The method relates to the technical field of organic silicone copolymers, it is suitable for the field of fiber substrate treatment and is more suitable for the field of textile treatment.

Described is a fibrous substrate treatment composition having a) 20-99.5% by weight of a silicone polyether polymer and b) 0.5-4% by weight of a cationic surfactant or a mixture of cationic and nonionic surfactant; wherein the silicone polyether polymer has 6-100% by weight of formula (I) or (II) and 0-94% by weight of repeat units from ethylenically unsaturated comonomers;

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wherein a and b are integers of 1 to 40 where a+b is an integer of at least 2; c and d are integers of 0 to 20; e is an integer of 1 to 40; X is a linear or branched C.sub.1-C.sub.4 alkylene group; R.sup.1 is a C.sub.1-C.sub.4 alkyl group; and R.sup.2 is —C(R.sup.1)═CH.sub.2 or polymer backbone unit —[C(R.sup.1)—CH.sub.2]— bonded at C(R.sup.1). Treatments exhibit improved balance of water repellency and oily stain release performance.

Described is a fibrous substrate treatment composition having a) 20-99.5% by weight of a silicone polyether polymer and b) 0.5-4% by weight of a cationic surfactant or a mixture of cationic and nonionic surfactant; wherein the silicone polyether polymer has 6-100% by weight of formula (I) or (II) and 0-94% by weight of repeat units from ethylenically unsaturated comonomers;

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wherein a and b are integers of 1 to 40 where a+b is an integer of at least 2; c and d are integers of 0 to 20; e is an integer of 1 to 40; X is a linear or branched C.sub.1-C.sub.4 alkylene group; R.sup.1 is a C.sub.1-C.sub.4 alkyl group; and R.sup.2 is —C(R.sup.1)═CH.sub.2 or polymer backbone unit —[C(R.sup.1)—CH.sub.2]— bonded at C(R.sup.1). Treatments exhibit improved balance of water repellency and oily stain release performance.

Wipes for preventing chlorine depletion suitable for commercial applications (e.g., industrial and consumer disinfectant wipes) are provided. The wipe includes at least one nonwoven layer, at least one pulp layer, and a nonionic modified siloxane additive. The at least one nonwoven layer and the at least one pulp layer may be hydroentangled to form a hydroentangled nonwoven fabric having a first surface and a second surface. Additionally, the nonionic modified siloxane additive may be disposed on at least one of the first surface or the second surface.

Wipes for preventing chlorine depletion suitable for commercial applications (e.g., industrial and consumer disinfectant wipes) are provided. The wipe includes at least one nonwoven layer, at least one pulp layer, and a nonionic modified siloxane additive. The at least one nonwoven layer and the at least one pulp layer may be hydroentangled to form a hydroentangled nonwoven fabric having a first surface and a second surface. Additionally, the nonionic modified siloxane additive may be disposed on at least one of the first surface or the second surface.

A composition for hydrophilic treatment of fibrous substrates that is washfast in terms of softness contains derivatives of amino-functional organopolysiloxanes containing siloxane units of a general formula (I), optionally siloxane units of a general formula (II), siloxane units of general formula (III), and siloxane units of a general formula (IV). Impurities of octamethylcyclotetrasiloxane (D4 cyclics), decamethylcyclopentasiloxane (D5 cyclics) and dodecamethylcyclohexasiloxane (D6 cyclics) are present in proportions of less than 0.1% by weight in each case and after a storage time of 20 days at a temperature of 50° C. the proportions of D4 cyclics, representative of D4, D5 and D6, remain below 0.1% by weight in each case, based in each case on the total weight of the derivatives of amino-functional organopolysiloxanes.

A composition for hydrophilic treatment of fibrous substrates that is washfast in terms of softness contains derivatives of amino-functional organopolysiloxanes containing siloxane units of a general formula (I), optionally siloxane units of a general formula (II), siloxane units of general formula (III), and siloxane units of a general formula (IV). Impurities of octamethylcyclotetrasiloxane (D4 cyclics), decamethylcyclopentasiloxane (D5 cyclics) and dodecamethylcyclohexasiloxane (D6 cyclics) are present in proportions of less than 0.1% by weight in each case and after a storage time of 20 days at a temperature of 50° C. the proportions of D4 cyclics, representative of D4, D5 and D6, remain below 0.1% by weight in each case, based in each case on the total weight of the derivatives of amino-functional organopolysiloxanes.

An aqueous dispersion includes precrosslinked organopolysiloxanes, emulsifiers, and water. The precrosslinked organopolysiloxanes include units of the formula R.sub.2SiO.sub.2/2 (I), and on average at least one structural unit of the formula SiR.sup.1O.sub.2/2—Y—SiR.sup.1O.sub.2/2 (III) where Y is a divalent radical of the formula —R.sup.2—[NR.sup.3—R.sup.4—].sub.nNR.sup.3—C(O)—C(O)—NR.sup.3—Z—NR.sup.3—C(O)—C(O)—NR.sup.3—[R.sup.4—NR.sup.3—].sub.nR.sup.2—.

An aqueous dispersion includes precrosslinked organopolysiloxanes, emulsifiers, and water. The precrosslinked organopolysiloxanes include units of the formula R.sub.2SiO.sub.2/2 (I), and on average at least one structural unit of the formula SiR.sup.1O.sub.2/2—Y—SiR.sup.1O.sub.2/2 (III) where Y is a divalent radical of the formula —R.sup.2—[NR.sup.3—R.sup.4—].sub.nNR.sup.3—C(O)—C(O)—NR.sup.3—Z—NR.sup.3—C(O)—C(O)—NR.sup.3—[R.sup.4—NR.sup.3—].sub.nR.sup.2—.

The present invention relates to a coating composition with 10 to 100% by weight of a non-fluorinated compound mixture, which comprises at least one compound b and at least one compound a, c, or d: a) alkali metal salt of poly(meth)acrylic acid, alkali metal salt of poly(meth)acrylic acid copolymer, ammonium compound or amine salt of poly(meth)acrylic acid, ammonium compound or amine salt of poly(meth)acrylic acid copolymer, or mixtures thereof; b) silicone polyether, alkali metal salt of silicone polyether carboxylate, ammonium compound or amine salt of silicone polyether carboxylate, or mixtures thereof; c) salt of hydrolyzed α-olefin/maleic anhydride copolymer, salt of esterified α-olefin/maleic anhydride copolymer, α-olefin/maleic anhydride copolymer amic acid resin or salt thereof, or mixtures thereof; or d) polycarboxylate calcium sequestrants or mixtures thereof. Such coatings exhibit improved soil and stain cleaning performance.