A composite article comprising at least one metal reinforcement element embedded in a polymer material, said metal reinforcement element being at least partially coated with an adhesion promoting layer, said adhesion promoting layer being interposed between said metal reinforcement element and said polymer material, characterized in that said adhesion promoting layer comprises an acid anhydride-grafted polyolefin and a phenolic antioxidant.

Provided are: a tire including: a tire frame; and a reinforcing metal cord member that is wound at least on the outer circumference of the tire frame, wherein at least a portion of the reinforcing metal cord member is coated with a coating composition via an adhesion layer that contains a polyamide-based adhesive and has a melting point of from 160 C. to 200 C., the coating composition containing at least one thermoplastic material selected from polyamide-based thermoplastic resins having a melting point of from 160 C. to 240 C. and polyamide-based thermoplastic elastomers having a melting point of from 160 C. to 240 C.; and a method of producing the same.

A tire includes a steel cord having a plated coating layer, rubber covering the steel cord, the plated coating layer including Cu and Zn, and a bonding layer including Cu.sub.2S and CuS provided closer to the rubber than an interface between the steel cord and the rubber, wherein a molar ratio Cu.sub.2S/CuS of Cu.sub.2S and CuS included in the bonding layer is 1.0 or higher.

Metal or metallized reinforcer, at least the surface of which is at least partially metallic, at least said metallic part being coated with a polybenzoxazine, the repeat units of which comprise at least one unit corresponding to the formulae (I) or (II):

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in which: Z.sub.1 represents an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P; X.sub.1 and X.sub.2, which are identical or different, represent O or S; Ar.sub.1 and Ar.sub.2, which are identical or different, represent a substituted or unsubstituted phenylene group; Z.sub.2 represents O or (S).sub.n, the symbol n representing an integer equal to 1 or greater than 1.

Use of such a reinforcement for the reinforcement of a rubber article, in particular a motor vehicle tyre.

This disclosure is to provide a brass-plated steel wire for reinforcing a rubber article, which is capable of improving the initial adhesiveness, heat-resistant adhesiveness and initial adhesion rate. This disclosure is a brass-plated steel wire for reinforcing a rubber article, wherein: when measured with XPS (X-ray photoelectron spectroscopy), an outermost surface contains zinc at an amount of 4.8 atom % or less, phosphorus at an amount of 0.5 atom % or more, and oxygen at an amount of 50 atom % or less; and in the outermost surface, an atomic ratio of copper to zinc is 1 to 6.

The present invention relates to an adhesive composition comprising: at least one phosphate salt chosen from sodium phosphate, potassium phosphate and mixtures of these phosphates; and at least one resin based on: at least one compound A1, compound A1 being chosen from a compound A11 comprising at least two functions, one of these functions being a hydroxymethyl function and the other being an aldehyde function or a hydroxymethyl function, or a compound A12 comprising at least one aldehyde function, or a mixture of a compound A11 and of a compound A12; and at least one phenol A21.

A threadlike metallic or metallized reinforcer, for example a thread, film, tape or cord made of carbon steel, at the periphery of which is positioned a layer of metal referred to as surface metal chosen from copper, nickel and copper/nickel alloys, is characterized in that this surface metal layer is itself coated, at least in part, with at least one layer of graphene; preferably, there is grafted, to this graphene, at least one functional group which can crosslink to a polymer matrix. This reinforcer of the invention is effectively protected from corrosion by virtue of the graphene present at the surface; advantageously, it can be adhesively bonded directly, without adhesion primer or addition of metal salt, to an unsaturated rubber matrix, such as natural rubber, by virtue of the possible functionalization of this graphene.

Provided are: a rubber article-reinforcing steel cord having excellent corrosion resistance; and a method of producing the same with excellent productivity. In a rubber article-reinforcing steel cord (1), plural sheath strands (3) each formed by twisting together plural steel filaments are twisted together around at least one core strand (2) formed by twisting together plural steel filaments. Brass plating is performed on the steel filaments, and zinc plating is further performed on at least the outer circumference of the brass plating of outermost-layer steel filaments of the sheath strands (3).

A tire having a rubber body in which a steel cord is embedded, wherein a layer composed of Zn.sub.xCo.sub.yO is formed at the interface between the steel cord and the rubber body and x+y is 5/6 or more and 1 or less.

A resin-metal composite member for a tire, the member including: a metal member; an adhesive layer; and a covering resin layer in this order, wherein: the adhesive layer includes a continuous phase that contains a polyester-based thermoplastic elastomer having a polar functional group, and a discontinuous phase that contains at least one of a polyphenylene ether resin or a styrene resin and contains a styrene-based elastomer having an epoxy group.