (4) water; and (5) a tertiary amine catalyst composition.

Polyurethane/polyisocyanurate foam insulation described herein is derived from a composition that contains an organic polyisocyanate, an isocyanate reactive material containing at least about 20% by weight, based on the total weight of the composition, of an aromatic polyester polyol, a hydrocarbon blowing agent, a first catalyst selected from the group consisting of a carboxylate salt of an alkali metal, a carboxylate salt of an alkaline earth metal, a carboxylate salt of a quaternary ammonium, and combinations thereof, and a second catalyst comprising a non-reactive tertiary amine, wherein a molar ratio of the first catalyst to the second catalyst is less than about 1.25, the composition gels quickly, and the composition has an isocyanate index greater than about 175. Such an insulating foam has a ratio of thermal conductivity at 75 F. to thermal conductivity at 25 F. between about 0.98 and about 1.10.

A two-part curable urethane composition comprising a main agent (A) and a curing agent (B), wherein the main agent (A) contains a urethane prepolymer (a), an isocyanurate-modified polyisocyanate compound (b), and a silane coupling agent (c) at a specified ratio by mass; and the curing agent (B) contains a polyether polyol (d), a polyether polyol having 4 or more hydroxy groups (e), and an amine catalyst (f) at a specified ratio by mass.

The present invention relates to aqueous, curable composition, comprising or consisting of A) at least one uretdione prepolymer, which comprises at least one uretdione group, and which is obtainable by reacting A1) at least one uretdione polyisocyanate having an isocyanate functionality of at least 2.0, whereby said uretdione polyisocyanate is obtained from at least one aliphatic polyisocyanate, with A2) at least one compound comprising at least one Zerewitinoff-active group, and A3) at least one reactant, which comprises at least one Zerewitinoff-active group and being different from A2 or which is H.sub.2O, preferably in the presence of at least one catalyst, to obtain the uretdione prepolymer, wherein the prepolymer has an acid number of at most 4 mg KOH/g, preferably determined according to DIN EN ISO 2114:2002-06 as 37 wt. % aqueous dispersion; and B) optionally at least one compound, which comprises at least one Zerewitinoff-active group; and C) at least one azolate-compound. Furthermore, the present invention pertains to a process for curing the composition of the present invention on a substrate and a cured article obtained by this process. Moreover, the invention relates to the use of the compositions of the present invention for coatings, adhesives and/or sealants.

The present technology provides a polyurethane composition including: a main agent; and a curing agent, wherein the main agent includes a urethane prepolymer having an isocyanate group, a morpholine compound having one morpholine ring, and an ether compound having two dimethylamino groups, and the curing agent includes an active hydrogen compound having two or more active hydrogen-containing groups in one molecule.

The present technology provides a one-part moisture-curable polyurethane composition excellent in long-term adhesion against weather resistance and vibration. According to the embodiment of the present technology, a one-part moisture-curable polyurethane composition includes: a urethane prepolymer having an isocyanate group; a morpholine compound having one morpholine ring; and an ether compound having two dimethylamino groups.

The present technology is to provide a one-part moisture-curable polyurethane composition having excellent adhesion to an adherend (coated plate), and a method for producing such a composition. The present technology is a one-part moisture-curable urethane composition including a preliminary composition obtained by mixing a urethane prepolymer, an aliphatic isocyanate A, and an aminosilane compound B, and a catalyst; and a method for producing such a composition.

A polymerizable composition for an optical material of the present invention includes (A) a compound of which pKa value is 1 to 9, (B) a di- or higher functional iso(thio)cyanate compound, and (C) a di- or higher functional active hydrogen compound.

The present invention relates to a process for preparing a thermoplastic copolymer from polycaprolactam and thermoplastic polyurethane (TPU), to thermoplastic copolymers thus obtained and to shaped articles formed from copolymers of this type.

The present disclosure is related to a catalyst for PIR/PUR foam production comprising a compound having the general formula (I) wherein R.sub.1 and R.sub.2 are independently selected from a C.sub.1-C.sub.18 straight-chain or branched alkyl group, unsubstituted or substituted with one or more hydroxyl, amino or aminoalkyl groups, or R.sub.1 and R.sub.2, taken together, form a 5- or 6-membered ring or 7-membered bicyclic structure, one of the members of the ring or bicyclic structure being X, wherein X is selected from CH.sub.2, O, S, NCH.sub.3 or NCH.sub.2COOM, wherein R.sub.3 and R.sub.4 are independently selected from hydrogen or a C.sub.1-C.sub.4 straight-chain or branched alkyl group and wherein M is an alkali metal ion or a quaternary ammonium ion, as well as to a process for production of said compound and uses thereof and to a process for the production of PIR/PUR foam or flexible foam in the presence of the catalyst of the present disclosure.

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