Systems, apparatuses, and methods include an upstream exhaust analysis circuit structured to determine a characteristic of an exhaust gas stream entering a nitrous oxide (NOx) storage catalyst; a prediction circuit structured to predict a downstream NOx concentration of an exhaust gas stream exiting the NOx storage catalyst based on a model of a NOx storage capacity or a dynamic response of the NOx storage catalyst; a downstream exhaust analysis circuit structured to determine a downstream NOx concentration of the exhaust gas stream exiting the NOx storage catalyst; and a comparison circuit structured to compare the predicted downstream NOx concentration to the determined downstream NOx concentration, and determine a health of the NOx storage catalyst based on the comparison.

A degradation diagnosis device includes a downstream air-fuel ratio sensor and a control device. The control device is configured to perform a rich process and a lean process alternately and repeatedly in a degradation diagnosis process for diagnosing degradation of the exhaust gas control catalyst. The control device is configured to, in the degradation diagnosis process, determine that the exhaust gas control catalyst has been degraded when the lean process is executed and the frequency with which an output air-fuel ratio of the downstream air-fuel ratio sensor is equal to the lean air-fuel ratio is equal to or more than a predetermined frequency.

Disclosed are a hydrocarbon adsorption and desorption complex showing hydrocarbon adsorption and oxidation performance by controlling the cation ratio in zeolite, and a preparation method therefor. The hydrocarbon adsorption and desorption complex controls a cation ratio to exhibit the excellent hydrocarbon adsorption ability and oxidation performance even at a temperature lower than the catalyst activation temperature, and increases hydrothermal stability of the hydrocarbon adsorption and desorption complex through hydrothermal treatment to exhibit the excellent hydrocarbon adsorption and desorption performance even in a situation where water is present at a high temperature.

A system includes a controller configured to perform an enable operation responsive to receiving information indicative of an enable parameter, the enable operation includes: determining a predicted downstream NOx value of an exhaust gas stream exiting a NOx storage catalyst; determining a downstream NOx value of the exhaust gas stream exiting the NOx storage catalyst; determining an error between the predicted downstream NOx value and the determined downstream NOx value; comparing the error to an error threshold; and determining that the NOx storage catalyst is in good health responsive to determining that the error does not exceed the error threshold. The controller is further configured to perform a disable operation responsive to receiving information indicative of a disable parameter, the disable operation causing a deactivation of at least a portion of the controller.

The present disclosure describes methods for evaluating quality of DEF dosed to an EAS including a close coupled SCR unit a downstream SCR unit. A NOx conversion efficiency of the close coupled SCR unit and a NOx conversion efficiency of the downstream SCR unit are used to evaluate quality of DEF. In some embodiments, the NOx conversion efficiency of close coupled SCR unit is used to evaluate quality of DEF. Operation of an EAS using the results of the evaluation of quality of DEF are described.

A method for ascertaining a fill level of at least one exhaust-gas component, which can be stored in a catalytic converter and which is generated in a combustion process, in the catalytic converter, wherein a variation of the fill level of the at least one exhaust-gas component in the catalytic converter during the combustion process is determined, wherein, during time periods in which the combustion process is not operated, a diffusion-induced change of the fill level of the at least one exhaust-gas component in the catalytic converter is determined, and wherein, on the basis of the determined variation during the combustion process and the diffusion-induced change, a fill level of the at least one exhaust-gas component in the catalytic converter is ascertained. The invention furthermore relates to a processing unit and to a computer program for carrying out such a method.

Various embodiments may include a method for monitoring a nitrogen oxide trap comprising: monitoring a storage capacity of the nitrogen oxide trap; deactivating nitrogen oxide trap regeneration based on the monitored storage capacity; and upon a predetermined event, reactivating nitrogen oxide trap regeneration.

A degradation diagnosis device includes a downstream air-fuel ratio sensor and a control device. The control device is configured to perform a rich process and a lean process alternately and repeatedly in a degradation diagnosis process for diagnosing degradation of the exhaust gas control catalyst. The control device is configured to, in the degradation diagnosis process, determine that the exhaust gas control catalyst has been degraded when the lean process is executed and the frequency with which an output air-fuel ratio of the downstream air-fuel ratio sensor is equal to the lean air-fuel ratio is equal to or more than a predetermined frequency.

An internal combustion engine control device and a catalyst deterioration diagnostic method according to the present invention control the amount of fuel to be supplied to an internal combustion engine such that the air-fuel ratio of the exhaust on the downstream side of the exhaust purification catalyst is alternately switched between rich and lean, measure the oxygen storage capability of the exhaust purification catalyst during a measurement period within a reversal period of the air-fuel ratio, and diagnose deterioration of the exhaust purification catalyst based on a measurement value of the oxygen storage capability. A time point at which the output of an exhaust sensor indicates that the air-fuel ratio of the exhaust on the downstream side of the exhaust purification catalyst begins to change from a vicinity of a stoichiometric air-fuel ratio to rich or lean is set as the time of end of the measurement period.

A method for monitoring a gas sensor (14) which comprises two electrochemical measuring cells (20, 30) and which is arranged in an exhaust tract (10) of an internal combustion engine (11), wherein the sensor elements (20, 30) exhibit a substantially identical sensitivity towards a first gas component and a different sensitivity towards a second gas component and are insensitive towards further gas components. In an operating state in which an exhaust gas stream at the gas sensor (14) contains less of the second gas component than of the first gas component a concentration of the first gas component is calculated from each of the sensor signals from the sensor elements (20, 30) and a defect in a sensor element (20, 30) is deduced from the concentrations of the first gas component.