A C3 hydrocarbon fractionation system includes: a) a unit for providing a feed containing mainly propane and propylene, b) a C3 fractionation column for separating the feed to provide a top product richer in propylene than the feed and a bottom product leaner in propylene than the feed, wherein the bottom product comprises at least 50 wt % of propylene and c) a cumene production unit comprising an alkylation reactor for producing cumene from a propylene feed and a benzene feed, wherein the propylene feed comprises the bottom product of the C3 fractionation column.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing an integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

Techniques and systems for separating components of a mixture of compressed gases each having different boiling points are described. One example system includes multiple recovery stages that each recover one of the gases by condensing it into liquid form. The recovery stages are chained together, such that each stage recovers a gas having a boiling point that is higher than those of the gases to be recovered in downstream stages. Each stage typically includes a warming element that is fluidly coupled to a condenser element that provides a surface cooled to a temperature low enough to condense one of the gases, but high enough such that the remaining gases remain in gaseous form. The system may include an initial evaporator stage that heats a liquid solution of phytochemical extracts and multiple solvents, thereby recovering the extracts and producing the mixture of gaseous solvents.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

Cryogenic removal of carbon dioxide from the atmosphere, or CryoDAC (Cryogenic Direct Air Capture), uses extremely low temperatures to convert atmospheric CO.sub.2 into a frozen solid while other components of air such as oxygen and nitrogen remain as gases. Air from the atmosphere is passed through a recuperative heat exchanger to cool the air to a temperature slightly above the deposition point of CO.sub.2. The cooled air is then passed over a deposition surface chilled to a temperature below the deposition point of CO.sub.2. Carbon dioxide in the air transitions from gas to solid form upon contact with the deposition surface. The frozen CO.sub.2 is collected and stored. The cold air with CO.sub.2 removed is passed back through the recuperative heat exchanger to cool incoming air and is then returned to the atmosphere. The deposition surface may be cooled by a cryogenic refrigerator.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing an integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A cryogenic carbon capture system includes a flue gas cooling device in fluid communication with a heat engine. The flue gas cooling device receives a fluid stream that is downstream from the heat engine and a cooled liquid coolant stream so that the fluid stream is cooled by the cooled liquid coolant stream and a cooled flue gas stream is formed. A cryogenic carbon capture unit receives at least a portion of the cooled flue gas stream and separates carbon dioxide from the first portion of the cooled flue gas stream so that a clean flue gas stream and a carbon dioxide stream are formed. A liquid coolant cooling device receives the clean flue gas stream and a liquid coolant stream and cools the liquid coolant stream using the clean flue gas stream so that the cooled liquid coolant stream is formed and provided to the flue gas cooling device. The heat engine is in fluid communication with the cryogenic carbon capture system and receives a portion of a split stream that is downstream from the flue gas cooling device as an exhaust gas recirculation stream and an air stream.

A CO2 separation and liquefaction system such as might be used in a carbon capture and sequestration system for a fossil fuel burning power plant is disclosed. The CO2 separation and liquefaction system includes a first cooling stage to cool flue gas with liquid CO2, a compression stage coupled to the first cooling stage to compress the cooled flue gas, a second cooling stage coupled to the compression stage and the first cooling stage to cool the compressed flue gas with a CO2 melt and provide the liquid CO2 to the first cooling stage, and an expansion stage coupled to the second cooling stage to extract solid CO2 from the flue gas that melts in the second cooling stage to provide the liquid CO2.

Methods and systems for separating a desublimatable compound from hydrocarbons is disclosed. A feed fluid stream, consisting of a hydrocarbon and a desublimatable compound, is passed into an upper chamber of a vessel. The feed fluid stream is cooled in the upper chamber, thereby desublimating a portion of the desublimatable compound out of the feed liquid stream to form a product gas stream and a desublimatable compound snow which is collected in the lower chamber of the vessel. A lower portion of the desublimatable compound snow is melted to form a liquid desublimatable compound stream such that an upper portion of the solid desublimatable compound snow remains as an insulative barrier between the upper chamber and the liquid desublimatable compound stream. The liquid desublimatable compound stream is removed at a rate that matches a production rate of the solid desublimatable compound snow, thereby maintaining the insulative barrier.

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.