The present invention discloses an acrylate oligomer, the acrylate oligomer is obtained by a reaction of isocyanate group-terminated oligomer and formate-terminated ethylene glycol methacrylate. After the acrylate oligomer provided by the present invention is photocured, the molecular structure, cross-linking density and other network structure characteristics of the acrylate oligomer can be changed through specific post-processing. Since the formate component formed after heat treatment has no water absorption and has a low glass transition temperature, the final material obtained after heat treatment has a lower water absorption rate and glass transition temperature. The present invention also provides a preparation method and an application method of the acrylate oligomer.

The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and an inorganic filler. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.

HCFO-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid PUR-PIR foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in discontinuous foam panel applications. The isocyanate-reactive composition includes a polyol blend, a blowing agent composition, and a tertiary amine catalyst. The polyol blend includes: (1) an aromatic polyester polyol having a functionality of 1.5 to less than 2.5 and an OH number of 150 to 360 mg KOH/g; (2) an aromatic polyester polyol having a functionality of at least 2.5 and an OH number greater than 360 mg KOH/g, which is present in an amount of at least 10% by weight, based on the total weight of the aromatic polyester polyol in the polyol blend; and (3) an amine-initiated polyether polyol having an OH number of at least 500 mg KOH/g and a functionality of 2.5 to 4. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide generating chemical blowing agent.

A thermally-conductive structural adhesive for new energy power batteries, including: composition A including 3.3-14 wt. % of a block polymerized telechelic carboxyl compound and/or a block polymerized telechelic amino compound; 0.1-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3.0 wt. % of a flame retardant agent; and composition B including 3.3-14 wt. % of a block polymerized telechelic isocyanate compound and/or a block polymerized telechelic epoxy compound; 0-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of a curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3 wt. % of a flame retardant agent. The composition A and the composition B are mixed evenly in a weight or volume ratio of 1:(0.25-2) and cured to obtain the thermally-conductive structural adhesive. A preparation of the thermally-conductive structural adhesive is also provided.

This invention relates to rigid polyurethane foams which are co-blown with a mixture of a hydrocarbon blowing agent and a halogenated olefin blowing agent. This invention also relates to a process for preparing these rigid polyurethane foams, and to an isocyanate-reactive component containing a polyol blend and the mixture of blowing agents. Phase stable isocyanate-reactive blends are also described.

Provided are a waterborne polyurethane emulsion for ultra-thin polyurethane condoms having a low modulus and a high strength, and a method for preparing the emulsion, wherein the waterborne polyurethane emulsion comprises 15 to 18 parts by mass of a macromolecular diol, 4 to 6 parts by mass of a diisocyanate, 0.6 to 0.9 parts by mass of a hydrophilic chain extender, 0.4 to 0.8 parts by mass of a small-molecule chain extender, and the like. The prepared waterborne polyurethane emulsion is characterized by a low modulus, a high strength, and high resilience.

An amino silicone oil-modified elastomer material includes Component A and Component R. Component A includes isocyanate prepolymer obtained through reaction of polyol and isocyanate, and the isocyanate prepolymer has a —NCO content of 22-30%; Component R includes the following components in parts by weight: 45-60 parts of polyether amine, 1-6 parts of liquid amine chain extender, 1-10 parts of polysulfide rubber, 2-8 parts of nano silica, and 3-8 parts of amino silicone oil. The elastomer material of the invention ensures the elasticity of the polymer while improving mechanical properties. Moreover, it can improve elongation, wear resistance and water resistance of the polyurea material.

An elastomer material includes at least two components; the first component includes isocyanate prepolymer obtained through reaction of polyol and isocyanate, and its —NCO content is 22-30%; the second component includes 50-70 parts of polyether amine, 2-10 parts of liquid amine chain extender, 5-15 parts of hydroxyl-terminated polybutadiene, and 1-15 parts of hybrid hard segment material; the hybrid hard segment material includes one or more of nano titanium dioxide, nano aluminum oxide and nano silica. Through adjusting the —NCO content of the isocyanate prepolymer, increasing the hard segment content, and combining with the components in the second component, the invention ensures the elasticity of the polymer while improving its mechanical properties, and also improves the electrical insulation and wear resistance of the material.

The presently claimed invention is directed to a polyurea-polyetheramine copolymer obtained by reacting at least one polyisocyanate (A) and at least one isocyanate reactive component (B); wherein the at least one polyisocyanate (A) has an NCO functionality of at least ≥2.0; and the at least one isocyanate reactive component (B) is a polyetheramine having at least two secondary amine functional groups and at least one hydroxy functional group.

A two-part curable urethane-based composition comprising a main agent (A); and a curing agent (B), wherein the main agent (A) contains a urethane prepolymer (a), an isocyanurate modified product of a polyisocyanate compound (b), and a silane coupling agent (c) in a specified ratio, the curing agent (B) contains a polyol (d) having a hydroxyl value of 50 to 500 mgKOH/g and an amine catalyst (e) in a specified amount, a mixing mass ratio of the main agent (A) to the curing agent (B) is 3:1 to 10:1, and an equivalent ratio of NCO group/OH group in the main agent (A) and the curing agent (B), respectively, is 1.0 to 5.0.