A gate insulation film composed of a polymer compound containing at least one repeating unit selected from the group consisting of a repeating unit of formula (2) and a repeating unit of formula (3); a repeating unit of formula (4) and a repeating unit of formula (1), or composed of a composition containing the polymer compound, wherein the molar ratio of the repeating unit of formula (4) to the sum of the repeating unit of formula (2) and the repeating unit of formula (3) is 50/100 to 200/100 with the total charging amount (molar quantity) of the repeating unit of formula (2) and the repeating unit of formula (3) being 100 and the content of the repeating unit of the following formula (1) is 75% by mol or more with the total content of all repeating units in the polymer compound being 100% by mol.

A blocking agent dissociation catalyst for blocked isocyanates comprising a nitrogen-containing compound represented by Formula (1a): ##STR00001##
wherein D is represented by Formula (2): ##STR00002##
wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and a are as described in the specification.

The invention provides a laminated polyester film that is highly transparent, is resistant to blocking, and has excellent adhesion to a hardcoat layer and UV ink. The laminated polyester film contains a polyester film substrate and a coating layer on at least one surface of the polyester film substrate. The coating layer is formed by curing a composition containing a urethane resin with a polycarbonate structure, a crosslinking agent, and a polyester resin. The maximum value of a nitrogen element distribution curve based on element distribution measurement of the coating layer in the depth direction is present in the vicinity of the surface of the coating layer on a side opposite to the polyester film substrate. The polycarbonate structure is present in a suitable amount at the surface of the coating layer on a side opposite to the polyester film substrate.

The subject matter is a new composition comprising at least one hydroxyl-group containing resin, at least one nitroso-containing compound or at least one nitroso precursor compound, at least one blocked isocyanate and at least one crystallization germ suitable as primer or coating for rubber to substrate bonding, which provides a scratch resistant surface, when applied, and excellent adhesion and steam resistance for rubber to substrate bonds. These compositions can especially be used as one coat systems.

Provided is a polymer capable of providing a coating film that has good initial adhesiveness to a base material and good adhesiveness thereto after a pressure cooker test, and has excellent abrasion resistance as determined by a falling sand abrasion test. The polymer includes a perhaloolefin unit, a vinyl ester unit that contains neither a hydroxy group nor an aromatic ring; and a hydroxy group-containing monomer unit. The polymer has a hydroxyl value of 110 mgKOH/g or greater.

A water-repellent composition containing (1) a polymer having 2-100 wt %, with respect to the polymer, of a repeating unit derived from an amide group-containing monomer (a) represented by the following formula

##STR00001##

[wherein R.sup.1 is an organic moiety having an ethylenically unsaturated polymerizable group, R.sup.2 is a C.sub.7-30 hydrocarbon group, and R.sup.3 is a C.sub.1-5 hydrocarbon group], (2) a co-agent containing at least one co-agent compound selected from the group consisting of a blocked isocyanate compound, a melamine resin, a silicone polymer, a wax, an acetylene-based emulsifier, and a polyoxyalkylene group-containing emulsifier, and (3) a liquid media. Preferably, the water-repellent composition includes no fluoroalkyl group-containing monomer, and preferably no fluorine-containing monomer. Also disclosed is a method for producing the water-repellent composition, a method for treating a substrate with the water-repellent composition, and a method for producing a treated textile product which includes treating a textile product with the water-repellent composition.

[Purpose] To provide a thermosetting composition with which it is possible to obtain paint films which not only display stain resistance for a short period after application, but with which excellent stain resistance can also be expected for longer periods, and which comply with the paint film properties required for painted steel sheet such as water resistance and bending workability, and have high environmental protection and safety qualities. [Solution] The present invention relates to a thermosetting composition, wherein it contains, as essential components, (A) a polyester resin of number average molecular weight 1,000-10,000 and hydroxyl value 5-200 mg KOH/g and, (B) 0.5 to 2.0 equivalents, relative to the hydroxyl groups of the aforesaid component (A), of a compound (B) which is a blocked aliphatic polyisocyanate compound having reactivity to the hydroxyl groups of component (A), wherein the blocks are methyl ethyl ketone oxime and/or ε-caprolactam, (C) 0.05 to 5 mass %, relative to the total resin solids mass of component (A) and component (B), of an organotin compound represented by the following general formula (I) [Chem.1] R.sup.1—Sn-(O)C═(O)—R.sup.2).sub.3 (I) (R.sup.1 in the formula represents an organic group wherein it has 1-24 carbons, and is directly bound to the Sn atom via a C atom. R.sup.2 represents an organic group wherein it has 1-24 carbons, and is directly bound to the C atom of the (C═O) via a C atom), and (D) 0.5 to 50 mass %, relative to the total resin solids mass of component (A) and component (B), of an organosilicate represented by the following general formula (II) and/or a condensation product thereof [Chem.2] (R.sup.3, R.sup.4, R.sup.5 and R.sup.6 in the formula are each a hydrogen atom or 1-10 carbon organic group, and may be the same or different, n is 1). ##STR00001##

A method for producing a shaped body, containing: producing the shaped body from a composition by a powder-based layer construction process, wherein the composition contains a thermoplastic polyurethane, obtained by reacting a polyisocyanate composition and a polyol composition, the thermoplastic polyurethane is solid at least in a temperature region below 50° C. and has end groups selected from the group consisting of first end groups and second end groups, wherein the first end groups are optionally eliminated at a first temperature, and the second end groups are optionally eliminated at a second temperature, to form reactive groups on the thermoplastic polyurethane that optionally enter into a reaction with functional groups of the thermoplastic polyurethane or functional groups of a further component of the composition, and wherein the first temperature and the second temperature are each greater than or equal to 60° C.

A blocking agent dissociation catalyst for blocked isocyanates comprising a nitrogen-containing compound represented by Formula (1a):

##STR00001##

wherein D is represented by Formula (2):

##STR00002##

wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and a are as described in the specification.

The present invention relates to the production of plastics by crosslinking of blocked polyisocyanates. The plastics obtainable are characterized in that they are substantially free of urethane groups and the crosslinking of the monomers is predominantly effected by isocyanurate groups.