Carbon dioxide is recovered from an exhaust gas in the form of liquid carbon dioxide or supercritical carbon dioxide utilizing a rotary separator. Nitrogen gas recovered from the rotary separator can be expanded to provide cooling for carbon dioxide in a closed-loop CO2 power cycle that is used to cool the exhaust gas upstream of the rotary separator. The recovery can power itself and can produce excess electricity from waste heat.

An apparatus for producing a purified, pressurized liquid carbon dioxide stream includes a distillation column (B) having packing (C) therein and a sump (D) below the packing, the distillation column in fluid communication with the liquid carbon dioxide supply tank for receiving the liquid carbon dioxide stream and the packing stripping volatile impurities from the liquid carbon dioxide stream; a heater (E) in contact with the liquid carbon dioxide stream in the sump (D) for vaporizing the liquid carbon dioxide stream in the sump; a vent in the distillation column (B) from which a first vaporized portion (G) of carbon dioxide vapor in the sump (D) is withdrawn from the distillation column: and a conduit (I) in fluid communication with the sump (D) and from which a second vaporized portion (H) of the carbon dioxide vapor in the sump is withdrawn into the conduit (I) to be introduced into the carbon dioxide vapor feed stream.

The invention relates to a method and apparatus for removing CO.sub.2 gas emissions from a coal combustion power plant, comprising a means for physically removing the CO.sub.2 gas from the coal, and then using a turbo compressor and turbo expander device to produce super chilled air, which can then be mixed with the CO.sub.2 gas to form frozen CO.sub.2 crystals which can agglomerate together to form dry ice blocks, wherein the ice blocks can be easily transported and stored, and/or used for commercial purposes (such as for the beverage industry). The heating (compression) and cooling (expansion) processes preferably generate additional energy which can then be used to offset the substantial costs associated with separating the CO.sub.2 gas from the coal.

The present invention relates to an improved method for removing contaminants from a gaseous stream substantially comprising carbon dioxide. More specifically, the method comprises the step of subjecting the gaseous stream to an absorption step in which the absorbent is liquid carbon dioxide wherein the waste of carbon dioxide is minimized by utilizing a compressing means for generating a pressure difference between two streams in a reboiler.

A process for separating carbon dioxide from a fluid containing carbon dioxide, NO.sub.2, and at least one of oxygen, argon, and nitrogen comprises the steps of separating at least part of the fluid into a carbon dioxide enriched stream, a carbon dioxide depleted stream comprising CO.sub.2 and at least one of oxygen, argon, and nitrogen and a NO.sub.2 enriched stream and recycling said NO.sub.2 enriched stream upstream of the separation step.

A set of process equipment for use in an enhanced oil recovery (EOR) process comprises first piping, a dehydrator, second piping, and a natural gas liquids recovery column. The first piping is configured to receive a wet carbon dioxide recycle stream from a recovery well. The dehydrator is configured to receive the wet carbon dioxide stream from the first piping and configured to dehydrate the wet carbon dioxide recycle stream using ethylene glycol to produce a dry carbon dioxide recycle stream. The second piping is configured to receive the dry carbon dioxide recycle stream from the dehydrator. The natural gas liquids recovery column is configured to receive the dry carbon dioxide recycle stream from the second piping and configured to separate the dry carbon dioxide recycle stream into a carbon dioxide reinjection stream and a natural gas liquids stream.

Light gases such as helium are extracted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.

The present disclosure relates to systems and methods that provide a low pressure liquid CO.sub.2 stream. In particular, the present disclosure provides systems and methods wherein a high pressure CO.sub.2 stream, such as a recycle CO.sub.2 stream from a power production process using predominately CO.sub.2 as a working fluid, can be divided such that a portion thereof can be expanded and used as a cooling stream in a heat exchanger to cool the remaining portion of the high pressure CO.sub.2 stream, which can then be expanded to form a low pressure CO.sub.2 stream, which may be in a mixed form with CO.sub.2 vapor. The systems and methods can be utilized to provide net CO.sub.2 from combustion in a liquid form that is easily transportable.

Cryogenic removal of carbon dioxide from the atmosphere, or CryoDAC (Cryogenic Direct Air Capture), uses extremely low temperatures to convert atmospheric CO.sub.2 into a frozen solid while other components of air such as oxygen and nitrogen remain as gases. Air from the atmosphere is passed through a recuperative heat exchanger to cool the air to a temperature slightly above the deposition point of CO.sub.2. The cooled air is then passed over a deposition surface chilled to a temperature below the deposition point of CO.sub.2. Carbon dioxide in the air transitions from gas to solid form upon contact with the deposition surface. The frozen CO.sub.2 is collected and stored. The cold air with CO.sub.2 removed is passed back through the recuperative heat exchanger to cool incoming air and is then returned to the atmosphere. The deposition surface may be cooled by a cryogenic refrigerator.

A system and method for producing acetic acid, including dry reforming methane with carbon dioxide to give syngas, cryogenically separating carbon monoxide from the syngas giving a first stream including primarily carbon monoxide and a second stream including carbon monoxide and hydrogen. The method includes synthesizing methanol from the second stream via hydrogenation of carbon monoxide in the second stream, synthesizing dimethyl ether from the methanol, and generating acetic acid from the dimethyl ether and first-stream carbon monoxide.