Methods are provided for emissions control of a vehicle. In one example, a method for an engine may include, responsive to a plurality of diagnostic entry conditions being met, indicating degradation of a hydrocarbon trap based on an NH.sub.3 amount in an exhaust gas. In some examples, the NH.sub.3 amount may be determined based on one or more NO.sub.x sensor outputs. In some examples, the plurality of diagnostic entry conditions may include the engine having been in operation over an initial duration immediately following an engine cold start. Conditions of the exhaust gas following the engine cold start may be opportunistically utilized in determining the NH.sub.3 amount from the one or more NO.sub.x sensor outputs. In some examples, the exhaust gas may be actively provided at a predetermined air-fuel ratio to meet at least one of the plurality of diagnostic entry conditions.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

Controlling exhaust after-treatment in a heavy-duty motor vehicle includes operating a diesel engine of a heavy-duty truck such that the diesel engine generates an exhaust gas flow that enters an exhaust after-treatment system of the heavy-duty truck, the exhaust after-treatment system including a selective catalytic reduction system, measuring a level of NO.sub.x gases in the exhaust gas flow downstream of the selective catalytic reduction system, and controlling a diesel exhaust fluid injector upstream of the selective catalytic reduction system to inject diesel exhaust fluid into the exhaust gas flow upstream of the selective catalytic reduction system at an injection rate that is based on the measured level of NO.sub.x gases.

The present description provides high working capacity adsorbents with low DBL bleed emission performance properties that allows the design of evaporative fuel emission control systems that are lower cost, simpler and more compact than those possible by prior art. Emission control canister systems comprising the adsorbent material demonstrate a relatively high gasoline working capacity, and low emissions.

A method for operating an exhaust gas post-treatment system of a diesel engine and associated exhaust gas post-treatment system are described. The system has two NOx sensors upstream and downstream of an SCR catalytic converter. The NOx sensor downstream of the SCR catalytic converter is used to divide the NOx information measured by the sensor upstream of the SCR catalytic converter into an NOx value and an NH.sub.3 value. Using this simple method, the SCR catalyst control and diagnosis can be carried out precisely and robustly.

Catalysts for passive NOx absorber to remove NOx from exhaust gas system during engine cold start operation having high storage capacity and ideal desorption properties. The catalysts may include a system having an alumina supported Pt/Ce—Zr mixed oxide catalysts material synthesized by deposition co-precipitation using a precipitation agent selected from the group consisting of ammonium hydroxide (NH.sub.4OH), ammonium carbonate ((NH.sub.4).sub.2CO.sub.3), sodium hydroxide (NaOH), sodium carbonate (Na.sub.2CO.sub.3).

Methods and systems are provided for a low temperature NOx adsorber (LTNA). In one example, a method includes operating in a first mode, the first mode including storing exhaust NOx in an LTNA, heating the LTNA until an LTNA outlet temperature reaches a first threshold temperature, and then converting released NOx in a downstream selective catalyst reduction (SCR) device; and operating in a second mode, the second mode including heating the LTNA until the LTNA outlet temperature reaches a second threshold temperature, higher than the first threshold temperature, and converting exhaust NOx in the SCR device.

An exhaust gas purification device includes a first catalyst, a bypass pipe, a second catalyst, and a switching controller. The first catalyst is provided in an exhaust pipe. The bypass pipe branches from a first portion of the exhaust pipe. The first portion is located upstream of the first catalyst. The bypass pipe is recoupled to a second portion of the exhaust pipe. The second portion is located upstream of the first catalyst. The second catalyst is provided in the bypass pipe. The switching controller is configured to switch a flow path of an exhaust gas to the bypass pipe based on a deterioration degree of the first catalyst.

An exhaust gas purification device includes a first catalyst, a second catalyst, a bypass pipe, a hydrocarbon adsorbent, and a switching controller. The first catalyst is provided in an exhaust pipe. The second catalyst is provided downstream of the first catalyst in the exhaust pipe. The bypass pipe branches from a first portion of the exhaust pipe. The first portion is located upstream of the second catalyst. The bypass pipe is recoupled to a second portion of the exhaust pipe. The second portion is located upstream of the second catalyst. The hydrocarbon adsorbent is provided in the bypass pipe. The switching controller is configured to switch a flow path of an exhaust gas to the bypass pipe based on a deterioration degree of the first catalyst.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr BETP butane loading step.