A circulating fluidized bed boiler is described, comprising a furnace, a loopseal, and a loopseal heat exchanger arranged in the loopseal. The loopseal heat exchanger comprises walls limiting an interior of the loopseal heat exchanger, a first particle outlet for letting out particulate material from the loopseal heat exchanger, an inlet for receiving bed material, heat exchanger tubes arranged in the interior of the loopseal heat exchanger, and a first ash removal channel configured to let out ash from the loopseal heat exchanger. An ash cooler is configured to receive ash from the first ash removal channel. In the loopseal heat exchanger the first ash removal channel is arranged at a lower level than the first particle outlet.

A counter-current catalyst regenerator with at least two stages of counter-current contact along with a regenerator riser is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst. The regenerator riser may provide a passage to transport the catalyst and may serve as a secondary stage for coke combustion to provide the regenerated catalyst.

A chemical looping reactor is provided. The reactor comprises a first reduction reactor, a second reduction reactor and a shared oxidation reactor. The shared oxidation reactor is set between the first and second reduction reactors. Therein, the present invention applies interconnected fluidized beds in chemical looping combustion. Single redox is processed with oxygen carrier (oxide of metal like nickel or copper). The first and second reduction reactors individually handle their own reactions and reactants. Thus, in a chemical looping reactor, two different source materials can be handled at the same time. The oxygen carrier can be cycled separately as well for fully releasing oxygen contained within. High-purity carbon dioxide is further obtained. The application can be extended to hydrogen generation. Hence, the present invention simplifies the reaction mechanism, enhances the yield, improves the operation efficiency and reduces the cost.

Disclosed herein are a fluid sand falling type circulating fluidized bed boiler with a plurality of risers for preventing erosion and corrosion of water tubes and increasing combustion efficiency, and a method of operating the same. The fluid sand falling type circulating fluidized bed boiler with a plurality of risers includes a boiler section into which fuel and oxidizer are injected, a riser section connected to the boiler section so that the fuel and fluid sand supplied from the boiler section are introduced from the bottom of the riser section and flow up, and a relay section provided on the boiler section to supply the fluid sand having passed through the riser section to the boiler section, wherein the fuel is injected from the top of the boiler section and burned while flowing down therein.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500 C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is hi the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least at least one feldspar or feldspathoid with a melting point higher than 1500 C., such as celsian, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from a precursor of the ceramic matrix, obtained from a macroporous zeolitic material with zeolite crystals of a specific size, and a precursor of the oxidation-reduction active mass.

The present invention relates to a device and a method for chemical looping combustion, for which the end of the intake duct (4) opening out within the chamber of the separator (1) is inclined with respect to a horizontal plane (H).

A cyclone separator is disclosed. The cyclone separator includes a housing that forms a separation chamber, a central cylinder made of a non-metal refractory material and located inside the housing, and a support structure that supports the central cylinder. The separation chamber is divided by the central cylinder into an outer separation chamber and an inner separation chamber. The separation chamber includes an inlet and an outlet that are in communication with the outer and inner separation chambers, respectively. The support structure comprises a hollowed-out upwardly-arched structure that is connected to an inner wall of the separation chamber by continuous pouring or masonry, with an arch face of the support structure being connected to a lower end of the central cylinder to support the central cylinder. The central cylinder is connected to both the housing and the supporting structure by continuous pouring or masonry.

A composition for binding metal oxides, a metal oxide pellet produced with the binder and metal oxide, and methods for producing the metal oxide pellets. The binder composition includes a pelletizing agent comprising at least one of a cement, a bitumen, and a polymer and a sinter enhancer comprising at least one of a metal sulfide, a metal chloride, and a metal nitrate.

Disclosed herein are systems (e.g., moving bed redox systems) and methods for supplying thermal energy to an endothermic chemical process.