A reactive composition for making a PIR comprising foam at an isocyanate index of at least 120, said composition comprising at least an isocyanate composition comprising one or more isocyanate compounds, an isocyanate-reactive composition comprising one or more isocyanate-reactive compounds, at least one PIR promoting catalyst, at least one physical blowing agent with a lambda gas ≤12 mW/m.Math.K at 10° C., at least one CO.sub.2 scavenging compound selected from at least one epoxy compound, and optionally a catalyst promoting epoxy reaction with CO.sub.2 characterized in that the amount of isocyanate-reactive compounds in the reactive composition is at least 10 wt % calculated on the total weight of the reactive composition, or at least more than the amount of epoxy compounds and the molar amount of epoxy compounds in the reactive composition is at least 7.8 times higher than the molar amount of CO.sub.2 formed by the water present in the reactive composition after reaction with isocyanates.

A polyester polyol comprising at least one esterified unit of formula (I) ##STR00001##
wherein L is a difunctional aliphatic group having from two to six carbon atoms and R is a C.sub.1-C.sub.4 alkyl group.

Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyol blend, a blowing agent composition, and a polyisocyanate. The polyol blend includes an aromatic amine-initiated polyether polyol, a saccharide-initiated polyether polyol, and an aromatic polyester polyol and has a content of —C.sub.2H.sub.4O— units of 3 to 6% by weight, based on the total weight of the polyurethane foam-forming composition. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide-generating chemical blowing agent.

This invention is a photon-interactive Gaussian surface lens method means that converts incident photons from a single or a plurality of wide band gap semiconductor class light emitting diode dies, into a secondary emission of photons emanating from a composite photon transparent colloidal stationary suspension of quantum dots, high efficiency phosphors, a combination of quantum dots and high efficiency phosphors and nano-particles of metal, silicon or similar semiconductors from the IIIB and IVB Group of the Periodic Table and any nano-material and/or micro/nano spheres that responds to Rayleigh Scattering and/or Mie Scattering; and a plurality of quantum dots in communication with said nano-particles in said suspension. The apparatus and methods according to the present invention provides in improved narrow pass-band of red, green, and blue photon efficiency over phosphor based conversion. Utilizing the invention's methodology, the white resultant colour temperature is stabilized against internal semiconductor thermal fluctuations or ambient thermal variations.

Provided are a solvent-free laminating adhesive which enables a laminate after lamination to have a good appearance, and which enables a laminate to maintain a good appearance even when the laminate is formed by high-speed lamination; a cured product of the solvent-free laminating adhesive; a polyol composition for lamination adhesives, which serves as one component of the adhesive; and a multilayer film which uses the adhesive. A solvent-free laminating adhesive composition contains, as essential components, (A) a polyisocyanate component and (B) a polyol component. In the solvent-free laminating adhesive composition, the polyol component (B) contains (b1) castor oil or a hydroxyl group-containing castor oil derivative, and (b2) a polyalkylene glycol having a number average molecular weight of 2,500 to 7,000.

The present invention relates to a poly(ester-urethane), to a poly(ester-urea-urethane), and also to aqueous dispersions of these and to their uses in aqueous coatings, adhesives or sealants, in particular as binder in paints or varnishes.

The invention relates to the use of aqueous dispersion adhesives on the basis of a mixture of aqueous polyurethane or polyurethane-urea dispersions for bonding foam substrates according to the spray coagulation method.

Disclosed are processes for in-mold coating of a plastic substrate. The processes include: (a) molding a plastic substrate in a first mold cavity of a mold comprising at least two cavities to form a molded plastic substrate; (b) introducing the molded plastic substrate into a second mold cavity of the mold; (c) introducing a coating composition into the second mold cavity containing the molded plastic substrate in order to coat the substrate, the coating composition comprising: (i) a polymer comprising isocyanate-reactive groups; and (ii) a polyisocyanate; (d) curing the composition in the second mold cavity; and (e) opening the mold cavity.

There is provided an adhesive composition comprising at least 50 wt % of an aqueous dispersion of an amorphous polyurethane having a Tg below 25° C.; and a water dispersible cross-linker, where the adhesive composition has a peel retention of greater than or equal to 5% according to the Water/IPA Exposure Test.

A first aspect of the present invention is an adhesive composition comprising one or more polyisocyanates and one or more phosphate-functional polyols. A second aspect of the present invention is a method of bonding two substrates together to form a bonded article, said method comprising the steps of applying a layer of the composition of the first aspect to one of said substrates, contacting said layer of the composition of claim 1 to a second substrate, and curing or allowing to cure the composition of claim 1. A third aspect of the present invention is a bonded article formed by the method of the second aspect.