The present invention relates to ultralow monomer PU prepolymers containing free NCO groups obtainable from polyols, diisocyanates and NCO-reactive compounds, obtainable by reacting at least one polyol with at least one polyisocyanate, wherein the at least one polyisocyanate is used in molar excess relative to the hydroxyl groups of the at least one polyol to obtain a polyurethane prepolymer containing free isocyanate groups; and adding at least one compound having at least one H-acidic functional group to the polyurethane prepolymer containing free isocyanate groups in an amount such that the molar ratio of the free isocyanate groups to H-acidic functional groups (NCO:XH ratio) is 2 to 15, preferably 2.5 to 10, more preferably 3 to 8. Also encompassed are methods for its production, laminating adhesives containing said prepolymer, methods of bonding substrates and the use of the described adhesives for laminating two or more films.

The present invention relates to ultralow monomer PU prepolymers containing free NCO groups obtainable from polyols, diisocyanates and NCO-reactive compounds, obtainable by reacting at least one polyol with at least one polyisocyanate, wherein the at least one polyisocyanate is used in molar excess relative to the hydroxyl groups of the at least one polyol to obtain a polyurethane prepolymer containing free isocyanate groups; and adding at least one compound having at least one H-acidic functional group to the polyurethane prepolymer containing free isocyanate groups in an amount such that the molar ratio of the free isocyanate groups to H-acidic functional groups (NCO:XH ratio) is 2 to 15, preferably 2.5 to 10, more preferably 3 to 8. Also encompassed are methods for its production, laminating adhesives containing said prepolymer, methods of bonding substrates and the use of the described adhesives for laminating two or more films.

A curable composition for making polyisocyanurate comprising products obtained by combining and mixing at an isocyanate index of at least 100 at least a polyisocyanate composition, an isocyanate reactive composition comprising at least 50 mol % diols and a toughening agent comprising acrylic block copolymers.

An adhesive film for polarizing plates, a polarizing plate including the same, and an optical display apparatus including the same are provided. An adhesive film for polarizing plates is formed of an adhesive composition including a (meth)acrylic copolymer, an isocyanate curing agent, a metal chelate curing agent, and an antistatic agent, and has a surface resistance difference ΔSR of 1.0 (log(Ω/□)) or less, as calculated by Equation 1 and, in Equation 1, SR1 is 10 (log(Ω/□)) or less.

The present invention relates to a process for producing a rigid polyurethane-polyisocyanurate foam C, comprising the step of reacting (i) an isocyanate-terminated prepolymer B with (ii) an activator component A comprising at least one trimerization catalyst A1 and at least one blowing agent A3 in a reaction mixture to form a foam, characterized in that—there is used an isocyanate-terminated prepolymer B obtained from a reaction of an isocyanate B1 having a mean isocyanate functionality of from ≧2.3 to ≦2.9 with a polyol component B2, and—the activator component A comprises water as the blowing agent A3 in an amount of from ≧5 wt. % to ≦50 wt. %,—the isocyanate index in the reaction mixture is in a range of from ≧400 to ≧500, and—the isocyanate content of the prepolymer B is in a range of from ≧21 wt. % to ≦30 wt. %, based on the total mass of the prepolymer B, and—wherein in the reaction of the prepolymer B and the activator component A a conversion contribution to polyisocyanurate of ≦75% is achieved. Rigid foams C so produced have good flame retarding properties while at the same time having good insulating properties and stability properties. The present invention relates further to a rigid polyisocyanurate foam C produced by the process according to the invention, to the use of such a rigid polyisocyanurate foam C in the production of heat-insulating structural components, and to a heat-insulating structural component comprising such a rigid polyurethane-polyisocyanurate foam.

Provided is a polyisocyanate mixture including: a triisocyanate compound (A) represented by Formula (I); and polyisocyanate (B) obtained from at least one diisocyanate selected from the group consisting of aliphatic diisocyanate, alicyclic diisocyanate, and aromatic diisocyanate. ##STR00001## (In Formula (1), a plurality of Y.sup.1's each independently represent a single bond or a divalent hydrocarbon group having 1 to 20 carbon atoms which may have an ester structure and/or an ether structure. A plurality of Y.sup.1's may be the same as or different from one another. R.sup.1 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 12 carbon atoms.)

The present invention relates to a PVC plastisol composition comprising at least one vinyl chloride polymer selected from polyvinylchlorides and copolymers of vinyl chloride with one or more monomers; at least one plasticizer; at least one epoxy resin; and at least one isocyanate resin blocked with cardanol. The PVC plastisol composition of this invention provides strong adhesion to the surface of various metals or various undercoats of metals by thermal treatment for a short time at 100° C.-200° C. and is excellent in storage stability. In addition, it offers good rheological properties with improved yield value dosing and viscosity stability during applications compared to the nonylphenol blocked isocyanate PVC adhesion promotor.

The application relates to a two-component composition comprising: a composition A comprising: at least one polyurethane P having at least two terminal methacrylate functions, the polyurethane content P being at least 6% by weight relative to the total weight of composition A; at least one reducing agent; and at least one methacrylate monomer; a composition B comprising: at least one oxidizing agent; and optionally at least one methacrylate monomer,
said polyurethane P being obtained by a method comprising: E1) a step of preparing an NCO-terminated polyurethane, comprising the polyaddition reaction between: i) at least one polyisocyanate; and ii) at least one polyol; E2) reacting the product formed at the end of step E1) with at least one methacrylate monomer M having at least one hydroxyl function.

A method of making an isocyanurate polymer is disclosed. An isocyanate including at least one of an aromatic isocyanate and an aliphatic isocyanate is provided. A trimerization catalyst including at least one of an amine catalyst, an organometallic compound, and an imidazole compound is provided. A reaction mixture that is substantially free of reactive hydrogen is formed by mixing less than about twenty percent by total weight of said reaction mixture of an epoxide with said isocyanate. The trimerization catalyst is mixed with the reaction mixture. The reaction mixture is cured to produce a polymer composition including a reaction product of two or more isocyanates.

A trimerization catalyst composition comprising a trimerization catalyst compound selected from one or more organic metal salt, preferably alkali or earth alkali metal salts, and one or more compounds selected from compounds which comprise a carboxamide group having the structure —CO—NH.sub.2 and/or from compounds which comprise a group having the structure —CO—NH—CO— is disclosed.

Further a stable polyisocyanate composition comprising the catalyst composition and a process for making the polyisocyanate composition is disclosed.

A curable polyisocyanate composition is obtained comprising the catalyst composition, a polyisocyanate composition, an epoxy resin and optionally a polyol/monool composition and a polyisocyanurate comprising material made by allowing the curable composition to react at elevated temperature and a process for making the polyisocyanurate comprising material.