Methods and systems are provided for an auto-ignition internal combustion engine comprising an exhaust gas recirculation arrangement, an intake system, and an exhaust gas discharge system for the discharge of exhaust gases, in which the internal combustion engine is operable, at least in a first, stoichiometric operating mode, by way of a spatial ignition method (HCCI mode). For the aftertreatment of the exhaust gas in the first operating mode, a three-way catalytic converter is provided in the exhaust gas discharge system for reducing nitrogen oxides and oxidizing unburned hydrocarbons and carbon monoxide. In this way, the auto-ignition internal combustion engine has a greater window of operation in the HCCI mode than conventional auto-ignition internal combustion engines.

Provided are a novel synthesis technique for producing pure phase aluminosilicate zeolite and a catalyst comprising the phase pure zeolite in combination with a metal, and methods of using the same. The pure phase aluminosilicate zeolite can be selected from those having an ITW framework and a silica to alumina ratio of less than about 140 or, an STW framework and a silica to alumina ratio less than about 100.

Methods and systems are provided for exhaust heat recovery and hydrocarbon trapping at an exhaust bypass assembly. Exhaust gas may flow in both directions through an exhaust bypass passage and each of a HC trap and a heat exchanger coupled to the bypass passage. The HC trap may be purged with the hot exhaust and heat from the exhaust may be recovered at the heat exchanger.

A sulfur-resistant, high activity methane oxidation catalyst for use in removing methane from gas streams having a concentration of methane by oxidizing the methane. The methane oxidation catalyst is especially useful in processing gas streams that also have a concentration of a sulfur compound. The sulfur-resistant methane oxidation catalyst includes a unique multi-crystalline zirconia as a support for a platinum component and a ruthenium component. The multi-crystalline zirconia contributes to the excellent properties of the catalyst. The platinum and ruthenium components can be included in the methane oxidation catalyst in a specific weight ratio that also contributes to the enhanced properties of the catalyst. The sulfur-resistant methane oxidation catalyst may also include a chloride component that contributes to enhanced properties of the catalyst.

An exhaust gas purifying system includes: a NOx trapping agent (2) which adsorbs nitrogen oxide when an excess air ratio of exhaust gas is more than 1, and releases nitrogen oxide when the excess air ratio is 1 or less; a NOx purifying catalyst (13) which reduces nitrogen oxide to nitrogen; and an oxygen concentration controller which controls oxygen concentration in the exhaust gas. When the excess air ratio of the exhaust gas is more than 1, nitrogen oxide is adsorbed to the NOx trapping agent (2). When the excess air ratio of the exhaust gas is 1 or less, the oxygen concentration controller controls the oxygen concentration of the exhaust gas at an inlet of the NOx purifying catalyst between 0.8 and 1.5% by volume, so that the NOx purifying catalyst reduces nitrogen oxide released from the NOx trapping agent.

[Problem] Provided is an exhaust gas purification catalyst capable of exhibiting even higher exhaust gas purification performance without impairing Pd catalytic activity, and an exhaust gas purification system using the exhaust gas purification catalyst.

[Solution] Provided is an exhaust gas purification catalyst comprising a substrate and a catalyst layer provided on the substrate, said catalyst having a first section located upstream along a flow direction of the exhaust gas and a second section located downstream from the first section; the catalyst layer in the first section comprises a first catalyst layer comprising palladium and a second catalyst layer comprising rhodium and covering the first catalyst layer, wherein a pore volume proportion is 12% or more and less than 18% wherein the pore volume proportion is a proportion of a total volume of the pores, which have a pore diameter of 0.06 μm to 30.0 μm as measured by mercury press-in method and existing in the substrate and the catalyst layer in the first section to a volume of a entire first section; and a wash coat amount is 100 g/L to 190 g/L, wherein a wash coat amount is a mass per unit volume of the catalyst layer in the first section to the volume of the substrate existing in the first section.

An exhaust gas purification apparatus includes a three-way catalyst. The three-way catalyst includes a downstream catalyst layer and an upstream catalyst layer. The downstream catalyst layer is to be provided in an exhaust pipe. The downstream catalyst layer contains a noble metal material containing at least one of Pd, Rh, or Pt, and an OSC material containing at least ceria. The upstream catalyst layer is to be provided in the exhaust pipe closer to an engine than the downstream catalyst layer is. The upstream catalyst layer contains the noble metal material and the OSC material. The upstream catalyst layer contains the ceria at a content less than a content of the ceria in the downstream catalyst layer.

An exhaust gas purification catalyst provides excellent removal performance of methane, which is chemically stable. Exhaust gas purification catalyst includes a substrate that divides cells through which an exhaust gas flows and a catalyst layer that is provided on a surface of the substrate. The catalyst layer includes a palladium layer containing palladium that extends from a first end part which is an end part on the side into which an exhaust gas in the cells flows to a second end part which is an end part on the side from which an exhaust gas flows out, a platinum layer containing platinum that extends from the second end part to the first end part, and a rhodium layer containing rhodium that is laminated with both the palladium layer and the platinum layer.

An exhaust gas purification device includes a first catalyst, a bypass pipe, a second catalyst, and a switching controller. The first catalyst is provided in an exhaust pipe. The bypass pipe branches from a first portion of the exhaust pipe. The first portion is located upstream of the first catalyst. The bypass pipe is recoupled to a second portion of the exhaust pipe. The second portion is located upstream of the first catalyst. The second catalyst is provided in the bypass pipe. The switching controller is configured to switch a flow path of an exhaust gas to the bypass pipe based on a deterioration degree of the first catalyst.

An engine exhaust aftertreatment device includes a first exhaust treatment unit and/or a second exhaust treatment unit; the first exhaust treatment unit includes a first bypass pipeline and a first connection pipe provided between a DPF and an SCR; the second exhaust treatment unit comprises a second bypass pipeline and a second connection pipeline provided between a DOC and the DPF, one end of the second bypass pipeline being in communication with the turbine front exhaust pipe, and the other end of the second bypass pipeline being in communication with the second connection pipeline; when it is detected that an engine satisfies a starting condition of the first exhaust treatment unit, the first exhaust treatment unit starts; and when it is detected that the engine satisfies a starting condition of the second exhaust treatment unit, the second exhaust treatment unit starts.