A method of three-dimensional stereolithography printing a thiourethane polymer part using the vat resin. Adding a resin to a vat of a three-dimensional stereolithography printer, the resin a liquid mixture including: a first type of monomer including two or more thiol functional groups, a second type of monomer including two or more isocyanate functional groups, a photolatent base, an anionic step-growth polymerization reaction inhibitor and a light absorber. The photolatent base is decomposable upon exposure to a light to form a non-nucleophillic base catalyst having a pKa greater than 7. The anionic step-growth polymerization reaction inhibitor has an acidic group configured to form an acid-base pair with the non-nucleophillic base. The light absorber has an absorbance in the liquid mixture that is greater than an absorbance of the photolatent base at a wavelength of the light used for the exposure.

Provided herein according to embodiments is a prepolymer compound of formula I: ##STR00001##
and a prepolymer compound of formula II: ##STR00002##
A polymerizable liquid composition comprising the prepolymer compound, methods of use in forming a three-dimensional object, and objects produced are also provided.

A branched polymer containing silane groups having an average of at least 2.1 silane groups per molecule, from the reaction of (i) a polymer containing isocyanate groups and having an NCO content ranging from 0.7% to 4% by weight, obtained from the reaction of at least one monomeric diisocyanate with at least one polyether polyol in a molar NCO/OH ratio of at least 1.5/1, (ii) with at least one amino-, mercapto- or hydroxysilane, in a stoichiometric ratio of at least 1 mol of amino-, mercapto- or hydroxysilane per molar equivalent of isocyanate groups. The polymer containing silane groups is storage-stable, liquid at room temperature and easily handled, and permits curable compositions having excellent processability, rapid curing, high strength coupled with good extensibility, and good thermal stability. It is particularly suitable as a constituent of moisture-curable sealants, adhesives or coatings, additionally including a further, in particular linear, polymer containing silane groups.

The present invention relates to an asphalt composition comprising a thermosetting reactive compound.

The present invention relates to a multi-aziridine compound having: a) at least 2 of the following structural units (A) whereby R.sub.1 is H; R.sub.2 and R.sub.4 are independently chosen from H, a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; R.sub.3 is chosen from a linear group containing from 1 to 8 carbon atoms and optionally containing one or more heteroatoms, a branched or cyclic group containing from 3 to 8 carbon atoms and optionally containing one or more heteroatoms, phenyl, benzyl, or pyridinyl; or R.sub.2 and R.sub.3 (in case R.sub.2 is different than H) may be part of the same cyclic group containing from 3 to 8 carbon atoms; R′ and R″ are independently H or an aliphatic hydrocarbon group containing from 1 to 12 carbon atoms; and b) a molecular weight of at least 600 Daltons, wherein the molecular weight is determined using MALDI-TOF mass spectrometry according to the description.

A curable resin composition that has low viscosity and forms a cured product having excellent mechanical physical properties, a cured product, and a three-dimensional object The curable resin composition contains a urethane resin (A) containing a (meth)acryloyl group, and a monofunctional (meth)acrylate compound (B1) and/or a bifunctional (meth)acrylate compound (B2), in which the urethane resin (A) is formed using, as essential reaction raw materials, a polyester polyol (a1), a polyisocyanate (a2), and a compound (a3) containing a hydroxyl group and a (meth)acryloyl group, and the polyester polyol (a1) is formed using, as essential reaction raw materials, a glycol (a1-1) containing a hydrocarbon group in a side chain, and a polycarboxylic acid (a1-2).

The invention relates to polymerizable compositions that are suitable for preparing polyisocyanurate-based plastics and have an extended worklife as compared to the compositions conventionally used for this purpose.

1) A sealant composition comprising: from 3% to 80% of a polymer (A) comprising an alkoxysilane group, at least 25% of a carbonate filler (B), and from 0.5% to 20% of a polysiloxane resin (C) comprising, as groups directly linked to the silicon atom: at least one phenyl group; and at least one group chosen from a hydroxyl and an aminoalkylene group; and from 0.1% to 1% of a crosslinking catalyst (D);

said percentages being expressed by weight on the basis of the total weight of said composition.

2) The use of said composition as adhesive, sealant or coating.

A solvent-based polyurethane retort adhesive system for producing laminates including: (A) at least one isocyanate compound, Component A, comprising: a blend of: (i) at least one aliphatic-based isocyanate and (ii) at least one aromatic-based isocyanate; and (B) at least one isocyanate-reactive component, Component B, comprising: (i) at least one phosphate ester compound and (ii) at least one polyether polyol having an average molecular weight of less than 1,500 g/mol; a process for producing the above adhesive; a multi-layer laminate product including the above adhesive; and a process for producing a laminate product using the above adhesive.

The present invention provides a polyisocyanate composition comprising at least one isocyanate compound selected from the group consisting of an aliphatic isocyanate and an alicyclic isocyanate as a skeleton, wherein an average value of a total number of isocyanate groups blocked with a blocking agent and not blocked with a blocking agent per polyisocyanate molecule is 2 or more, and among the isocyanate groups in the polyisocyanate composition, 1 mol % or more and 99 mol % or less are blocked with a blocking agent, and the like.