Methods and systems are provided for two-stage treatment of contaminated particulate material, such as soil, sediment, and/or sludge. The methods and systems utilize a thermal desorption process combined with a smoldering combustion process. The contaminated particulate material is first exposed to thermal desorption at high temperatures (e.g., greater than 150 C.) to form a heated contaminated particulate material. Next, a smoldering combustion process is initiated by introducing a combustion-supporting gas. The combined process can take place in the same or different treatment units.

The present invention is directed to an apparatus for domestic hot water and electricity production by the use of a natural organic fuel, the apparatus comprising a separated chambers pyrolysis furnace comprising: a) a pyrolysis chamber wherein the fuel is heated, substantially in the absence of oxygen at a temperature capable of causing pyrolysis of fuel; b) a combustion chamber of the pyrolyzed fuel, wherein the pyrolyzed fuel is burned in the presence of an air flux. The invention is also directed to an apparatus for the production of domestic hot water and electricity, which apparatus comprises: the above defined furnace; b) a heat exchanger connected to the exit of the exhausted gas, wherein domestic water is heated; c) a power generator connected with the exit of syngas, wherein syngas produced in the pyrolysis chamber is used as a fuel.

The invention is concerned with an integrated unit comprising a unitary boiler and gas cleaning apparatus. Preferably the integrated unit comprises a boiler unit, and gas cleaning apparatus, the integrated unit has a reaction unit and further comprises a radiant zone connected to the reaction unit, the radiant zone being connected to a convection zone. The integrated unit further comprises a heat exchange means encircling at least one of the radiant zone and the convection zone, and gas cleaning means is preferably provided around at least a part of the heat exchange means. The reaction unit may comprise a fluid bed boiler, gasifier or pyrolytic chamber and wherein fuel is burned completely; burned under pyrolytic conditions; or is gasified. The heat exchange means may comprise an annular heat exchange chamber and the gas cleaning means may be provided in an annular gas cleaning chamber encircling the heat exchange chamber.

A thermochemical system & method may be configured to convert an organic feedstock to various products. A thermochemical system may include a solid material feed module, a reactor module, an afterburner module, and a solid product finishing module. The various operational parameters (temperature, pressure, etc.) of the various modules may vary depending on the desired products. The product streams may be gaseous, vaporous, liquid, and/or solid.

A thermochemical system & method may be configured to convert an organic feedstock to various products. A thermochemical system may include a solid material feed module, a reactor module, an afterburner module, and a solid product finishing module. The various operational parameters (temperature, pressure, etc.) of the various modules may vary depending on the desired products. The product streams may be gaseous, vaporous, liquid, and/or solid.

A pyrolysis waste-to-energy conversion system has a muffle furnace housing a rotating retort drum within the furnace and having an inlet sleeve and an outlet sleeve extending through inlet and outlet ends of the muffle furnace. A rotating retort drum drive applies rotary drive to the inlet rotating retort drum sleeves and an in-feed auger is within a tube within the inlet sleeve. An out-feed auger is within a tube within the outlet sleeve and arranged to deliver char and pyrolysis syngas to a char processing system and a syngas processing system. The inlet sleeve and said outlet sleeve are arranged to provide a gas seal to prevent air ingress or syngas egress to and from the rotating retort drum. A gas cleaning system has a cracking tower arranged to retain inlet gas at an elevated temperature for a residence time, and a gas quench and scrubber system.

A pyrolysis reactor system includes a reactor and a contactor mounted above the reactor. The reactor has a shell, an inlet and an outlet. A central shaft runs along its axis and supports agitation blades in a counter-helical arrangement, and an auger. Rotation of the auger in one direction feeds feedstock into the vessel, and in the opposite direction removes char at the end of a batch. The contactor includes four elements with a frusto-conical part supported on vertical support arms, and being connected to a disc by legs. The contactor elements allow short chains to pass through apertures while long chains condense on their surfaces or on the vessel wall surface. There is dynamic tuning of carbon number of gases flowing downstream by active temperature and pressure control at the contactor.

A process is described for treating waste plastics material to provide at least one on-specification fuel product. Plastics material is melted and then pyrolyzed in an oxygen-free atmosphere to provide pyrolysis gases. The pyrolysis gases are brought into contact with plates in a contactor vessel so that some long chain gas components condense and return to be further pyrolyzed to achieve thermal degradation. Short chain gas components exit the contactor in gaseous form and proceed to distillation to provide one or more on-specification fuel products. A pipe directly links the pyrolysis chamber to the contactor, suitable for conveying upwardly-moving pyrolysis gases and downwardly-flowing long-chain liquid for thermal degradation.

Systems and methods are disclosed for pyrolysis of waste feed material. Some systems include a main retort and a secondary retort. Syngas is produced by pyrolysis in the main retort, and is then mixed with combustion air and ignited, in some cases to produce energy. Carbon char travels to the secondary retort and is exhausted from the system through an airlock.

A carbonaceous feed pyrolysis apparatus is provided including two or more hot particle fluidised beds, one of which contains a combustion zone, and one or more positive displacement apparatus for the transfer of hot particles beds. Also provided is a bio-oil production process including two or more fluidised beds, a first combustion zone carried out in one or more combustion fluidised beds in which a particulate material is fluidised and heated, and a second pyrolysis zone carried out in one or more pyrolysis fluidised beds in which hot particles heated in the combustion zone are used for pyrolysis of bio-mass, the combustion zone being operated at or about atmospheric pressure at a temperature of from 400 C. to 1100 C., and the pyrolysis zone being operated at a pressure of from atmospheric to 100 Barg at a temperature of from 400 C. to 900 C.