A protective garment, gussets for protective garments, and individual gusset layers, being a moisture wicking layer, a core moisture absorbing layer and a moisture impermeable layer, and combinations thereof. The moisture wicking layer including a double knit fabric wherein a technical face of the fabric forms an eyelet mesh utilising both hydrophilic and hydrophobic yarns and a technical back of the fabric forms an interlock utilising only hydrophilic yarns. The moisture absorbing layer including a sinker terry fabric knit comprising sinker loops with plush loops made form synthetic fibres treated with a hydrolysing enzyme that splits the fibres into fibrils. The moisture impermeable layer including a base fabric knit laminated with a polyurethane sheet.

An aqueous emulsion comprising an aqueous continuous phase and a discontinuous oil phase comprising particles having an interpenetrating network (IPN) comprising: i) an MQ resin, ii) a polyorganosiloxane and iii) an organic polymer.

The invention relates to a water-repellent and lipophilic composite needle-punched nonwoven fabric and a preparation method thereof. The method comprises the following steps: blending a PET fiber and a polyolefin-based fiber in a mass ratio of 3:1-1:3, and performing needle punching to obtain a composite needle-punched nonwoven fabric; carrying out hot-drying treatment on the composite needle-punched nonwoven fabric at 110-160° C. for 40-90 min; and carrying out water-repellent finishing on the hot-dried fabric using 50-70 mL/L of an aqueous solution of a modified resin-based fluorine-free waterproofing agent, and drying to obtain the water-repellent and lipophilic composite needle-punched nonwoven fabric, wherein the water-repellent finishing is dip rolling, the air pressure is 1.8 kPa and the liquid carrying rate is 160-230%. The preparation method of the invention is simple, and the prepared composite needle-punched nonwoven fabric has significantly improved water repellency, lipophilicity and tensile strength compared with the fabric before treatment.

A soil-resistant fiber fabric having excellent water/oil repellency and excellent soil dirt resistance is obtained by fixing colloidal silica to a fiber fabric, and by subsequently treating the fiber fabric with a water/oil repellent fluorine compound, thereby having the water/oil repellent fluorine compound adhere to a surface of the fiber fabric.

Aqueous emulsions contain: (A) β-ketocarbonyl-functional organosilicon compounds having at least one Si—bonded radical A of the formula
(Si)-L.sup.1-[X.sup.1-L.sup.2-].sub.yX.sup.2  (I) where L.sup.1 are divalent, Si—C-bonded C.sub.1-18 hydrocarbon radicals, L.sup.2 are divalent C.sub.1-6 hydrocarbon radicals, X.sup.1 is a radical —O—, —NZ—, —NR.sup.2— or —S—, X.sup.2 is a radical —O—Z, —NH—Z, —NR.sup.2—Z, —S—Z, Z is a radical —C(═O)—CHR.sup.3—C(═O)—CH.sub.2R.sup.3, R.sup.2 is a monovalent C.sub.1-18 hydrocarbon radical, R.sup.3 is a monovalent, optionally substituted C.sub.12 hydrocarbon radical atoms, y is 0, 1, 2 or 3 (B) at least one salt of a saturated or unsaturated fatty acid having at least 10 carbon atoms, and (C) water, with the proviso that no nonionic emulsifier having an HLB of less than 15 is present.

An oligomer represented by the formula

##STR00001##

where R.sup.1 is hydrogen or methyl, R.sup.2 is an alkyl group having from 2 to 18 carbons, inclusive, R.sup.3 is hydrogen or hydroxyl, Y is hydrogen or an initiator residue, Z is a single bond or methylene, and n is an integer from 9 to 40, inclusive. Acrylate oligomer emulsions including the disclosed oligomer and fluorine-free treating compositions including the acrylate oligomer emulsion. Methods of making and using such compositions are also disclosed.

A method for producing a water/oil repellent composition can produce an article which is excellent in the oil repellency while maintaining the water repellency and the heavy-rain durability. The method includes mixing an emulsion of a polymer having from 10 to 50 mass % of units based on a monomer having a perfluoroalkyl group per all units and an emulsion of a monomer component containing at least 80 mass % of a monomer having a perfluoroalkyl group so that the proportion of the mass of the polymer will be from 50 to 99 mass % per the sum of the mass of the polymer and the total mass of the monomer component and then polymerizing the monomer component. The monomer component includes emulsified particles in the emulsion of the monomer component. The emulsified particles have an average particle size of from 50 to 600 nm.

The present disclosure relates to a wearable water triboelectric generator, wherein the water triboelectric generator comprises a first substrate having a first surface and a second surface, wherein the first surface and the second surface are opposing to each other; and wherein the first surface comprises a modified hydrophobic surface comprising a coating of hydrophobic cellulose oleoyl ester nanoparticles. There is also provided a wearable dual mode water and contact triboelectric generator comprising said water triboelectric generator and a contact triboelectric generator, wherein the water triboelectric generator and the contact triboelectric generator are arranged such that the first substrate of the water triboelectric generator completely surrounds or encapsulates the contact triboelectric generator.

The invention relates to a polymeric fabric comprising an outer functional layer having hydrophobic and oleophobic characteristics made of a first compound, and a second functional layer having hydrophobic characteristics made of a second compound, wherein the first and the second compound differ from each other. Further the outer functional layer at least partly coats the second layer. Additionally, the invention relates to a method of producing a polymeric fabric and an apparatus for producing a polymeric fabric.

The present invention relates to microparticles having a polymeric shell, and also to aqueous dispersions comprising these microparticles. The microparticles having a polymeric shell comprise: a) at least one acrylic copolymer of HASE type; b) at least one solid/liquid phase change material having a phase transition temperature Tf.sub.1 of greater than or equal to 20° C.; c) at least one solid/liquid phase change material having a phase transition temperature Tf.sub.2 of less than or equal to 30° C., provided that Tf.sub.2 is less than Tf.sub.1; d) optionally at least one active agent.