An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

A system includes a controller configured to perform an enable operation responsive to receiving information indicative of an enable parameter, the enable operation includes: determining a predicted downstream NOx value of an exhaust gas stream exiting a NOx storage catalyst; determining a downstream NOx value of the exhaust gas stream exiting the NOx storage catalyst; determining an error between the predicted downstream NOx value and the determined downstream NOx value; comparing the error to an error threshold; and determining that the NOx storage catalyst is in good health responsive to determining that the error does not exceed the error threshold. The controller is further configured to perform a disable operation responsive to receiving information indicative of a disable parameter, the disable operation causing a deactivation of at least a portion of the controller.

A mixer assembly for a vehicle exhaust system includes an inner wall surface and a flow diverter with a flow directing surface that is spaced apart from the inner wall surface to provide an exhaust gas inlet area. The flow directing surface terminates at a distal end that is spaced apart from the inner wall surface to provide an orifice between the distal end and the inner wall surface through which exhaust gas flow accelerates and is directed to flow along the inner wall surface. A vehicle exhaust component assembly that includes the mixer and a method for mixing injected fluid spray into the mixer are also disclosed.

A process for capturing carbon dioxide (CO.sub.2) emissions and converting the CO.sub.2 into other products is disclosed herein. The process includes capturing CO.sub.2 emissions from an exhaust mechanism at a CO.sub.2 capture device. The process also includes converting the CO.sub.2 emissions into a carbon-based product using catalysis, such as an electrochemical process or a photocatalytic process.

A method for operating an internal combustion engine includes combusting a fuel and air mixture within a combustion chamber of an internal combustion engine, thereby forming an exhaust gas, passing the exhaust gas out of the combustion chamber, performing a startup procedure, the startup procedure including passing the exhaust gas from the combustion chamber to a storage unit, capturing criteria pollutants of the exhaust gas with the storage unit, passing the exhaust gas from the storage unit to an aftertreatment system, heating the aftertreatment system to an activation temperature with the exhaust gas from the storage unit, and subsequent to heating the aftertreatment system to the activation temperature, performing a secondary procedure, the secondary procedure including passing the exhaust gas from the combustion chamber to the aftertreatment system thereby forming a treated exhaust gas, and passing the treated exhaust gas to the storage unit.

The present description provides high working capacity adsorbents with low DBL bleed emission performance properties that allows the design of evaporative fuel emission control systems that are lower cost, simpler and more compact than those possible by prior art. Emission control canister systems comprising the adsorbent material demonstrate a relatively high gasoline working capacity, and low emissions.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

A control system for a vehicle, the control system comprising one or more controllers, the control system being arranged to: determine a prediction of an end of a current driving cycle of the vehicle, determine a likelihood of slippage from an emissions trap of the vehicle in a next driving cycle of the vehicle in dependence on the prediction of the end of the current driving cycle, and control purging of the emissions trap prior to the prediction of the end of the current driving cycle in dependence on the likelihood of slippage.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol% and 50 vol% n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol% and 50 vol% n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr BETP butane loading step.