F25J1/0027

Industrial and hydrocarbon gas liquefaction
11035610 · 2021-06-15 · ·

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as −71° C.

USE OF SUPERCRITICAL CO2 AS SOLVENT FOR ORGANIC POLYMERS IN A METHOD FOR COATING UREA-CONTAINING GRANULES

A process may be utilized to coat urea-containing granules with organic polymers. The process may involve compressing gaseous carbon dioxide and condensing the carbon dioxide to obtain liquid carbon dioxide, increasing the pressure and/or the temperature above the critical point of carbon dioxide and obtaining supercritical carbon dioxide, dissolving an organic polymer in the supercritical carbon dioxide to obtain a polymer-containing solution, and mixing the polymer-containing solution with urea-containing granules and lowering the temperature and/or the pressure below the critical point of carbon dioxide and obtaining coated urea-containing granules and gaseous carbon dioxide. In some cases the organic polymer may include biodegradable polymers, and the polymer-containing solution may contain between 20 to 70% by weight biodegradable polymers.

STEAM METHANE REFORMING UNIT FOR CARBON CAPTURE
20210284530 · 2021-09-16 ·

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-CO.sub.2 gas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-CO.sub.2 flue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of CO.sub.2 reaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

METHOD FOR LIQUEFYING AMMONIA

A method for liquefying ammonia can include the steps of: providing a pressurized carbon dioxide stream from a power generating facility; expanding the pressurized carbon dioxide stream to a lower pressure that is sufficient to produce a dual phase carbon dioxide fluid; introducing the dual phase carbon dioxide fluid to a gas-liquid separator; withdrawing a liquid stream from the gas-liquid separator; and liquefying an ammonia gas stream in an ammonia liquefier by indirect contact with the liquid stream from the gas-liquid separator, thereby forming a liquid ammonia stream and a gaseous carbon dioxide stream.

Booster system

A booster system for increasing pressure of an object gas includes: a first compression unit that compresses the object gas to intermediate pressure equal to or higher than the critical pressure and lower than the target pressure and generates an intermediate supercritical fluid; a cooling unit that cools the intermediate supercritical fluid with a cooling medium and generates an intermediate supercritical pressure liquid; a liquid extracting and pressure reducing unit that extracts a part of the intermediate supercritical pressure liquid; a flow regulating valve that regulates a flow rate of the extracted part of the intermediate supercritical pressure liquid; a second compression unit that increases pressure of the rest of the intermediate supercritical pressure liquid to be equal to or higher than the target pressure; and a pressure sensor that detects pressure of the intermediate supercritical pressure liquid.

CRYOGENIC LIQUEFIER BY INTEGRATION WITH POWER PLANT

A method for producing liquid nitrogen using a residual gas stream derived from a flue gas of a power plant is provided. The residual gas stream is purified in a front-end purification unit to remove freezable components and then the purified stream is compressed. Following compression, the stream can be divided into a first portion and a second portion, wherein the first portion is cooled and sent to a distillation column, wherein oxygen and argon are separated, thereby leaving an essentially pure gaseous nitrogen stream. The gaseous nitrogen stream can then be liquefied using refrigeration provided by expanding the second portion of the purified stream. In a preferred embodiment, the second portion is expanded in two turbines, and the gaseous nitrogen is compressed in a cold nitrogen booster, which is powered by one of the two turbines. In an additional embodiment, after warming, the expanded second portion of the purified stream can be used to regenerate the front-end purification unit.

Integration of Contaminant Separation and Regasification Systems
20210131613 · 2021-05-06 ·

Methods and systems for cryogenically separating contaminants and regasification of LNG utilizing common refrigeration equipment and/or fuel. An integrated system includes: a component for separating contaminants from an input feed stream; a heat exchanger coupled to a first line, wherein: the first line is coupled to the component for separating contaminants, and the heat exchanger cools a first feed stream of the first line; and a LNG regasification system comprising a vaporizer, wherein: the vaporizer heats a LNG stream of the LNG regasification system, and the heat exchanger functions as the vaporizer. A process includes: separating contaminants from an input feed stream with a component for separating contaminants; cooling a first feed stream with a heat exchanger, wherein the heat exchanger is coupled to the component for separating contaminants; and heating a LNG stream with a vaporizer of a LNG regasification system, wherein the heat exchanger functions as the vaporizer.

POWER GENERATION PROCESS UTILIZING FUEL, LIQUID AIR AND/OR OXYGEN WITH ZERO CO2 EMISSIONS
20230408192 · 2023-12-21 ·

A system which integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.

Booster system

A booster system includes: a cooling temperature regulating unit configured to regulate a temperature of an intermediate supercritical pressure liquid cooled and generated by a main cooling unit on upstream of a pump unit according to a flow rate of a supplied cooling medium; and a pressure detection unit configured to detect inlet pressure of the intermediate supercritical pressure liquid on an inlet side of the pump unit and detect outlet pressure of a target supercritical fluid on an outlet side of the pump unit. The cooling temperature regulating unit controls the flow rate of the cooling medium based on a pressure difference between the inlet pressure and the outlet pressure or a pressure ratio between the inlet pressure and the outlet pressure.

Method for liquid air energy storage with fueled and zero carbon emitting power output augmentation
10940424 · 2021-03-09 ·

A proposed method provides a fueled power output augmentation of the liquid air energy storage (LAES) with zero carbon emissions of its exhaust. It combines the production of liquid air using a low-demand power from the renewable or/and conventional energy sources and the recovery of stored air for production of on-demand power in the fueled supercharged reciprocating internal combustion engine (RICE) and associated expanders. An integration between the LAES and RICE makes possible to recover the RICE exhaust energy for increase in power produced by the expanders of LAES and to use a cold thermal energy of liquid air being re-gasified at the LAES facility for cryogenic capture of CO.sub.2 emissions from the RICE exhaust.