Enhancements to the distillation column system and cycles for an argon and nitrogen producing cryogenic air separation unit are provided. The enhancements include systems and methods for: (i) recovery of xenon and krypton; (ii) production of oxygen product substantially free of hydrocarbons; and (iii) improvement in the design and performance of the super-stage argon column. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Cryogenic removal of carbon dioxide from the atmosphere, or CryoDAC (Cryogenic Direct Air Capture), uses extremely low temperatures to convert atmospheric CO.sub.2 into a frozen solid while other components of air such as oxygen and nitrogen remain as gases. Air from the atmosphere is passed through a recuperative heat exchanger to cool the air to a temperature slightly above the deposition point of CO.sub.2. The cooled air is then passed over a deposition surface chilled to a temperature below the deposition point of CO.sub.2. Carbon dioxide in the air transitions from gas to solid form upon contact with the deposition surface. The frozen CO.sub.2 is collected and stored. The cold air with CO.sub.2 removed is passed back through the recuperative heat exchanger to cool incoming air and is then returned to the atmosphere. The deposition surface may be cooled by a cryogenic refrigerator.

An air separation apparatus comprises: a first rectification column, a first condensing portion, a second rectification column, a third rectification column, a second condensing portion, a fourth rectification column, a third condensing portion, and a recycling pipe for recycling a gas drawn from the third condensing portion to the second rectification column. The air separation apparatus furthermore comprises: a branch pipe branching from the recycling pipe; and a control unit for controlling opening/closing of a valve so that a gas drawn from the third condensing portion is fed to the branch pipe for a predetermined period from the start of driving of the third condensing portion, and for controlling opening/closing of the valve so that the gas drawn from the third condensing portion is fed to the recycling pipe after the predetermined period has elapsed.

A CO2 separation and liquefaction system such as might be used in a carbon capture and sequestration system for a fossil fuel burning power plant is disclosed. The CO2 separation and liquefaction system includes a first cooling stage to cool flue gas with liquid CO2, a compression stage coupled to the first cooling stage to compress the cooled flue gas, a second cooling stage coupled to the compression stage and the first cooling stage to cool the compressed flue gas with a CO2 melt and provide the liquid CO2 to the first cooling stage, and an expansion stage coupled to the second cooling stage to extract solid CO2 from the flue gas that melts in the second cooling stage to provide the liquid CO2.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen.

An integrated industrial unit is provided, which can include: a nitrogen source configured to provide liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 75 K and 100 K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen. The refrigeration is provided by expansion of a pressurized gaseous nitrogen stream and vaporization of a liquid nitrogen stream that is sourced from a nearby air separation unit.

A cryogenic cooling system for an aircraft includes a first air cycle machine, a second air cycle machine, and a means for collecting liquid air. The first air cycle machine is operable to output a cooling air stream based on a first air source. The second air cycle machine is operable to output a chilled air stream at a cryogenic temperature based on a second air source cooled by the cooling air stream of the first air cycle machine. An output of the second air cycle machine is provided to the means for collecting liquid air.

A SPECTRA process for low-temperature fractionation of air, in which bottoms liquid from an additional second rectification column used to obtain oxygen is evaporated in a second condenser-evaporator. In this second condenser-evaporator, gas that has been evaporated beforehand in a first condenser-evaporator, which is used for condensation of tops gas from a first rectification column, is condensed at the pressure level of the previous evaporation. The invention likewise provides a corresponding plant.

A ground-based cryogenic cooling system includes a means for cooling an airflow and producing chilled air responsive to a power supply. A liquid air condensate pump system is operable to condense the chilled air into liquid air and urge the liquid air through a feeder line. A cryogenic cartridge includes a coupling interface configured to detachably establish fluid communication with the feeder line and a cryogenic liquid reservoir configured to store the liquid air under pressure. The cryogenic cartridge can be coupled to a cryogenic liquid distribution system on an aircraft. The liquid air can be selectively released from the cryogenic cartridge through the cryogenic liquid distribution system for an aircraft use.