A dispersion of capsules in critical or supercritical carbon dioxide is provided. The capsules include an aqueous solution encapsulated by magnetic covalent organic framework particles. Also provided is a method of making a dispersion of aqueous solution capsules. The method includes providing a medium of critical or supercritical carbon dioxide, introducing the aqueous solution into the critical or supercritical carbon dioxide medium, and introducing a magnetic covalent organic framework particle into the critical or supercritical carbon dioxide medium. Associated methods of using the disclosed dispersions in hydrocarbon-bearing formations are also provided.

Y-Grade NGL fracturing systems and methods of using Y-Grade NGL stimulation fluids.

The present invention relates to a process for purification of a carbon dioxide feedstock, for example from a production well, which comprises carbon dioxide and gaseous and liquid C.sub.1+ hydrocarbons. Specifically, a carbon dioxide feedstream is passed through one or more separation unit wherein each separation unit removes one or more C.sub.1+ hydrocarbon from the carbon dioxide feedstream to provide a richer carbon dioxide gas stream. The process comprises one or more separation unit which employs an adsorption media and has an adsorption step and a media regeneration step wherein the regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process. One embodiment of this method provides for the use of a different regenerable adsorbent media in two or more separation units.

A method and apparatus for enhanced oil recovery comprising separating CO.sub.2 gas from coal or flue emissions of a power plant, and flash freezing the CO.sub.2 gas with super chilled air, to form frozen CO.sub.2 ice blocks or cylinders, wherein the CO.sub.2 blocks or cylinders can then be inserted into an abandoned oil well, and the CO.sub.2 can be allowed to warm up and change phase to a gas, which enables the CO.sub.2 gas to mix with the oil, and helps reduce the viscosity of the oil and allows it to flow more freely, so that it can be pumped out using conventional equipment. A first application comprises having top and bottom valves and the CO.sub.2 blocks or cylinders being allowed to change phase to a gas while inside the injection pipe, to increase the pressure therein, such that, by opening the bottom valve, pressurized jets of CO.sub.2 gas can be released into the oil, causing the oil to mix vigorously with the carbon dioxide gas, and reduce the viscosity thereof. A second application comprises allowing the CO.sub.2 cylinders or blocks to drop into the oil itself, wherein the relatively warm oil causes the frozen CO.sub.2 to change phase to a gas, which causes violent gas bubbles to form that vigorously mix with the oil, which helps reduce the viscosity of the oil so it flows more freely through the reservoir.

Methods and systems for enhanced recovery of coal bed methane. A method includes generating a diluent gas mixture comprising N.sub.2 and CO.sub.2 in a semi-closed Brayton cycle power plant, injecting at least a portion of the diluent gas mixture into a coal bed, and recovering a mixed production gas comprising methane from the coal bed.

An apparatus utilizes a membrane unit to capture components from atmospheric air, including carbon dioxide, enriches the carbon dioxide concentration, and delivers the enriched concentration of carbon dioxide to a sequestering facility. The membrane is configured such that as a first gas containing oxygen, nitrogen and carbon dioxide is drawn through the membrane, a permeate stream is formed where the permeate stream has an oxygen concentration and a carbon dioxide concentration higher than in the first gas and a nitrogen concentration lower than in the first gas. A permeate conduit, having a vacuum applied to it by a vacuum generating device receives the permeate stream and a delivery conduit delivers at least a portion of the enriched carbon dioxide to a sequestering facility. The apparatus may comprise a component of a system where the system may have a flue gas generator and/or a secondary enrichment system disposed between the vacuum generating device and the sequestering facility.

The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.

A CCUS system for exploiting a thickened oil reservoir based on an optimal flue gas CO.sub.2 enrichment ratio. The CCUS system comprises a flue gas CO.sub.2 enrichment unit, a flue gas injection unit, a thickened oil thermal production well group unit and a produced gas recovery unit; the fuel gas CO.sub.2 enrichment unit comprises an air separating enrichment unit and a boiler injection gas premixed tank; the air separating enrichment unit comprises an air separating primary device used for separating air into oxygen and nitrogen preliminarily, and an air separating secondary device used for further enriching a part of the oxygen which is subjected to the preliminary separation; and the boiler injection gas premixed tank is used for mixing the preliminarily separated nitrogen, the preliminarily separated part of the oxygen and/or the further enriched oxygen.

Disclosed herein is a method of injecting a fluid into a subterranean formation, the method comprising: placing a first wellbore in the subterranean formation; injecting the fluid through the first wellbore into the subterranean formation at an injection rate of R1, wherein R1 is varied with time or fixed; subsequently injecting the fluid through the first wellbore into the subterranean formation at an injection rate of R2 for a duration of time D1, wherein R2 is varied with time or fixed; subsequently injecting the fluid through the first wellbore into the subterranean formation at an injection rate of R3, wherein R3 is varied with time or fixed.

A method for treating a hydrocarbon-containing formation includes injecting an aqueous solution that contains an alkali nitrite, an ammonium halide, and a foaming agent into the formation, injecting supercritical carbon dioxide into the formation, allowing a portion of the carbon dioxide to dissolve in the aqueous solutions, causing the alkali nitrite and ammonium halide to react and generate nitrogen gas, and allowing a foam to form by the interaction of the nitrogen gas with the foaming agent.