A scraped heat exchanger apparatus, including a vessel and a plurality of internally cooled plates disposed parallel to each other within the vessel. A rotating shaft is disposed at a central axis of the vessel. A rotating scraper arm, connected to the rotating shaft, moves between adjacent plates. The rotating scraper arm includes a scraper positioned to scrape solids from the outer surfaces of adjacent plates. A cooling fluid flows through an interior of each plate. The cooling fluid cools a gaseous process fluid flowing between adjacent plates. An opening in each of the plates permits the process fluid, and solids removed from the process fluid and scraped by the rotating scraper arm, to pass through the plates.

The present disclosure relates to an energy storage device for water electrolysis hydrogen production coupled with low temperature and an energy storage method, which are used for solving the problem of the contradiction between the discontinuous photoelectric resources and the continuous requirements of green hydrogen for production. The device comprises a liquid nitrogen precooling hydrogen liquefaction system, a liquid hydrogen-liquid nitrogen heat exchanging system, a cold energy storage system and a cold energy utilization system of an air separation device. According to the present disclosure, the systems are highly coupled with each other, the photoelectric renewable energy can be maximized in the form of hydrogen storage, the energy consumption cost of green hydrogen preparation and utilization can be effectively reduced while high-efficiency energy storage and peak regulation are realized, the energy saving effect is achieved, and a good popularization prospect occurs.

A plant for energy storage, comprises: a basin (2) for a work fluid having a critical temperature (T.sub.c) lower than 0°; a tank (3) configured to store the work fluid in at least partly liquid or super-critical phase with a storage temperature (T.sub.s) close to the critical temperature (T.sub.c); an expander (4); a compressor (5); an operating/drive machine (6) operatively connected to the expander (4) and to the compressor (5); a thermal store (8) operatively interposed between the compressor (5) and the tank (3) and between the tank (3) and the expander (4). The plant (1) is configured for actuating a Cyclic Thermodynamic Transformation (TTC) with the work fluid, first in a storage configuration and then in a discharge configuration. The thermal store (8), in the storage configuration, is configured for absorbing sensible heat and subsequently latent heat from the work fluid and, in the discharge configuration, it is configured for transferring latent heat and subsequently sensible heat to the work fluid.

A system for cooling a feed stream including hydrogen or helium with a mixed refrigerant includes a pre-cooling heat exchanger. A compression system has an inlet in fluid communication with the pre-cooling heat exchanger and receives and increases a pressure of a refrigerant vapor stream including hydrogen and/or helium mixed with at least one other refrigerant such that the molecular weight of the mixture is greater than 6 kg/kgmol. The compression system has an outlet in fluid communication with the pre-cooling heat exchanger. A first refrigerant separation device receives fluid from the pre-cooling heat exchanger and has a liquid outlet in fluid communication with the pre-cooling heat exchanger and a vapor outlet. A refrigerant purifier has a purifier inlet in fluid communication with the vapor outlet of the first refrigerant separation device and an outlet in fluid communication with the pre-cooling heat exchanger.

In a process for the separation of a flow containing at least 97% mol of carbon monoxide containing at least one lighter compound and at least one heavier compound, the flow is separated in a column and a column, one of the columns being a denitrogenation column and the other a column for purification in argon, in order to form a flow very rich in carbon monoxide.

Disclosed techniques include gas liquefaction using hybrid processing. A gas is compressed adiabatically to produce a compressed gas at a first pressure. The compressing a gas adiabatically is accomplished using one or more compressing stages. Heat is extracted from the compressed gas at a first pressure. The heat that is extracted is collected in a thermal store. The compressed gas at a first pressure is further compressed. The further compressing is accomplished using a first liquid piston compressor. The further compressing produces a compressed gas at a second pressure. The first liquid piston compressor is cooled using a liquid spray. The compressed gas at a second pressure is cooled using a heat exchanger. The cooling accomplishes liquefaction of the compressed gas at a second pressure. The gas that was liquefied is stored for future use. The gas that was liquefied is used to perform work.

A method for operating the liquid air energy storage (LAES) includes production of the storable liquid air through consumption of a low-demand power and recovery the liquid air for co-production of an on-demand power and a high-grade saleable cold thermal energy which may be used, say, for liquefaction of the delivered natural gas; in so doing zero carbon footprint is provided both for fueled augmentation of the LAES power output and for LNG co-production at the LAES facility.

Plant and process for the production of liquid methane from a feed gas stream comprising at least methane and carbon dioxide. A feed gas stream is injected into a CO.sub.2 crystallizer in countercurrent fashion against a stream of predominantly liquid methane, thereby crystallizing amounts of carbon dioxide from the feed gas stream. Gaseous methane recovered from the CO.sub.2 crystallizer is liquefied at a liquefaction exchanger.

A proposed method provides a fueled power output augmentation of the liquid air energy storage (LAES) with zero carbon emissions of its exhaust. It combines the production of liquid air using a low-demand power from the renewable or/and conventional energy sources and the recovery of stored air for production of on-demand power in the fueled supercharged reciprocating internal combustion engine (RICE) and associated expanders. An integration between the LAES and RICE makes possible to recover the RICE exhaust energy for increase in power produced by the expanders of LAES and to use a cold thermal energy of liquid air being re-gasified at the LAES facility for cryogenic capture of CO.sub.2 emissions from the RICE exhaust.

The invention relates to a method for separating a synthesis gas comprising hydrogen and carbon monoxide by cryogenic distillation, according to which the synthesis gas (1, 5) is cleaned and cooled to a cryogenic temperature, the cooled synthesis gas is separated by a first means (15) in order to produce a hydrogen-depleted liquid (33), the hydrogen-depleted liquid is introduced into the upper part of a stripping column (25) and a hydrogen-enriched gas (27) is drawn off at the head of the stripping column, at least partially condensed and sent back to the upper part of the stripping column.