Polyurethane foams that are hydrophilic but nonetheless have low compression sets are made from a combination of MDI and TDI prepolymers, water, and a polymer polyol. The foams optionally are made incorporating a phase change material in the foam formulation. The phase change material does not require encapsulation.

A two-component polyurethane compositions including (i) a polyol component A comprising a tri- or higher functional polyol P1 having an OH equivalent weight of from 60 g/mol to 250 g/mol and a di- or tri-functional polyether or polyester polyol P2 which is different from the polyol P1; and (ii) an isocyanate component B comprising at least one polyisocyanate I. Polyurethane compositions have surprisingly been found to be suitable for 3D printing processing, where they provide printed 3D objects with reduced tackiness even shortly after the printing. In addition, the invention provides processes for the production of three dimension objects form such compositions as well as three dimensional objects prepared accordingly and the use of corresponding compositions in 3D printing processes.

A moisture-curable composition, including: a) at least one polyurethane polymer P having isocyanate groups; b) at least one blocked polyamine BA having blocked, hydrolytically activatable amino groups; and c) at least one monoamine MA of formula (V),

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where R.sup.a represents a linear, cyclic, or branched alkyl or alkenyl radical or optionally substituted aryl radical with 1 to 12 C atoms and optionally including ether oxygen atoms; R.sup.b and R.sup.c either independently represent a rest R.sup.a or a hydrogen atom, where at least one of R.sup.b and R.sup.c is a hydrogen atom, or R.sup.b and R.sup.c together with the N atom of monoamine MA form an aldimine group that under influence of water hydrolyzes to a aldehyde and an amine R.sup.a—NH.sub.2; wherein polymer P is the reaction product of 2,4- and/or 2,6-toluylene diisocyanate (TDI) and at least one polyol, wherein the polyol has an average functionality of >2.

Processes for producing filled polyol compositions, such as polymer polyol compositions. The processes include reacting a polymerizable composition in the presence of a composition comprising a base polyol and an amine antioxidant, in which the amine antioxidant comprises a secondary diarylamine, a primary aromatic amide, a triazole, or a combination thereof.

A (poly)ol block copolymer of general structure B-A-(B)n, wherein block A is a polycarbonate block or polyester block, n=t−1 and t=the number of reactive end residues on block A, wherein block B is a polyethercarbonate block and wherein >70% of the copolymer chain ends are terminated by primary hydroxyl groups, and a process of producing such copolymers and products incorporating such copolymers.

A description is given of the use of compounds having n 2-oxo-1,3-dioxolane-4-carboxamide units as a reactive component in 2-component adhesives, especially for preparing hydroxypolyurethanes or hydroxypolycarbonates for adhesives applications, where n is a number greater than or equal to 2. A description is also given of corresponding two-component adhesives and adhesive bonding methods. Employed preferably as a second component of the two-component adhesive is a polyfunctional curing agent compound which is preferably selected from polyamines which have two or more amine groups and polyols which have two or more alcoholic hydroxyl groups.

A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component and an isocyanate-reactive component that includes at least a polyol component, an additive component, and a preformed aqueous polymer dispersant. The mixture includes 50.0 wt % to 99.8 wt % of the polyol component, 0.1 wt % to 49.9 wt % of the additive component, and 0.1 wt % to 6.0 wt % of the preformed aqueous polymer dispersant. The aqueous polymer dispersant has a pH from 6.0 to 12.0 and includes from 5 wt % to 60 wt % of a polymeric component and from 40 wt % to 95 wt % of a fluid medium. The polymeric component includes at least one base polymer derived from 20 wt % to 100 wt % of at least one hydrophilic acid monomer having at least one carbonyl group, phosphate group, phosphonate group, or sulfonyl group, and optionally derived from at least one hydrophobic terminally unsaturated hydrocarbon monomer.

Composites having a polymer or natural leather skin layer and a polyurethane foam layer are made in a molding process. The polyurethane foam layer is made from a foam formulation that includes certain polyester polyols. The presence of the polyester polyol improves flow characteristics of the foam formulation. The foam so produced has unexpectedly low quantities of VOCs.

The present disclosure provides a two-component solventless adhesive composition comprising a polyol component and an isocyanate component. The polyol component comprises a phosphate functional compound, and at least one polyol selected from polyester, polyether, and the combination thereof; and the isocyanate component comprises isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from polyester, polyether, and the combination thereof.

A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R.sup.1).sub.1(R.sup.2).sub.1(R.sup.3).sub.1(R.sup.4).sub.0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R.sup.1, R.sup.2, and R.sup.3 each includes a same fluoroalkyl-substituted phenyl group, and optional R.sup.4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.