Patent classifications
A63B37/0023
Methods for applying polyurethane coatings to golf balls having a thermoplastic polyurethane cover
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.
METHODS FOR TREATING THERMOPLASTIC POLYURETHANE COVERS FOR GOLF BALLS WITH EPOXY COMPOSITIONS
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.
METHODS FOR CROSS-LINKING THERMOPLASTIC POLYURETHANE COVERS FOR GOLF BALLS
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.
METHODS FOR APPLYING POLYURETHANE COATINGS TO GOLF BALLS HAVING A THERMOPLASTIC POLYURETHANE COVER
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. Polyurethane primer coatings and polyurethane top-coatings are applied to the thermoplastic polyurethane cover. Different coating methods can be used. Isocyanate-rich and polyol-rich polyurethane coatings can be applied. In one embodiment, the golf ball can be treated with a multi-functional isocyanate prior to applying the coatings. The polyurethane cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. Heat is used to cure the coatings. The coating methods have many benefits and the finished balls have good physical properties.
GOLF BALLS HAVING COVERS MADE WITH THERMOPLASTIC POLYURETHANE AND EPOXY BLEND COMPOSITIONS
Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. In another embodiment, the cover composition comprises a reaction product of thermoplastic polyurethane, epoxy-functional compound, and epoxy curing agent. Surface coatings of isocyanates, amines, and imines also can be applied to the cover. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives.
Golf ball and method of manufacture
In a golf ball having a core and a cover of one or more layer encasing the core, an outermost layer of the cover is molded of a thermoplastic material selected from the group consisting of polyurethane, polyurea and mixtures thereof, and the surface of the cover is treated with a polyisocyanate compound that is free of organic solvent. A method of manufacturing the golf ball is also described. Such golf balls are endowed with an excellent spin performance and scuff resistance, in addition to which productivity of the golf balls is high.
Golf ball layers including a fatty acid (meth)acrylic acid salt
The present invention relates to the use of a fatty acid (meth)acrylic acid salt in a golf ball layer. The fatty acid (meth)acrylic acid salt may be added to one or more portions of a golf ball including a core, intermediate, or cover layer. For example, in one embodiment, the fatty acid (meth)acrylic acid salt may be blended with a polybutadiene rubber material. In another embodiment, the fatty acid (meth)acrylic acid salt of the present invention may be blended with an ionomer. In some embodiments, the fatty acid (meth)acrylic acid salt may be blended with a formulation including both a polybutadiene rubber component and an ionomer.
Method for treating thermoplastic polyurethane golf ball covers
A method of forming a golf ball is disclosed herein. The method includes injecting a cover mixture into a mold to form a cover mixture comprising a thermoplastic polyurethane resin and a polyahl, subjecting the golf ball to a polyisocyanated solution to create a golf ball with a polyisocyanated cover, and heating the golf ball or polyisocyanated cover to remove a solvent component of the polyisocyanated solution and promote the reaction of the polyisocyanate with the cover mixture and polyahl.
GOLF BALL HAVING AT LEAST ONE LAYER CONSISTING OF A MIXTURE OF A THERMOSET OR THERMOPLASTIC COMPOSITION AND A PLURALITY OF ALKOXYLATED SILOXANE-SURFACE TREATED PARTICLES AND/OR POLYETHER-MODIFIED SILOXANE-SURFACE TREATED PARTICLES
Golf ball having CoR of at least 0.700 and Atti compression of at least about 50 and comprising layer consisting of mixture of thermoset or thermoplastic composition and plurality of particulates, at least a portion surface-treated with alkoxylated siloxanes and/or polyether-modified siloxanes, and may be selected from titanium dioxide particles, barium sulfate particles, zinc sulfide particles, and/or zinc oxide particulates. At least some particulates are contacted with compound having the formula:
##STR00001##
Compound (I) may be included in amount of 0.01 to 2% by weight based on total weight of portion of plurality being contacted. The plurality may be included in mixture in amount such that layer has specific gravity of from 0.5 to about 10.0, tensile strength of from about 300 psi to about 50,000 psi, and elongation at break of from about 20% to about 1000%, each being greater than that of the thermoset or thermoplastic composition portion of the mixture.
GOLF BALL
In a golf ball having a core, a cover of at least one layer and a paint film layer formed on a surface of the cover, the paint film layer has an elastic work recovery of at least 60%, the cover layer in contact with the paint film layer has a material hardness on the Shore D scale of at least 55 and, letting M be the elastic work recovery (%) of the paint film layer and N be the material hardness (Shore D hardness) of the cover layer, MN>0. The ball surface is scratch-resistant and has an excellent durability, and the ball has a reduced spin rate on shots with a driver or a long iron, resulting in an increased carry.