Soy-based high temperature products, or thermoset resins, are produced by solvent free polymerization of soy polyols and polyisocyanates at room temperature. The ratio of isocyanate equivalents to polyol equivalent used in the synthesis is greater than or equal to 3. The invented soy-based products are polyisocyanurate solid materials with excellent stability at high temperature. Heat resistance of the material is influenced by ratio of soy polyol and polyisocyanate.

A blocking agent dissociation catalyst for blocked isocyanates comprising a nitrogen-containing compound represented by Formula (1a): ##STR00001##
wherein D is represented by Formula (2): ##STR00002##
wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and a are as described in the specification.

Recovery times and/or airflow of flexible polyurethane foam is increased by including certain tackifiers in the foam formulation. The tackifiers are characterized in being incompatible with polyol or polyol mixture used to make the foam, having a viscosity of at least 5,000 centipoise at 25 #C and having a glass transition temperature of at most 20 #C. The tackifier is pre-blended with certain monols to form a lower-viscosity blend that is combined with one or more other polyols and a polyisocyanate to form a reaction mixture for producing a polyurethane foam.

The present invention provides an allophanate polymer system made by a method comprising combining a neutralized polyol with a polyuretdione resin in the presence of a reactive reducer comprising a reducing agent and a tertiary amine catalyst to produce a clear-coat, and contacting the clear-coat with a basecoat comprising a tertiary amine catalyst. The reaction between the polyol and the polyuretdione will proceed after the reactive reducer reduces the viscosity of the one component clear-coat formulation to appropriate levels. The inventive allophanate polymer system is particularly applicable in providing coatings, adhesives, castings, composites, and sealants with good performance.

Disclosed is a polyurethane foam formulation based on conventional polyether and polyester polyols based on renewable raw materials, with in particular MDI, for the production of preferably viscoelastic PUR moulded foams and sound insulations with foams based thereon.

Provided by the present invention is a two-component adhesive which includes a first composition and a second composition, in which the first composition contains: a complex derived from an organoborane and a first compound having a first group capable of undergoing an addition reaction to an isocyanate group; and a second compound having a plurality of hydroxy groups, and the second composition contains: a third compound having a plurality of isocyanate groups; a fourth compound having a polymerizable group; and a dehydrating agent. Provided that a mass of the fourth compound in the second composition is X, and that a total mass of the second compound in the first composition and the third compound in the second composition is Y, a value X/(X+Y) is preferably no less than 0.4 and no greater than 0.85.

The adhesive system of the invention is especially useful in bonding replacement windows into vehicles. They allow for sufficient working time while still realizing a fast drive away time. The adhesive system is comprised of a moisture curable adhesive and a cure accelerator that may be applied using a simple single caulk gun and may be applied at ambient temperatures such as −10° C. and about 45° C. The cure accelerator is comprised of a polyol having a backbone that has at least one amine in the backbone. The moisture curable adhesive typically is comprised of an isocyanate terminated prepolymer.

A polyurethane composition raw material liquid agent comprises a polyol or an isocyanate, and a filler. The polyurethane composition raw material liquid agent has a viscosity at 25° C. and a rotation speed of 60 rpm of 950 mPa.Math.s or less, and is filled in at least one cartridge-like container of a caulking gun that includes two cartridge-like containers and is capable of mixing two components.

Disclosed are polyurethane-based foams. The foams may have one or more vicrucidal/bactericidal agents. The foams may be used as filters that capture and/or inactivate viral particles, such as, virions associated with COVID-19. Also described are methods of making the foams and methods of using the foams.

Provided are a polyol composition in which hard caking does not occur when stored for a long period of time, and a polyurethane foam using the same.

The polyol composition comprises a polyol compound, a foaming agent, a filler, and a metal oxide fine particle, the foaming agent including a hydrofluoroolefin, and the metal oxide fine particle having a count number ratio of OH ions of a metal constituting the metal oxide fine particle with respect to a total count number of all ions measured using time-of-flight secondary ion mass spectrometry of 0.1 or less.