An acid gas purification system is described herein that includes a primary membrane system with a CO.sub.2- and H.sub.2S-enriched permeate stream effluent and a hydrocarbon stream effluent; a first compression stage arranged to receive the CO.sub.2- and H.sub.2S-enriched permeate stream and produce a compressed stream; and a cryogenic separation system to receive the compressed stream, the cryogenic separation system including a cooler followed by a fractionator, wherein the fractionator produces a CO.sub.2- and H.sub.2S liquid stream and a hydrocarbon gas stream.

The present disclosure relates to systems and methods useful for power production. In particular, a power production cycle utilizing CO.sub.2 as a working fluid may be configured for simultaneous hydrogen production. Beneficially, substantially all carbon arising from combustion in power production and hydrogen production is captured in the form of carbon dioxide. Further, produced hydrogen (optionally mixed with nitrogen received from an air separation unit) can be input as fuel in a gas turbine combined cycle unit for additional power production therein without any atmospheric CO.sub.2 discharge.

The present disclosure relates to systems and methods useful for power production. In particular, a power production cycle utilizing CO.sub.2 as a working fluid may be combined with a second cycle wherein a compressed CO.sub.2 stream from the power production cycle can be heated and expanded to produce additional power and to provide additional heating to the power production cycle.

The present disclosure provides an integrated power generating system and method and liquefied natural gas (LNG) vaporization system and method. More particularly, heat from a CO.sub.2 containing stream from the power generating system and method can be used to heat the LNG for re-gasification as gaseous CO.sub.2 from CO.sub.2 containing stream is liquefied. The liquefied CO.sub.2 can be captured and/or recycled back to a combustor in the power generating system and method.

A marine vessel and method for carbon capture and sequestration are described. The marine vessel includes a buoyant hull, a cryogenic storage tank within the hull, and a gaseous carbon dioxide loading manifold. The marine vessel also includes a carbon dioxide liquefaction system in fluid communication with the cryogenic storage tank downstream of the carbon dioxide liquefaction system and with the gaseous carbon dioxide loading manifold upstream of the carbon dioxide liquefaction system. Finally, the marine vessel includes a carbon dioxide supercritical system in fluid communication with the cryogenic storage tank. In operation, the marine vessel moves between multiple locations, where gaseous carbon dioxide is onboarded, liquified and stored. Thereafter, the marine vessel transports the liquified carbon dioxide to a location adjacent an offshore geological reservoir. The liquefied carbon dioxide is then pressurized to produce supercritical carbon dioxide, which is then injected directly into the reservoir from the marine vessel.

The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO.sub.2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO.sub.2 circulating fluid. Fuel derived CO.sub.2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

In this patent we disclose, for the first time, detailed methods of our newly invented state-of-the-art cryogenic technology for the cost effective energy efficient capture of each known component of entire emissions (nearly 100%) such as carbon dioxide (CO.sub.2), sulfur oxides (SO.sub.x), nitrogen oxides (NO.sub.x), carbon monoxide(CO), any other acid vapor, mercury, steam and unreacted nitrogen from industrial plants (coal and natural gas fired power plants, cement plants etc.), in a liquefied or frozen/solidified form, such that each of the components is captured separately and is industrially useful. This new technology includes a novel NH.sub.3 power plant to generate auxiliary electrical power from the heat energy of the flue gas to further improve the energy efficiency and cost effectiveness of the capture processes. It is the most cost effective of all existing emission capture technologies. It does not require use of any chemicals/reagents/external cryogens, unlike the current technologies. It uses only a fixed amount of water needed for the cooling process which can be used repeatedly. We present detailed methods of operations, together with scientific and economic analysis of the energy needed and cost involved for the said capture in two specific examples, and advantages of the new technology over the existing ones.

The power required to recover C.sub.3+ hydrocarbons from crude carbon dioxide comprising C.sub.1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C.sub.3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce lighter and heavier hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.

In a process for separating at least one heavy impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one light impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the light impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed light impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.

A proposed method provides a highly efficient fueled power output augmentation of the liquid air energy storage (LAES) through its integration with the semi-closed CO.sub.2 bottoming cycle. It combines the production of liquid air in air liquefier during LAES charge using excessive power from the grid and an effective recovery of stored air for production of on-demand power in the fueled supercharged reciprocating internal combustion engine (ICE) and associated expanders of the power block during LAES discharge. A cold thermal energy of liquid air being re-gasified is recovered for cryogenic capturing most of CO.sub.2 emissions from the facility exhaust with following use of the captured CO.sub.2 in the semi-closed bottoming cycle, resulting in enhancement of total LAES facility discharge power output and suppressing the thermal NOx formation in the ICE.